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超滤膜处理稀土冶炼废水过程膜污染特性分析 被引量:7
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作者 桂双林 麦兆环 +3 位作者 付嘉琦 魏源送 陈小平 万金保 《膜科学与技术》 CAS CSCD 北大核心 2020年第5期77-84,共8页
采用超滤膜错流过滤稀土冶炼萃取废水,对污染物的处理效率和膜污染特征进行了研究.通过设计膜阻实验,测算膜污染总阻力及其构成比例,结果表明膜自身阻力相对较高,膜污染阻力以沉积层阻力和堵塞阻力为主,浓差极化阻力较弱.考察了膜通量... 采用超滤膜错流过滤稀土冶炼萃取废水,对污染物的处理效率和膜污染特征进行了研究.通过设计膜阻实验,测算膜污染总阻力及其构成比例,结果表明膜自身阻力相对较高,膜污染阻力以沉积层阻力和堵塞阻力为主,浓差极化阻力较弱.考察了膜通量随时间和跨膜压差变化规律,以及超滤膜对污染物的截留效率,当跨膜压差为0.1~0.5 MPa时,COD和浊度平均去除率分别为26.5%和77.7%.SEM、EDX分析发现膜面有大量颗粒物和结晶物等污染物,Na、Ca、Cl和S为主要无机元素.采用纯水、HCl、NaOH、NaClO和EDTA 5种清洗液对污染膜进行了清洗,对洗脱液组成、污染膜和清洗膜的形貌特征进行了分析,结果表明酸洗对无机金属离子有着较好的去除效果,碱洗对有机物尤其是腐殖酸类和芳香族化合物的去除效果较佳. 展开更多
关键词 超滤﹔稀土冶炼 膜污染﹔废水处理
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Sorption Kinetic Analysis for the Removal of Copper(Ⅱ) by Using Biofilm 被引量:3
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作者 张敬 姜斌 +2 位作者 李鑫钢 刘瑞轩 孙永利 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2005年第1期135-139,共5页
The biosorption of copper(Ⅱ) ions onto biofilm was studied in a batch system with respect to the temperature, initial pH value and biofilm sorbent mass. The biomass exhibited the highest copper(Ⅱ) sorption capacity ... The biosorption of copper(Ⅱ) ions onto biofilm was studied in a batch system with respect to the temperature, initial pH value and biofilm sorbent mass. The biomass exhibited the highest copper(Ⅱ) sorption capacity under the conditions of room temperature, initial pH value of 6.0 and the sorbent mass 8 g. The experimental data were analyzed using four sorption kinetic models, the pseudo-first order, the Ritchie second order, the modified second order and the Elovich equations to determine the best-fit equation for the sorption of metal ions onto biofilm. Comparing with the sum of squared-errors, the results show that both the Ritchie second order and modified second order equations can fit the experimental data very well. 展开更多
关键词 BIOSORPTION copper(Ⅱ) BIOFILM KINETICS
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Fouling Characteristics and Prevention Techniques for Membrane Bioreactor
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作者 LUHua WANGZhi-qiang YANGJin-ying 《Journal of China University of Mining and Technology》 EI 2005年第1期36-40,共5页
Membrane fouling is the main problem of membrane bioreactors (MBR), which seriously influ- ences its wastewater treatment effect and running. The characteristics of microbiology and hydrodynamics concerning membrane f... Membrane fouling is the main problem of membrane bioreactors (MBR), which seriously influ- ences its wastewater treatment effect and running. The characteristics of microbiology and hydrodynamics concerning membrane fouling were investigated and the measure was put forward for optimum operation of MBR. The measure is that 1) the parameters of activated sludge concentration (X) and membrane flux should be lower than the critical values of X and membrane flux respectively, and 2) the activated sludge should be discharged periodically. The experimental results show that the combination backwashing of gas and perme- ated effluent is better than single gas backwashing or single permeated effluent backwashing. This technique can remove the cake layer deposited on the membrane surface, decrease the membrane fouling, and recover the membrane flux effectively. So it is effective for prevention of membrane fouling. 展开更多
关键词 membrane bioreactor (MBR) membrane fouling membrane fouling index BACKWASHING ratio of gas to permeated effluent
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