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含亲水疏油链段聚合物改性PVDF膜的抗污染性能研究 被引量:3
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作者 孙程奇 白仁碧 杨晶晶 《塑料工业》 CAS CSCD 北大核心 2020年第9期121-126,共6页
基于一种亲水疏油PVDF超滤膜对不同浓度的油和天然有机物的过滤试验结果,评估膜抗污染性能和分析膜污染机制。试验采用错流过滤的试验方法,通过测定水样的浊度和总有机碳(TOC)来评估该膜对有机物的去除效果;通过清洗后膜通量的恢复率评... 基于一种亲水疏油PVDF超滤膜对不同浓度的油和天然有机物的过滤试验结果,评估膜抗污染性能和分析膜污染机制。试验采用错流过滤的试验方法,通过测定水样的浊度和总有机碳(TOC)来评估该膜对有机物的去除效果;通过清洗后膜通量的恢复率评估膜的抗污染性能;运用阻力叠加模型和扩展的德亚盖因-兰多-弗韦-奥弗比克理论(XDLVO)计算分析膜污染机制,结合扫描电子显微镜(SEM)对膜表面的观察结果支持得出的结论。该膜对较高浓度的乳化油去除率达90%以上,清洗后通量基本恢复初始值。过滤50 mgC/L的有机物时,该膜对海藻酸钠(SA)的去除率为85%,对腐植酸(HA)的去除率为45.2%,对牛血清蛋白(BSA)的去除率很低;SA和油的膜污染机制是在膜表面形成致密的滤饼层,SA还有部分膜孔吸附;HA污染机制是膜孔堵塞和在膜表面形成滤饼层;BSA污染机制主要是膜孔吸附。经简单化学清洗后通量恢复率达95%以上,该膜具有较强的抗污染性能。 展开更多
关键词 亲水疏油 PVDF超滤 有机物去除 污染性能 膜清洗效率
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Characterization of polysulfone hollow-fiber ultrafiltration membrane and its cleaning efficiency by streaming potential and flux method 被引量:1
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作者 邱运仁 缪畅 叶红齐 《Journal of Central South University》 SCIE EI CAS 2009年第2期195-200,共6页
Polysulfone(PS)hollow-fiber ultrafiltration membrane was characterized combined with flux and streaming potential in single electrolyte solutions.The effects of trans-membrane pressure,electrolyte concentration,ion va... Polysulfone(PS)hollow-fiber ultrafiltration membrane was characterized combined with flux and streaming potential in single electrolyte solutions.The effects of trans-membrane pressure,electrolyte concentration,ion valence and pH value of electrolyte solution on the streaming potential(SP)of the membrane were investigated.The zeta potential and surface charge density of the membrane were calculated on the basis of Helmholtz-Smoluchowski equation and Gouy-Chapmann theory.The results indicate that the valence and concentration of cation have a greater influence on the SP and surface charge density of PS membrane than those of anion,and the pH value of electrolyte solution has great effects on the SP and zeta potential of the membrane surface. Both the absolute value of the streaming potential and water flux of the adsorbed membrane decrease,compared with those of the clean membrane.The streaming potential and flux of the cleaned membrane can be completely recovered by cleaning with the mass fraction of 0.8%EDTA at pH=10. 展开更多
关键词 hollow fiber membrane POLYSULFONE ULTRAFILTRATION streaming potential CLEANING
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