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含氟丙烯酸酯共聚乳液及其膜表面特性的研究 被引量:45
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作者 赵兴顺 丁小斌 +4 位作者 张军华 郑朝晖 潘毅 朱珠 彭宇行 《高分子学报》 SCIE CAS CSCD 北大核心 2004年第2期196-200,共5页
以十二烷基硫酸钠 (SDS)和OP 10混合乳化剂 ,制备了甲基丙烯酸全氟辛基乙酯 (FMA8) 甲基丙烯酸丁酯 (BMA) 甲基丙烯酸 (MAA)共聚乳液 .通过DSC、FT IR、1 H NMR对共聚物的结构、组成进行了表征研究 .采用JZHY 180界面张力仪研究了共... 以十二烷基硫酸钠 (SDS)和OP 10混合乳化剂 ,制备了甲基丙烯酸全氟辛基乙酯 (FMA8) 甲基丙烯酸丁酯 (BMA) 甲基丙烯酸 (MAA)共聚乳液 .通过DSC、FT IR、1 H NMR对共聚物的结构、组成进行了表征研究 .采用JZHY 180界面张力仪研究了共聚乳液膜表面的性质 ,结果表明 ,随着共聚物中全氟单体含量的增加 ,共聚物膜的表面能显著降低 ,当全氟单体的含量达到 2 5wt %时 ,其表面能降低到 19 74mJ m2 .X ray光电子能谱(XPS)对共聚物表面原子组成的分析结果表明 ,共聚物表面氟的含量远高于其平均含量 ,证明了含氟基团的趋表现象 .经退火处理 ,共聚物膜表面的氟含量增加 。 展开更多
关键词 含氟丙烯酸酯 乳液共聚 膜表面特性 表面自由能 甲基丙烯酸全氟辛基乙酯 表面活性剂 退火处理
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The Effects of Annealing on the Surface Properties of Titania Films Prepared on Titanium by Micro-Arc Oxidation
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作者 JIN Fanya ZHU Ming LI Jiong WANG Ke SHEN Liru TONG Honghui 《Southwestern Institute of Physics Annual Report》 2005年第1期144-146,共3页
Titanium and its alloys are widely used in the aerospace, marine, and biomedical industry due to their unique bulk properties such as high strength-to-weight ratio and melting temperature, good corrosion resistance, a... Titanium and its alloys are widely used in the aerospace, marine, and biomedical industry due to their unique bulk properties such as high strength-to-weight ratio and melting temperature, good corrosion resistance, and favorable biocom- patibility. However, in some applications, com- ponents made of titanium or titanium alloys exhibit poor wear resistance under stationary or dynamic loading as well as contact corrosion manifested by the relatively negative standard electrode potential (-1.63 V ) . In order to improve the surface properties of titanium and its alloys, several techniques such as PVD ( physical vapor deposition ) /CVD (chemical vapor deposition ) coatings, 展开更多
关键词 Micro-arc oxidation Titanium oxide film Annealing Surface properties
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Mixed P3HT/PCBM Organic Thin-Film Transistors: Relation between Morphology and Electrical Characteristics
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作者 Khairul Anuar Mohamad Afishah Alias +3 位作者 Ismail Saad Bablu Kumar Gosh Katsuhiro Uesugi Hisashi Fukuda 《Journal of Chemistry and Chemical Engineering》 2014年第5期476-481,共6页
The mixed P3HT (poly(3-hexylthiophene)) and [6,6]-PCBM (phenyl C61-butyric acid methyl ester) organic thin films were investigated for electronic structure using UV-Vis spectrophotometer and PESA (photo-electro... The mixed P3HT (poly(3-hexylthiophene)) and [6,6]-PCBM (phenyl C61-butyric acid methyl ester) organic thin films were investigated for electronic structure using UV-Vis spectrophotometer and PESA (photo-electron spectroscopy in air). Furthermore, ESR (electron spin resonance) and AFM (atomic force microscopy) were used to investigate the surface morphology and molecular orientation, respectively. ESR analysis indicated the molecular orientation of the P3HT crystalline in the blend thin films, which the crystalline oriented normal to the substrate with distribution of 35°. AFM images indicated that the surface morphology of P3HT film was affected by the presence of PCBM nanoparticles. Solution-processed OTFTs (organic thin-film transistors) based on P3HT/PCBM blend thin film in a top source-drain contact structure was fabricated, and the electrical characteristics of the devices were also investigated. A unipolar property with p-channel characteristics were obtained in glove box measurement. 展开更多
关键词 Organic semiconductor P3HT PCBM P3HT/PCBM blend thin film organic thin-film transistor.
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