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二硫纶修饰的β-环糊精的自包合以及对金属离子的响应(英文)
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作者 焦华晶 王琪 +1 位作者 丁刘镠 芦昌盛 《无机化学学报》 SCIE CAS CSCD 北大核心 2015年第7期1269-1277,共9页
利用圆二色光谱,核磁,等温滴定量热法和化学滴定方法研究单-6-马来二氰二硫代酸钠-β-环糊精在水溶液中的自包合性质。化学滴定实验结果表明十二烷基硫酸钠(SDS),Cu2+和Co2+可以改变单-6-马来二氰二硫代酸钠-β-环糊精的构象,并且得出单... 利用圆二色光谱,核磁,等温滴定量热法和化学滴定方法研究单-6-马来二氰二硫代酸钠-β-环糊精在水溶液中的自包合性质。化学滴定实验结果表明十二烷基硫酸钠(SDS),Cu2+和Co2+可以改变单-6-马来二氰二硫代酸钠-β-环糊精的构象,并且得出单-6-马来二氰二硫代酸钠-β-环糊精在水溶液中的存在形式是自包合的结论;Cu2+可以作为打开单-6-马来二氰二硫代酸钠-β-环糊精自包合结构的"钥匙",使其构象改变后可以与中性红(NR)发生包合作用;加入EDTA与Cu2+配位后,单-6-马来二氰二硫代酸钠-β-环糊精恢复自包合结构,同时释放中性红客体分子。 展开更多
关键词 单-6-马来二氰二硫代酸钠-β-环糊精 圆二色 自包合 金刚烷胺
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Investigation of a Network Failure Problem with a Significant Path, from the Perspective of Crisis Management 被引量:1
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作者 Jun-ichi Takeshita Hiroaki Mohri 《Journal of Mathematics and System Science》 2014年第7期479-485,共7页
The objective of this study is to investigate a network failure problem with a significant path, emerging from the context of crisis management, such as in the case of natural disasters. For a given tree with m failed... The objective of this study is to investigate a network failure problem with a significant path, emerging from the context of crisis management, such as in the case of natural disasters. For a given tree with m failed edges, we assume that we have sufficient resources to recover k edges of the m edges. Each node has a positive weight. In this situation, we consider which k edges should be fixed in order to maximize the sum of the weights of the nodes reachable from the significant path. In this paper, we formulate such a problem as a combinatorial problem. Further, we show that a part of our problem may be solved by translating it into the terms of the so-called tree knapsack problem. 展开更多
关键词 Network failure GRAPH tree structure combinatorial optimization risk management
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