Various ordered mesoporous carbons (OMCs) have been prepared by evaporation-induced trieonstituent co-assembly method. Their mesostructural stability under different carbon content, aging time and acidity were conve...Various ordered mesoporous carbons (OMCs) have been prepared by evaporation-induced trieonstituent co-assembly method. Their mesostructural stability under different carbon content, aging time and acidity were conveniently monitored by X-ray diffraction, transmission electron microscopy, and N2 sorption isotherms techniques. The results show mesostruetural stability of OMCs is enhanced as the carbon content increases from 36% to 46%, further increasing carbon content deteriorates the mesostructural stability. Increasing aging time from 0.5 h to 5.0 h make the mesostructural stability go through an optimum (2.0 h) and gradually reduce framework shrinkage of the OMCs. Highly OMCs can only be obtained in the acidity range of 0.2-1.2 mol/L HC1, when the acidity is near the isoelectrie point of silica, the resulting OMCs have the best mesostructure stability. Under the optimum condition, the carbon content of 46%, aging time of 2.0 h, and 0.2 mol/L HCl, the resulting OMCs have the best mesostrueture stability and the highest BET surface areas of 2281 m2/g.展开更多
To study the influence of Fe addition on the Al-based amorphous alloys,the structure and properties of Al84Ni10La6 and Al84Ni9Fe1La6 alloys were investigated through various techniques.The results show that 1% Fe(mol...To study the influence of Fe addition on the Al-based amorphous alloys,the structure and properties of Al84Ni10La6 and Al84Ni9Fe1La6 alloys were investigated through various techniques.The results show that 1% Fe(molar fraction) addition increases the area of the pre-peak in the structure factor and decreases the thermal expansion coefficient difference between the crystalline and amorphous states.1% Fe addition also improves the glass forming ability(GFA),micro-hardness,fracture toughness,electric resistivity,absolute diamagnetism and corrosion resistance of Al-Ni-La alloys,which is related to the changes of medium-range order and quench-in free volume caused by 1% Fe addition.展开更多
The paper presented a new regular pattern (network structure ) of great earthquakes occurred in China's Mainland during the past 700 years, which may be helpful to improve the understanding of great earthquakes ...The paper presented a new regular pattern (network structure ) of great earthquakes occurred in China's Mainland during the past 700 years, which may be helpful to improve the understanding of great earthquakes and can serve as a base for the study of prediction of future great earthquakes. It can be done because there are quite complete and confident records of historical and recent earthquakes in a wide extent in China.展开更多
This paper deals with the exact detection analysis of the Ordered-Statistic(OS) processor along with OS Greatest Of(OSGO) and OS Smallest Of(OSSO) modified versions, for M postdetection integrated pulses when the oper...This paper deals with the exact detection analysis of the Ordered-Statistic(OS) processor along with OS Greatest Of(OSGO) and OS Smallest Of(OSSO) modified versions, for M postdetection integrated pulses when the operating environment is nonhomogeneous. Analytical results are presented in multiple-target case as well as in regions of clutter power transitions. The primary and the secondary interfering targets are assumed to be fluctuating in accordance with the SWII target fluctuation model. As the number of noncoherently integrated pulses increases,lower threshold values and consequently better detection performances are obtained in both homogeneous and multiple target background models. However, the false alarm rate performance of OSSO-CFAR(Constant False Alarm Rate) scheme at clutter edges is worsen with increasing the postdetection integrated pulses. As predicted, the OSGO-CFAR detector accommodates the presence of spurious targets in the reference window, given that their number is within its allowable range in each local window, and controls the rate of false alarm when the contents of the reference cells have clutter boundaries.展开更多
We consider the covalence characters of the 3d electron with the eg orbital freedoms and put forward a new mechanism of the orbital ordering (00) based on the direct coulomb repulsion in this article. The results sh...We consider the covalence characters of the 3d electron with the eg orbital freedoms and put forward a new mechanism of the orbital ordering (00) based on the direct coulomb repulsion in this article. The results show that the orbital-orbital interaction (OO-I) between the adjacent ions in 180-degree configuration is dominated by the superexchange energy accompanied by a weak orbital-spin coupling, and the OO-I in 90-degree configuration is monitored by the oxygen on-site coulomb repulsion. The ferro-OO is the stable ground state for the one-dimensional chain in the case of the 90-degree configuration.展开更多
In this paper, an investigation into the propagation of far field explosion waves in water and their effects on nearby structures are carried out. For the far field structure, the motion of the fluid surrounding the s...In this paper, an investigation into the propagation of far field explosion waves in water and their effects on nearby structures are carried out. For the far field structure, the motion of the fluid surrounding the structure may be assumed small, allowing linearization of the governing fluid equations. A complete analysis of the problem must involve simultaneous solution of the dynamic response of the structure and the propagation of explosion wave in the surrounding fluid. In this study, a dynamic adaptive finite element procedure is proposed. Its application to the solution of a 2D fluid-structure interaction is investigated in the time domain. The research includes:a) calculation of the far-field scatter wave due to underwater explosion including solution of the time-depended acoustic wave equation, b) fluid-structure interaction analysis using coupled Euler-Lagrangian approach, and c) adaptive finite element procedures employing error estimates, and re-meshing. The temporal mesh adaptation is achieved by local regeneration of the grid using a time-dependent error indicator based on curvature of pressure function. As a result, the overall response is better predicted by a moving mesh than an equivalent uniform mesh. In addition, the cost of computation for large problems is reduced while the accuracy is improved.展开更多
Self-assembly of colloidal nanocrystals(NCs)into large-scale superlattices with complex and controllable structures has attracted extensive attention due to their collective properties and promising device application...Self-assembly of colloidal nanocrystals(NCs)into large-scale superlattices with complex and controllable structures has attracted extensive attention due to their collective properties and promising device applications.Plasmonic NCs are very popular for long-range ordered superstructures by virtue of their collective nanogaps for electromagnetic field enhancement,in particular bulk-scale single-layer assembly.Large-area two-dimensional(2D)quasinanosheets(QNSs)composed of mono-component Au NCs or multi-component Au@ZnS core-shell hetero-nanocrystals(HNCs)were successfully prepared,via careful solvent evaporation-induced interfacial self-assembly.The entire selfassembly process was carried out on the liquid-air surface and mediated simply by tuning the operating temperatures and concentrations of the NCs.Specifically,monolayer and double-layer 2D QNSs in tens of micrometers scale with different stacking models were fabricated by precisely controlling the solvent evaporation rate and colloidal concentration.展开更多
基金This work was supported by the National Natural Science Foundation of China (No.20872135).
文摘Various ordered mesoporous carbons (OMCs) have been prepared by evaporation-induced trieonstituent co-assembly method. Their mesostructural stability under different carbon content, aging time and acidity were conveniently monitored by X-ray diffraction, transmission electron microscopy, and N2 sorption isotherms techniques. The results show mesostruetural stability of OMCs is enhanced as the carbon content increases from 36% to 46%, further increasing carbon content deteriorates the mesostructural stability. Increasing aging time from 0.5 h to 5.0 h make the mesostructural stability go through an optimum (2.0 h) and gradually reduce framework shrinkage of the OMCs. Highly OMCs can only be obtained in the acidity range of 0.2-1.2 mol/L HC1, when the acidity is near the isoelectrie point of silica, the resulting OMCs have the best mesostructure stability. Under the optimum condition, the carbon content of 46%, aging time of 2.0 h, and 0.2 mol/L HCl, the resulting OMCs have the best mesostrueture stability and the highest BET surface areas of 2281 m2/g.
基金Projects(50871061,50871062,50831003 and 50631010)supported by the National Natural Science Foundation of ChinaProject(2008BS04020)supported by the Excellent Youth Science and Technology Award of Shandong Province,China+2 种基金Project(NCET-06-584)supported by the New Century Talents Program of the Ministry of Education,ChinaProject(2007CB613901)supported by the National Basic Research Program of ChinaProject(LZUMMM2010008)supported by Open Project of Key Laboratory for Magnetism Materials of the Ministry of Education,China
文摘To study the influence of Fe addition on the Al-based amorphous alloys,the structure and properties of Al84Ni10La6 and Al84Ni9Fe1La6 alloys were investigated through various techniques.The results show that 1% Fe(molar fraction) addition increases the area of the pre-peak in the structure factor and decreases the thermal expansion coefficient difference between the crystalline and amorphous states.1% Fe addition also improves the glass forming ability(GFA),micro-hardness,fracture toughness,electric resistivity,absolute diamagnetism and corrosion resistance of Al-Ni-La alloys,which is related to the changes of medium-range order and quench-in free volume caused by 1% Fe addition.
基金The Central Level,Scientific Research Institutes for Basic R & D Special Fund Business (No.2060302)National Natural Science Foundation of China(No.40841016,No.40372131 and No.40702056)Old Experts Science Foundation of China Earthquake Administration(No.201039)
文摘The paper presented a new regular pattern (network structure ) of great earthquakes occurred in China's Mainland during the past 700 years, which may be helpful to improve the understanding of great earthquakes and can serve as a base for the study of prediction of future great earthquakes. It can be done because there are quite complete and confident records of historical and recent earthquakes in a wide extent in China.
文摘This paper deals with the exact detection analysis of the Ordered-Statistic(OS) processor along with OS Greatest Of(OSGO) and OS Smallest Of(OSSO) modified versions, for M postdetection integrated pulses when the operating environment is nonhomogeneous. Analytical results are presented in multiple-target case as well as in regions of clutter power transitions. The primary and the secondary interfering targets are assumed to be fluctuating in accordance with the SWII target fluctuation model. As the number of noncoherently integrated pulses increases,lower threshold values and consequently better detection performances are obtained in both homogeneous and multiple target background models. However, the false alarm rate performance of OSSO-CFAR(Constant False Alarm Rate) scheme at clutter edges is worsen with increasing the postdetection integrated pulses. As predicted, the OSGO-CFAR detector accommodates the presence of spurious targets in the reference window, given that their number is within its allowable range in each local window, and controls the rate of false alarm when the contents of the reference cells have clutter boundaries.
文摘We consider the covalence characters of the 3d electron with the eg orbital freedoms and put forward a new mechanism of the orbital ordering (00) based on the direct coulomb repulsion in this article. The results show that the orbital-orbital interaction (OO-I) between the adjacent ions in 180-degree configuration is dominated by the superexchange energy accompanied by a weak orbital-spin coupling, and the OO-I in 90-degree configuration is monitored by the oxygen on-site coulomb repulsion. The ferro-OO is the stable ground state for the one-dimensional chain in the case of the 90-degree configuration.
文摘In this paper, an investigation into the propagation of far field explosion waves in water and their effects on nearby structures are carried out. For the far field structure, the motion of the fluid surrounding the structure may be assumed small, allowing linearization of the governing fluid equations. A complete analysis of the problem must involve simultaneous solution of the dynamic response of the structure and the propagation of explosion wave in the surrounding fluid. In this study, a dynamic adaptive finite element procedure is proposed. Its application to the solution of a 2D fluid-structure interaction is investigated in the time domain. The research includes:a) calculation of the far-field scatter wave due to underwater explosion including solution of the time-depended acoustic wave equation, b) fluid-structure interaction analysis using coupled Euler-Lagrangian approach, and c) adaptive finite element procedures employing error estimates, and re-meshing. The temporal mesh adaptation is achieved by local regeneration of the grid using a time-dependent error indicator based on curvature of pressure function. As a result, the overall response is better predicted by a moving mesh than an equivalent uniform mesh. In addition, the cost of computation for large problems is reduced while the accuracy is improved.
基金supported by the National Natural Science Foundation of China(NSFC,51872030,51631001,21801015,21643003,51702016,51501010 and 21703219)the Fundamental Research Funds for the Central Universities+1 种基金Beijing Institute of Technology Research Fund Program for Young ScholarsJoint R&D Plan of HongKong,Macao,Taiwan and Beijing(Z191100001619002)。
文摘Self-assembly of colloidal nanocrystals(NCs)into large-scale superlattices with complex and controllable structures has attracted extensive attention due to their collective properties and promising device applications.Plasmonic NCs are very popular for long-range ordered superstructures by virtue of their collective nanogaps for electromagnetic field enhancement,in particular bulk-scale single-layer assembly.Large-area two-dimensional(2D)quasinanosheets(QNSs)composed of mono-component Au NCs or multi-component Au@ZnS core-shell hetero-nanocrystals(HNCs)were successfully prepared,via careful solvent evaporation-induced interfacial self-assembly.The entire selfassembly process was carried out on the liquid-air surface and mediated simply by tuning the operating temperatures and concentrations of the NCs.Specifically,monolayer and double-layer 2D QNSs in tens of micrometers scale with different stacking models were fabricated by precisely controlling the solvent evaporation rate and colloidal concentration.