石墨烯含量对铜铁基自润滑摩擦材料组织结构及摩擦性能的影响

目的改善石墨烯与铜铁基摩擦材料的结合方式,探究不同含量的石墨烯对铜铁基摩擦材料组织结构的影响,研究加入不同含量石墨烯时摩擦材料的摩擦性能和摩擦机理。方法采用粉末冶金冷压法制备铜铁基摩擦材料,利用SEM、XRD等分析方法和手段,探究不同含量石墨烯对摩擦材料的组织结构、综合力学性能和摩擦性能的影响规律,确定最佳工艺参数。结果在铜铁基摩擦材料中加入石墨烯时,其密度和抗压强度随着石墨烯含量的增加呈下降趋势,硬度呈先上升后降低的趋势。在相同转速下,随着石墨烯含量的增加,其摩擦材料的摩擦因数呈下降趋势,磨损率呈现先下降后上升的趋势。在石墨烯的质量分数为0.5%时,摩擦材料的摩擦率最小,为2.52×10^(-9)mm^(3)/(N·m),此时摩擦材料的磨损机理为黏着磨损及少量磨粒磨损。结论在铜铁基摩擦材料中,石墨烯作为润滑组元,与基体的结合性能表现优异,对比石墨烯对铜铁基摩擦材料的影响规律可知,在石墨烯的质量分数为0.5%时,摩擦材料的性能最佳。

自润滑摩擦对材料表层和亚表层位错密度的影响

利用ＴＥＭ 研究了自润滑摩擦对材料位错密度的影响，结果表明，在自润滑稳态摩擦时，可忽略摩擦对材料表层和亚表层位错密度的影响；位于自润滑失稳向干摩擦过渡阶段时，材料摩擦表层和次表层的位错密度将会提高。

核主泵推力轴承自润滑摩擦副研究

本文介绍了一种适用于核主泵油润滑推力轴承的自润滑摩擦副,由碳纤维增强复合材料和硬质合金构成。对摩擦副材料进行了摩擦磨损和机械性能试验研究,研究显示摩擦副具有较低的摩擦系数和比磨损率,可承受高温和高剂量辐照。开展新摩擦副的高载荷推力轴承台架试验,试验结果显示自润滑摩擦副在无高压油顶起和无冷油循环时具有较好的耐磨性。新方案可以降低轴封式核主泵全厂断电工况下主推力瓦磨损和一回路系统压力低工况下副推力瓦磨损,降低启停时高压油顶起系统对交流电源依赖,提高设备可靠性。

陶瓷及其复合材料高温自润滑的研究现状

本文就固态润滑组元性质、与陶瓷基体界面特性以及摩擦化学反应膜层等几方面因素对陶瓷自润滑效应的影响，简要介绍了当前自润滑金属陶瓷材料、自润滑陶瓷复合材料和结构陶瓷自身润滑功效的一些研究情况。总结了自润滑陶瓷材料研究中存在的不足，并提出了今后研究应注意的问题。

Preparation and tribological performances of Ni-P-multi-walled carbon nanotubes composite coatings

Multi-walled carbon nanotubes （MWNTs） were wet-milled in the presence of ammonia and cationic surfactant and then used as reinforcements to prepare Ni-P-MWNTs composite coatings by electroless plating. The tribological performances of the composite coatings under dry condition were investigated in comparison with 45 steel and conventional Ni-P coating, Micrographs show that short MWNTs with uniform length and open tips were obtained through the wet-milling process. The results of wear test reveal that the Ni-P-MWNTs composite coatings posses much better friction reduction and anti-wear performances when compared with 45 steel and Ni-P coating. Within the MWNTs content range of 0.74%-1.97%, the friction coefficient and the volume wear rate of the composite coatings decrease gradually and reach the minimum values of 0.08 and 6.22x10-15 m3/（N.m）, respectively. The excellent tribological performances of the composite coatings can be attributed to the introduction of MWNTs, which play both roles of reinforcements and solid lubricant during the wear process.

Effect of wear conditions on tribological properties of electrolessly-deposited Ni-P-Gr-SiC hybrid composite coating

The friction and wear properties of the electrolessly-deposited Ni-P-Gr-SiC composites were investigated. The effects of graphite content, load and rotation speed on the friction coefficient and wear resistance of the composite coatings were mainly investigated. The worn surface and cross section of the coatings were characterized by scanning electron microscopy and energy-dispersive X-ray analysis. The results show that the composite coatings reveal good antifriction and wear resistance due to the synergic effect of graphite and SiC particles. The formation of graphite-rich mechanically mixed layer （GRMML） on the surface of Ni-P-Gr-SiC coating contributes to the good tribological behavior of the wear counterparts and SiC particles play a load bearing role in protecting GRMML from shearing easily.

核主泵无顶油惰转推力轴承磨损研究

本文介绍了核主泵在无高压油顶起推力轴承推力瓦的工况下,惰转停机过程推力轴承的磨损规律研究。基于雷诺方程分析,推力轴承流体动压润滑的油膜压力及油膜厚度变化规律,惰转停机过程分为流体动压润滑阶段、不连续流体动压润滑阶段和边界润滑阶段。核电厂全厂断电(SBO)工况下,核主泵无高压油轴承顶起系统对于选用传统的金属材料摩擦副推力轴承会有较大磨损概率,因此应采取必要措施确保核电站的运行经济性和可靠性。本文提出了轴封式核主泵用油润滑双向推力轴承所采用的新型自润滑复合材料摩擦副,从根本上解决SBO工况下推力轴承摩擦副的磨损,停机后可以再次启动核主泵并稳定运行。

Effects of environment on dry sliding wear behavior of silver-copper based composites containing tungsten disulfide

Silver based composites containing different amounts of WS2were prepared by hot-pressing method and their tribologicalbehaviors were investigated against coin silver under humid air,dry nitrogen and vacuum on a ball-on-disk tester with normal load of5N.The components of composites,microstructure of debris and worn surface were characterized using XRD SEM,EDS and XPS.It is demonstrated that environmental conditions significantly affect the tribological behavior of silver based composites.The frictioncoefficient is the highest in humid air,and the lowest in dry nitrogen.It is found that the friction and wear behavior of the compositesare strongly depended on the characteristics of the lubrication film forming in different operating environments,such as thicknessand composition.In addition,it is indicated that the dominant wear mechanisms of silver based composites are abrasive wear anddelamination under different conditions.

Tribological behavior of Cu-15Ni-8Sn/graphite under sea water, distilled water and dry-sliding conditions

The tribological behaviors of Cu-15Ni-8Sn/graphite composites with the graphite content of 38 vol.%against AISI321 stainless steel under dry-sliding,deionized water and sea water were investigated on a block-on-ring configuration.The results indicated that the friction coefficient was the lowest under dry-sliding,and the highest in deionized water.The wear rate decreased to reach the minimum value of 1.39×10-15 m3/(N·m)in sea water and in deionized water,it increased to the maximum value of 5.56×10-15 m3/(N·m).The deionized water hindered the formation of tribo-oxide layer and lubricating film,which resulted in the largest friction coefficient and wear rate.In sea water,however,the corrosion products comprised of oxides,hydroxides and chlorides were found on the worn surface,and the compacted layer composed of corrosion products and graphite played an important role in keeping the excellent wear resistance.It was elucidated that the tribological behaviors of Cu-15Ni-8Sn/graphite composite were powerful influenced by the friction environments.

Effects of copper-coated MoS_(2) on friction performance of bronze-graphite-MoS_(2) self-lubricating materials

Two kinds of bronze-graphite-MoS_(2) self-lubricating materials with copper-coated MoS_(2) and uncoated MoS_(2) were prepared by powder metallurgy.Friction and wear experiments were carried out under 4 N and 10 N loads respectively,and the effects of copper-coated MoS_(2) on the friction performances of the materials were studied.Results showed that the way of copper-coated on the surface of MoS_(2) could reinforce the bonding between MoS_(2) and matrix,and inhibited the formation of MoO_(2).Moreover,both materials formed a MoS_(2) lubricating film on the surface during the friction process.While the lubricating film formed after copper coating on MoS_(2) was thicker and had uneven morphology,it was more conducive to improving the friction performance of the material.Compared with conventional materials,the wear rate of copper-coated materials was reduced by one order of magnitude,and the friction coefficient was also reduced by 22.44% and 22.53%,respectively,when sliding under 4 N and 10 N loads.It shows that copper-coated MoS_(2)can improve friction properties of bronze-graphite-MoS_(2)self-lubricating materials furtherly.

Tribological properties of nano-porous anodic aluminum oxide template

A highly ordered porous alumina template with pores of 45 nm in diameter was synthesized by a two-step electrochemical anodizing process. The influence of pore-enlargement treatment on the porous structure and tribological properties of the film was investigated, and ultrasonic impregnation technology was applied on it to form self-lubricating surface. The structure of the self-lubricating film and its tribological properties were investigated in detail. It can be concluded that the optimum time of pore-enlargement treatment is 20 min. The diameter of the pores and the surface porosity of the film are about 70 nm and 30%, respectively, while the film maintains the property of its high hardness. Under the same friction condition, the frictional coefficient of the self-lubricating film is 0. 18, much lower than that of the anodic aluminum oxide template, which is 0.52. In comparison with the lubricating surface of non-porous dense anodic aluminum oxide template, the lubricating surface fabricated by the ultrasonic impregnation method on the porous anodic aluminum oxide template keeps longer period with low friction coefficient. SEM examination shows that some C60 particles have been embedded in ultrasonic impregnation technology. the nanoholes of the anodic aluminum oxide template by the

载荷对PTFE/AlSi10Mg复合材料摩擦磨损行为的影响

采用选区激光熔化(SLM)、浸渗和真空烧结工艺制备了以AlSi10Mg为基体的多孔骨架填充聚四氟乙烯(PTFE)的自润滑复合材料。采用往复式Bruker UMT-3摩擦试验机研究了速度为5mm/s、不同载荷下复合材料的摩擦磨损性能,并采用SEM、EDS等对其成分、结构以及摩擦学行为进行了研究。结果表明,复合材料的平均摩擦因数和磨损率随着载荷的增加呈现先增大后减小的趋势;复合材料的摩擦稳定性主要由存储在骨架中的PTFE决定。其摩擦机制主要是在载荷的作用下,当磨擦表面发生磨损时,骨架中的PTFE将磨屑捕获,形成完整的PTFE润滑层,并且发生膜的转移,从而增加了复合材料的摩擦学稳定性。