自热法快速测定化学需氧量

介绍无需加热回流测定化学需氧量ＣＯＤ的快速测定法。该法取样量少、简便、安全。

“自热法”快速测定砼强度的测试技术研究

抗压强度是混凝土质量评定与控制的重要指标之一。本研究利用水泥自身的水化对砼进行加速养护,通过测定砼24h的抗压强度来推测标准养护28d的砼抗压强度。

加压中和-喷雾自热法干燥粉状磷酸一铵抗结块方法的研究与应用

国内采用浓缩磷酸法生产的粉状磷酸一铵普遍存在结块缺陷，云南三环化工有限公司通过技术攻关解决了此问题。文章对粉状磷酸一铵结块的原因进行了分析，介绍了试验研究情况，解决结块的方法和运用到工业生产后取得的效果。

温度传感器响应时间测量装置的设计与实现

目前,国内对温度传感器响应时间的测试通常采用浸入式方法在实验室中进行离线测量,实验室环境无法完全模拟现场使用环境,很难反映传感器在实际运行工况下响应时间的变化,同时非美标核电机组保护系统响应时间测试暂未考虑就地传感器响应时间的影响。基于LCSR法和自热法设计研发了温度传感器响应时间测量装置,该装置考虑了安装和工艺条件对响应时间的影响,根据传感器的温度瞬态,计算其在役期间实际运行条件下的响应时间。试验结果表明,该装置测量出的响应时间符合NB/T20338-2015标准,为后续非美标核电机组温度传感器响应时间测量的现场应用奠定了基础。

Apparent activation energy for spontaneous combustion of sulfide concentrates in storage yard

In order to evaluate the spontaneous combustion hazard of sulfide concentrates in storage, three different kinds of sulfide concentrates （sulfur-rich sulfide concentrate, iron sulfide concentrate and copper sulfide concentrate） were obtained from a storage yard in Dongguashan Copper Mine, China. The reaction processes at different heating rates of 5, 10, 15, 20, and 25 ℃/min in air flow from ambient temperature to 1 000 ℃ were studied by TG-DTG-DSC analysis. By the peak temperatures of DTG curves, the whole reaction process for each sample was divided into different stages, and the corresponding apparent activation energies were calculated by the Ozawa-Flynn-Wall method. It is found that the reaction process of each sample is considerably complex; the apparent activation energy values change from 36 to 160 kJ/mol in different temperature ranges; sulfur-rich sulfide and iron sulfide concentrates have lower apparent activation energy than copper sulfide concentrate below 150 ℃; so they are more inclined to cause spontaneous combustion at ambient temperature.

托普索天然气大型甲醇厂工艺技术的选择

介绍了大型甲醇厂转化、甲醇合成、甲醇精馏工艺技术的特点 ,针对转化工艺技术的选择 ,对一段转化法、二段转化法和自热转化法进行了论述 ,从投资、操作性能、生产规模、经济效益等方面对上述 3种方法进行了对比。讨论了单系列甲醇装置的最大规模问题 ,结论认为 ,采用二段转化法和自热转化法的最大系列规模分别是采用一段转化法的 2倍和 4倍。

天然气制合成油的技术经济分析

天然气制合成油 (GTL)最近几年一直是业内广为关注的焦点 ,文章对世界各大石油公司的GTL技术进行了比较分析 ,从技术经济角度论证了现阶段建设相应规模GTL装置的可行性。

Study on the automatic process of line heating for pillow shape plate

This paper focuses on the process for pillow shape plate by line heating technique, which is widely applied in the production of ship hull. Based on the analysis of primary parameters and experimental data in line heating process, the amount of local contraction generated by line heating has been illustrated. Then, combining with the computational result of local deformation determined by shell plate development, an optimization method for line heating parameters has been studied. This prediction system may provide rational arrangements of heating lines and technical parameters of process. By integrating the prediction system into the line heating robot for pillow shape plate, the automatic process of line heating for pillow shape plate can be achieved.

Hierarchically skeletal multi-layered Pt-Ni nanocrystals for highly efficient oxygen reduction and methanol oxidation reactions

Pt based materials are the most efficient electrocatalysts for the oxygen reduction reaction(ORR)and methanol oxidation reaction(MOR)in fuel cells.Maximizing the utilization of Pt based materials by modulating their morphologies to expose more active sites is a fundamental objective for the practical application of fuel cells.Herein,we report a new class of hierarchically skeletal Pt-Ni nanocrystals(HSNs)with a multi-layered structure,prepared by an inorganic acid-induced solvothermal method.The addition of H_(2)SO_(4)to the synthetic protocol provides a critical trigger for the successful growth of Pt-Ni nanocrystals with the desired structure.The Pt-Ni HSNs synthesized by this method exhibit enhanced mass activity of 1.25 A mgpt−1 at 0.9 V(versus the reversible hydrogen electrode)towards ORR in 0.1-M HClO_(4),which is superior to that of Pt-Ni multi-branched nanocrystals obtained by the same method in the absence of inorganic acid;it is additionally 8.9-fold higher than that of the commercial Pt/C catalyst.Meanwhile,it displays enhanced stability,with only 21.6%mass activity loss after 10,000 cycles(0.6–1.0 V)for ORR.Furthermore,the Pt-Ni HSNs show enhanced activity and anti-toxic ability in CO for MOR.The superb activity of the Pt-Ni HSNs for ORR and MOR is fully attributed to an extensively exposed electrochemical surface area and high intrinsic activity,induced by strain effects,provided by the unique hierarchically skeletal alloy structure.The novel open and hierarchical structure of Pt-Ni alloy provides a promising approach for significant improvements of the activity of Pt based alloy electrocatalysts.

评用炼厂干气取代轻油制氢制氨

介绍国内外用炼厂干气制氢、制氨概况，对３种炼厂干气加氢流程进行比较，讨论用炼厂干气取代石脑油作为合成氨原料时，对后面工序的影响。

前苏联有色冶金工业节能述评

评述了解体前苏联有色冶金工业的节能状况,采用的冶炼新工艺、应用富氧热风,利用余热、改变能源结构等措施,以及收到的节能效果。

Effects of pyrite on the spontaneous combustion of coal

Abstract Pyrite has a significant effect on the spontaneous combustion of coal. The presence of pyrite can change the propensity of coal towards spontaneous combustion. The influences of various pyrite contents on the parameters of spontaneous combustion, such as index gases, temperature and released heat etc., were investigated in this study, Coal samples with different pyrite contents （0 %, 3 %, 5 %, 7 % and 9 %） were made by mixing coal and pyrite. The oxidation experiments under temperature-programmed condition were carried out to test the release rate of gaseous oxidation products at different temperatures. Differential scanning calorimeter （DSC） was employed to measure the intensity of heat release during coal oxidation for various pyrite contents. The results indicate that pyrite can nonlinearly accelerate the process of spontaneous combustion. The coal sample with a pyrite content of 5 % has the largest CO release rate and oxygen adsorption as well. However, the coal sample with a pyrite content of ？ % has the largest rate of heat flow according to the results from the DSC tests. Pyrite contents of 5 %-7 % in coal has the most significant effects on spontaneous combustion within the range of this study. The conclusions are conducive to the evaluation and control for the spontaneous combustion of coal.

Analysis of the Influence of Different Drying Methods on the Active Ingredients of Fresh Medicine

The heating area of the material is large and the thermal efficiency is high,but it is n ecessary to control the suitable drying temperature ofdiffere nt medici nal materials to preserve the effective in gredients.D iff ere nt kinds of Chinese medicine need different drying conditions to fulfill good drying requirements.Natural drying in the shade is one of the traditional drying methods,which takes a long time and is easily affected by the weather.The water volatilizes slowly.It is prone to mildew and discoloration during the drying process.However,it can better preserve the volatile oil components of Chinese medicine.The hot-air drying machine has lower requirements.The medicinal materials have a large heating area and high thermal efficiency,but it is necessary to control the appropriate drying temperature of different medicinal materials in order to preserve the active ingredients of the medicinal materials;it is not suitable for medicinal materials that stick and bind easily.The microwave drying method possesses superiority in drying some valuable medicinal materials such as Ren she n(Radix et Rhizoma Ginseng)and Lurong(Co「nu Cervi Pantotrichum),and the effective ingredients are preserved at a high degree;it can also achieve the purpose of killing enzymes and protecting glycosides and have a good bactericidal effect,but it is not suitable for Chinese medicines containing heat-sensitive ingredients,because it will destroy most of the proteins,amino acids,and peptides of Chinese medicine and result in the loss of efficacy.The far-infrared drying method is suitable for drying thin-layer medicinal materials and is friendly to the environment.Freeze-drying can preserve the active ingredients very well and greatly retain the efficacy,but it has obvious limitations in preserving some Chinese medicinal materials that need to kill enzymes and protect glycosides;besides,the cost is relatively high and the drying time is long.

Simulation of Spin-3/2 Blume-Capel Model on a Cellular Automaton with Heating and Cooling Algorithm

The spin-3/2 B1ume-Capel model is studied using the heating and cooling algorithms improved from the Creutz cellular automaton （CCA）. The calculations are done on various sizes of the simple cubic lattice in the 0 ≤ D/J ≤ 5 parameter region. The phase diagram of the model and temperature variation of the thermodynamic quantities are obtained. We confirm the existence of a critical end point within the heating calculations. However, in contrast to the heating calculations, we do not obtain the first-order line at low temperature with cooling algorithm calculations. The results are compared with those of other theories.

Evaluation on the Thermal Stability and Hazards Behaviors of ADVN Using Green Thermal Analysis Approach

ADVN （2,2＇-Azobis （2,4-dimethyl） valeronitrile）, a free radical initiator, is widely applied for the polymerization reaction of polymers in the chemical industries. When ADVN releases free radical during the decomposition process, it can accompany abundant heat and huge pressure to increase the possibility of thermal runaway and hazard, causing unacceptable thermal explosion or fire accidents. To develop an inherently safer process for ADVN, the thermal stability parameters of ADVN were obtained to investigate thermal decomposition characteristics using a DSC （differential scanning calorimetry） and TG （thermogravimetry）. We used various kinetic models to completely depict the kinetic behavior and determine the thermal safety parameters for ADVN. The green thermal analysis approach could be used to substitute for complicated procedures and large-scale experiments of traditional thermal analysis methods, avoiding environmental pollution and energy depletion.

Structure characterization,magnetic and photoluminescence properties of Mn doped ZnS nanocrystalline

Wurzite ZnS:Mn nanorods are synthesized via a solvothermal method by using ethylenediamine and water as mixed solvent.The diameters of the nanorods increase and the lengths decrease with the Mn concentration.High resolution transmission electron microscopic images illustrate that a few cubic ZnS:Mn nanoparticles arise along with hexagonal nanorods on high Mn concentration.The samples set off yellow-orange emission at 590 nm,characteristic of 4 T→ 6 A 1 transition of Mn 2+ at T d symmetry in ZnS.Electron spin resonance spectrum of the nanorods shows that high Mn concentrations produce a broad envelope,whereas six-line hyperfine appears for lower Mn concentrations.These results together with the magnetization curves indicate that all the ZnS:Mn samples are paramagnetic even down to 4 K,which suggests that the ZnS:Mn is not suitable for dilute magnetic semiconductor.

Thermo-fluidic characteristics of natural convection in honeycombs:The role of chimney enhancement

The natural convective heat transfer performance and thermo-fluidic characteristics of honeycombs with/without chimney extensions are numerically investigated.The present numerical simulations are validated by the purposely-designed experimental measurements on honeycombs with/without chimney.Good agreement between numerical simulation and experimental measurement is obtained.The influences of inclination angle and geometric parameters such as cell shape,streamwise and spanwise length are also numerically quantified.With the increment in inclination angle,the overall heat transfer rate decreases for the honeycombs with/without chimney.For honeycombs with the same void volume fraction but different cell shapes,there is little difference on the overall heat transfer rate.To enhance the natural convective heat transfer of honeycombs,these techniques including increasing the length of honeycomb in the streamwise/spanwise direction,increasing the thermal conductivity of hon-eycomb structure or adding a chimney extension may be helpful.

Isothermal crystallization of polypropylene/surface modified silica nanocomposites

In the present work, 3-methacryloxypropyltrimethoxy-silane silanized silica （SiO2-WD70） and 9,10-dihydro-9-oxa-10-phospha- phenanthrene-10-oxide immobilized silica （SiO2-WD70-DOPO） nanoparticles were prepared. Silica, SiO2-WD70 and SiO2- WD70-DOPO were incorporated into polypropylene （PP） by melt compounding. Differential scanning calorimetry （DSC）, X-ray diffraction （XRD） and polarized optical microscopy （POM） were employed to investigate the isothermal crystallization behavior of PP and PP/silica composites. The kinetic constant （kn）, and half crystallization time （t1/2） were calculated by Avrami equation, while the surface free energy of folding was calculated by Lauritzen-Hoffman theory. The increased k,, decreased t1/2 and the surface free energy （ere） in the order ofPP, PP/SiO2, PP/SiO2-WD70 and PP/SiO2-WD70-DOPO nanocomposites were attributed to the surface modification of silica. XRD indicated that SiO2-WD70-DOPO addition had no effect on PP crystal structure but accelerated the crystallization rate. POM determined that SiO2-WD70-DOPO addition promoted the nucleation of PP by inducing a higher nucleation density during isothermal conditions. The surface modified nanoparticle SiO2-WD70-DOPO might find possible application as a new type of inorganic nano-sized nucleation agent for PP.