The issues of reducing CO_2 emissions, sustainably utilizing natural mineral resources, and dealing with industrial waste offer challenges for sustainable development in energy and the environment. We propose an effic...The issues of reducing CO_2 emissions, sustainably utilizing natural mineral resources, and dealing with industrial waste offer challenges for sustainable development in energy and the environment. We propose an efficient methodology via the co-reaction of K-feldspar and phosphogypsum for the extraction of soluble potassium salts and recovery of SO_2 with reduced CO_2 emission and energy consumption. The results of characterization and reactivity evaluation indicated that the partial melting of K-feldspar and phosphogypsum in the hightemperature co-reaction significantly facilitated the reduction of phosphogypsum to SO_2 and the exchange of K^+(K-feldspar) with Ca^(2+)(CaSO_4 in phosphogypsum). The reaction parameters were systematically investigated with the highest sulfur recovery ratio of ~ 60% and K extraction ratio of ~ 87.7%. This novel methodology possesses an energy consumption reduction of ~ 28% and CO_2 emission reduction of ~ 55% comparing with the present typical commercial technologies for utilization of K-feldspar and the treatment of phosphogypsum.展开更多
The development of waste management can be considered in some way dictates of time. Ukraine has unique conditions of the secondary usage of natural resources, which is particularly important given to the increasing ge...The development of waste management can be considered in some way dictates of time. Ukraine has unique conditions of the secondary usage of natural resources, which is particularly important given to the increasing generation of waste and its progressive accumulation. The relevant provisions relate to the industrial sector as well as areas of consumption. However, for most of recyclable materials is still low. The formation of market relations in Ukraine contributed to enhance this process and relevant field of entrepreneurship. Now the formation of a separate segment is taking place. The state and the perspectives of the development of collection, accumulation and recycling of waste stream have been analyzed in the article. Conceptual position of the legislative regulation of this field is defined. The ways of improving the legal support of secondary raw materials have been defined. The peculiarities of waste management of Ukraine are considered.展开更多
基金Supported by the National Natural Science Foundation of China(21336004)the State Key Research Plan of the Ministry of Science and Technology(2013BAC12B03)
文摘The issues of reducing CO_2 emissions, sustainably utilizing natural mineral resources, and dealing with industrial waste offer challenges for sustainable development in energy and the environment. We propose an efficient methodology via the co-reaction of K-feldspar and phosphogypsum for the extraction of soluble potassium salts and recovery of SO_2 with reduced CO_2 emission and energy consumption. The results of characterization and reactivity evaluation indicated that the partial melting of K-feldspar and phosphogypsum in the hightemperature co-reaction significantly facilitated the reduction of phosphogypsum to SO_2 and the exchange of K^+(K-feldspar) with Ca^(2+)(CaSO_4 in phosphogypsum). The reaction parameters were systematically investigated with the highest sulfur recovery ratio of ~ 60% and K extraction ratio of ~ 87.7%. This novel methodology possesses an energy consumption reduction of ~ 28% and CO_2 emission reduction of ~ 55% comparing with the present typical commercial technologies for utilization of K-feldspar and the treatment of phosphogypsum.
文摘The development of waste management can be considered in some way dictates of time. Ukraine has unique conditions of the secondary usage of natural resources, which is particularly important given to the increasing generation of waste and its progressive accumulation. The relevant provisions relate to the industrial sector as well as areas of consumption. However, for most of recyclable materials is still low. The formation of market relations in Ukraine contributed to enhance this process and relevant field of entrepreneurship. Now the formation of a separate segment is taking place. The state and the perspectives of the development of collection, accumulation and recycling of waste stream have been analyzed in the article. Conceptual position of the legislative regulation of this field is defined. The ways of improving the legal support of secondary raw materials have been defined. The peculiarities of waste management of Ukraine are considered.
