Photodissociation of H2S in the VUV region plays an important role in the atmospheric chemistry and interstellar chemistry.To date,however,few studies have been focused on this topic.In this article,we have described ...Photodissociation of H2S in the VUV region plays an important role in the atmospheric chemistry and interstellar chemistry.To date,however,few studies have been focused on this topic.In this article,we have described a laser dispersion method applied in the apparatus combining the high-n H atom Rydberg tagging time-of-flight technique with the vacuum ultraviolet free electron laser(VUV FEL).The Lyman-αlaser beam(121.6 nm)used in the H-atom detection was generated by the difference frequency four-wave mixing schemes in a Kr/Ar gas cell.After passing through an off-axis biconvex LiF lens,the 121.6 nm beam was dispersed from the 212.6 nm and 845 nm beams due to the different deflection angles experienced by these laser beams at the surfaces of the biconvex lens.This method can eliminate the background signal from the 212.6 nm photolysis.Combined with the VUV FEL,photodissociation of H2S at 122.95 nm was studied successfully.The TOF spectrum was measured and the derived total kinetic energy release spectrum was displayed.The results suggest that the experimental setup is a powerful tool for investigating photodissociation dynamics of molecules in the VUV region which involves the H-atom elimination processes.展开更多
Spectroscopic characterization of clusters is crucial to understanding the structures and reaction mechanisms at the microscopic level,but it has been proven to be a grand challenge for neutral clusters because the ab...Spectroscopic characterization of clusters is crucial to understanding the structures and reaction mechanisms at the microscopic level,but it has been proven to be a grand challenge for neutral clusters because the absence of a charge makes it di伍cult for the size selection and detection.Infrared(IR)spectroscopy based on threshold photoionization using a tunable vacuum ultraviolet free electron laser(VUV-FEL)has recently been developed in the lab.The IR-VUV depletion and IR+VUV enhancement spectroscopic techniques open new avenues for size-selected IR spectroscopies of a large variety of neutral clusters without confinement(i.e.,an ultraviolet chromophore,a messenger tag,or a host matrix).The spectroscopic principles have been demonstrated by investigations of some neutral water clusters and some metal carbonyls.Here,the spectroscopic principles and their applications for neutral clusters are reviewed.展开更多
The LCLS-II (linac coherent light source II) will build on the success of the world's most powerful X-ray laser: the LCLS (linac coherent light source). It will add two new X-ray laser beams and room for additio...The LCLS-II (linac coherent light source II) will build on the success of the world's most powerful X-ray laser: the LCLS (linac coherent light source). It will add two new X-ray laser beams and room for additional new instruments, thus greatly increasing the number of experiments carried out each year. Multiple operation modes are proposed to accommodate a variety of user requirements. There are a large number of variables and objectives in the design. For each operation mode, MOGA (multi-objective genetic algorithm) is applied to optimize the machine parameters in order to minimize the jitters, energy spread, collective effects and emittance.展开更多
With the stat-of-the-art laser technique, the quality of electron beam generated from LPA (laser-plasma accelerator) is now becoming much better. The natural merits of electron beam from LPA, e.g., high peak current...With the stat-of-the-art laser technique, the quality of electron beam generated from LPA (laser-plasma accelerator) is now becoming much better. The natural merits of electron beam from LPA, e.g., high peak current, ultra-low emittance and ultra-short bunch length, etc., pave the way to the novel light sources, especially in the realm of developing much more compact x-ray light sources, e.g., table-top XFEL (x-ray free-electron laser). However, the radiation power is limited by the rather larger energy spread than conventional radio-frequency electron LINAC (linear accelerator). Luckily, much more power could be extracted by using the undulator with transverse gradient when energy spread effect could be compensated. In this paper, we introduce a novel soit x-ray light source driven by LPA together with TGU (transverse gradient undulator) technique, meanwhile we present a simple idea on how to achieve much higher rep-rate (e.g., -100 kHz) FELs (free-electron lasers) boosted by TGU based on storage rings.展开更多
The echo-enabled harmonic generation (EEHG) scheme holds promising prospects for efficiently generat- ing intense coherent radiation at very high harmonics of the initial seed laser. In this paper, we study the feas...The echo-enabled harmonic generation (EEHG) scheme holds promising prospects for efficiently generat- ing intense coherent radiation at very high harmonics of the initial seed laser. In this paper, we study the feasibility of operating the Shanghai X-ray free-electron laser test facility with a single stage EEHG setup. With a combina- tion of existing numerical codes, start-to-end simulations considering various three-dimensional effects have been carried out to show the possible performance of the EEHG FEL. Simulation results demonstrate that a single stage EEHG can generate high power soft X-ray radiation pulses with narrow bandwidth directly from UV seed lasers. With the help of the harmonic lasing technique or upgraded linac, we also show the possibility of generating coherent soft X-ray radiation in the "water window" with a single stage EEHG.展开更多
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences (No.XDB17000000)the National Natural Science Foundation of China (NSFC Center for Chemical Dynamics (No.21688102)+4 种基金the National Natural Science Foundation of China (No.21673232, No.21873099, No.21922306)the International Partnership Program of Chinese Academy of Sci-ences (No.121421KYSB20170012)supported by the National Natural Science Foundation of China (No.21973010)supported by the National Natural Science Foundation of China (No.21773236)supported by the Natural Science Research Project of Education Department of Anhui Province (No.KJ2019A0521).
文摘Photodissociation of H2S in the VUV region plays an important role in the atmospheric chemistry and interstellar chemistry.To date,however,few studies have been focused on this topic.In this article,we have described a laser dispersion method applied in the apparatus combining the high-n H atom Rydberg tagging time-of-flight technique with the vacuum ultraviolet free electron laser(VUV FEL).The Lyman-αlaser beam(121.6 nm)used in the H-atom detection was generated by the difference frequency four-wave mixing schemes in a Kr/Ar gas cell.After passing through an off-axis biconvex LiF lens,the 121.6 nm beam was dispersed from the 212.6 nm and 845 nm beams due to the different deflection angles experienced by these laser beams at the surfaces of the biconvex lens.This method can eliminate the background signal from the 212.6 nm photolysis.Combined with the VUV FEL,photodissociation of H2S at 122.95 nm was studied successfully.The TOF spectrum was measured and the derived total kinetic energy release spectrum was displayed.The results suggest that the experimental setup is a powerful tool for investigating photodissociation dynamics of molecules in the VUV region which involves the H-atom elimination processes.
基金This work was supported by the National Natural Science Foundation of China(No.92061203 and No.21688102)the Strategic Priority Research Program of Chinese Academy of Sciences(XDB17000000)+3 种基金International Partnership Program of Chinese Academy of Sciences(121421KYSB20170012)Chinese Academy of Sciences(GJJSTD20190002)K.C.Wong Education Foundation(GJTD-2018-06)Dalian Institute of Chemical Physics(DICP DCLS201702).
文摘Spectroscopic characterization of clusters is crucial to understanding the structures and reaction mechanisms at the microscopic level,but it has been proven to be a grand challenge for neutral clusters because the absence of a charge makes it di伍cult for the size selection and detection.Infrared(IR)spectroscopy based on threshold photoionization using a tunable vacuum ultraviolet free electron laser(VUV-FEL)has recently been developed in the lab.The IR-VUV depletion and IR+VUV enhancement spectroscopic techniques open new avenues for size-selected IR spectroscopies of a large variety of neutral clusters without confinement(i.e.,an ultraviolet chromophore,a messenger tag,or a host matrix).The spectroscopic principles have been demonstrated by investigations of some neutral water clusters and some metal carbonyls.Here,the spectroscopic principles and their applications for neutral clusters are reviewed.
文摘The LCLS-II (linac coherent light source II) will build on the success of the world's most powerful X-ray laser: the LCLS (linac coherent light source). It will add two new X-ray laser beams and room for additional new instruments, thus greatly increasing the number of experiments carried out each year. Multiple operation modes are proposed to accommodate a variety of user requirements. There are a large number of variables and objectives in the design. For each operation mode, MOGA (multi-objective genetic algorithm) is applied to optimize the machine parameters in order to minimize the jitters, energy spread, collective effects and emittance.
基金The authors would like to thank Huang, Z., and Ding, Y. from SLAC and Feng, C., Deng, H., Lan, T., Shen, L., Wang, X. and Liu, B. from SINAP for helpful discussions. The authors are grateful for the support of Major State Basic Research Development Program of China (No. 2011CB808300), and Natural Science Foundation of China (No. 11075199).
文摘With the stat-of-the-art laser technique, the quality of electron beam generated from LPA (laser-plasma accelerator) is now becoming much better. The natural merits of electron beam from LPA, e.g., high peak current, ultra-low emittance and ultra-short bunch length, etc., pave the way to the novel light sources, especially in the realm of developing much more compact x-ray light sources, e.g., table-top XFEL (x-ray free-electron laser). However, the radiation power is limited by the rather larger energy spread than conventional radio-frequency electron LINAC (linear accelerator). Luckily, much more power could be extracted by using the undulator with transverse gradient when energy spread effect could be compensated. In this paper, we introduce a novel soit x-ray light source driven by LPA together with TGU (transverse gradient undulator) technique, meanwhile we present a simple idea on how to achieve much higher rep-rate (e.g., -100 kHz) FELs (free-electron lasers) boosted by TGU based on storage rings.
基金This work was partially supported by the National Development and Reform Commission ([201312347), the National Natural Science Foundation of China (11475250, 11175240, 11275253 and 11322550) and the National Basic Research Program of China (2015CB859700).
文摘The echo-enabled harmonic generation (EEHG) scheme holds promising prospects for efficiently generat- ing intense coherent radiation at very high harmonics of the initial seed laser. In this paper, we study the feasibility of operating the Shanghai X-ray free-electron laser test facility with a single stage EEHG setup. With a combina- tion of existing numerical codes, start-to-end simulations considering various three-dimensional effects have been carried out to show the possible performance of the EEHG FEL. Simulation results demonstrate that a single stage EEHG can generate high power soft X-ray radiation pulses with narrow bandwidth directly from UV seed lasers. With the help of the harmonic lasing technique or upgraded linac, we also show the possibility of generating coherent soft X-ray radiation in the "water window" with a single stage EEHG.