To study the influence of Fe addition on the Al-based amorphous alloys,the structure and properties of Al84Ni10La6 and Al84Ni9Fe1La6 alloys were investigated through various techniques.The results show that 1% Fe(mol...To study the influence of Fe addition on the Al-based amorphous alloys,the structure and properties of Al84Ni10La6 and Al84Ni9Fe1La6 alloys were investigated through various techniques.The results show that 1% Fe(molar fraction) addition increases the area of the pre-peak in the structure factor and decreases the thermal expansion coefficient difference between the crystalline and amorphous states.1% Fe addition also improves the glass forming ability(GFA),micro-hardness,fracture toughness,electric resistivity,absolute diamagnetism and corrosion resistance of Al-Ni-La alloys,which is related to the changes of medium-range order and quench-in free volume caused by 1% Fe addition.展开更多
Surface roughness is an important factor that affects the wetting of molten metal on ceramics.The effect of surface roughness of the alumina substrate on the contact angle,contact diameter,drop height and surface tens...Surface roughness is an important factor that affects the wetting of molten metal on ceramics.The effect of surface roughness of the alumina substrate on the contact angle,contact diameter,drop height and surface tension of molten lead was investigated in the temperature range of 923-1123 K.The microstructure of the lead/substrate interface was observed by SEM.The surface free energy of alumina substrates was calculated by the geometrical average method.When the surface roughness of the substrate increased from 0.092 to 2.23μm,the surface free energy increased gradually,ranging from 13.356 to 39.998 mJ/m^(2).The contact diameter of lead droplets decreased from 9.111 to 7.19 mm.The lead drop height increased from 3.41 to 3.85 mm.The contact angle increased from 113.05°to 137.15°.Moreover,the surface depression of the alumina substrate was filled with lead,and no obvious change was observed.The results demonstrated that the wetting of lead drop on alumina substrates was consistent with the Wenzel state.展开更多
基金Projects(50871061,50871062,50831003 and 50631010)supported by the National Natural Science Foundation of ChinaProject(2008BS04020)supported by the Excellent Youth Science and Technology Award of Shandong Province,China+2 种基金Project(NCET-06-584)supported by the New Century Talents Program of the Ministry of Education,ChinaProject(2007CB613901)supported by the National Basic Research Program of ChinaProject(LZUMMM2010008)supported by Open Project of Key Laboratory for Magnetism Materials of the Ministry of Education,China
文摘To study the influence of Fe addition on the Al-based amorphous alloys,the structure and properties of Al84Ni10La6 and Al84Ni9Fe1La6 alloys were investigated through various techniques.The results show that 1% Fe(molar fraction) addition increases the area of the pre-peak in the structure factor and decreases the thermal expansion coefficient difference between the crystalline and amorphous states.1% Fe addition also improves the glass forming ability(GFA),micro-hardness,fracture toughness,electric resistivity,absolute diamagnetism and corrosion resistance of Al-Ni-La alloys,which is related to the changes of medium-range order and quench-in free volume caused by 1% Fe addition.
基金financial supports from the National Natural Science Foundation of China(Nos.51974022,U1738101)Fundamental Research Funds for the Central Universities,China(No.FRF-MP-20-17)。
文摘Surface roughness is an important factor that affects the wetting of molten metal on ceramics.The effect of surface roughness of the alumina substrate on the contact angle,contact diameter,drop height and surface tension of molten lead was investigated in the temperature range of 923-1123 K.The microstructure of the lead/substrate interface was observed by SEM.The surface free energy of alumina substrates was calculated by the geometrical average method.When the surface roughness of the substrate increased from 0.092 to 2.23μm,the surface free energy increased gradually,ranging from 13.356 to 39.998 mJ/m^(2).The contact diameter of lead droplets decreased from 9.111 to 7.19 mm.The lead drop height increased from 3.41 to 3.85 mm.The contact angle increased from 113.05°to 137.15°.Moreover,the surface depression of the alumina substrate was filled with lead,and no obvious change was observed.The results demonstrated that the wetting of lead drop on alumina substrates was consistent with the Wenzel state.