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三聚氰胺-三聚氰酸自组装薄竹的阻燃性能 被引量:1
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作者 王琮琮 顾仲凯 +3 位作者 林鹏 张毓格 俞友明 侯俊峰 《林业工程学报》 CSCD 北大核心 2023年第4期51-58,共8页
以三聚氰胺和三聚氰酸为阻燃剂,采用自组装技术对刨切薄竹试样进行浸渍处理以提高其阻燃性能。通过傅里叶变换红外光谱(FT-IR)仪、X射线衍射(XRD)仪、扫描电子显微镜(SEM)和热重分析(TG-DTG)仪等对薄竹表面所形成的阻燃层成分、形貌变... 以三聚氰胺和三聚氰酸为阻燃剂,采用自组装技术对刨切薄竹试样进行浸渍处理以提高其阻燃性能。通过傅里叶变换红外光谱(FT-IR)仪、X射线衍射(XRD)仪、扫描电子显微镜(SEM)和热重分析(TG-DTG)仪等对薄竹表面所形成的阻燃层成分、形貌变化以及阻燃机理进行表征。通过锥形量热仪对自组装薄竹的燃烧特性进行表征,揭示质量分数比对自组装薄竹阻燃性能的影响规律。FT-IR、XRD和SEM测试结果表明,在3469和1659 cm^(-1)处出现了新吸收峰,证实了三聚氰胺和三聚氰酸通过自组装生成三聚氰胺-三聚氰酸盐,并沉积在薄竹试样表面形成阻燃层。根据TG-DTG测试结果,三聚氰胺和三聚氰酸溶液自组装处理可以有效延缓薄竹试样的热解;试样的起始热解温度显著降低,最大失重峰值温度升高。锥形量热仪测试结果表明,处理后薄竹的热释放速率峰值(PHRR)、总热释放量(THR)和总烟释放速率(TSR)大幅度降低,残余质量分数显著增大。与对照组相比,当质量分数比增加到3.0∶2.0时,薄竹试样的PHRR、THR和TSR分别降低了25.84%,24.79%和38.47%,残余质量分数增加了5.82个百分点。通过三聚氰胺和三聚氰酸自组装处理可以显著提升薄竹的热稳定性、阻燃性能和抑烟性能。 展开更多
关键词 薄竹 自组装处理 三聚氰胺 三聚氰酸 阻燃性能
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A New Self-assembly Metal CMG Discriminator by Multi-exposure LiGA Like Process and Sacrificial Layer Process 被引量:1
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作者 张卫平 陈文元 +2 位作者 赵小林 丁桂甫 李胜勇 《Journal of Donghua University(English Edition)》 EI CAS 2005年第4期91-93,共3页
The counter-meshing gears (CMG) discriminator is a mechanically coded lock, which is used to prevent the occurrence of High Consequence Events. This paper advanced a new kind of self-assembly metal CMG discriminator... The counter-meshing gears (CMG) discriminator is a mechanically coded lock, which is used to prevent the occurrence of High Consequence Events. This paper advanced a new kind of self-assembly metal CMG discriminator based on multi-exposure LiGA like process and sacrificial layer process. The new CMG discriminator has the following characters except low cost: 1) it has only discrimination teeth sections; 2) the thickness of each gear layer exceeds one hundred micrometers; 3) it is axially driven by a separate dectronic magnetic micromotor directly; 4) its CMG is made of metal and is batch fabricated in the assembled state; 5) it is prevented from rotating in the opposite direction by pawl/ratchet wheel mechanism; 6) it has simpler structure. This device has better strength and reliability in abnormal environment compared to the existing surface micro machining (SMM) discriminator. 展开更多
关键词 Counter-meshing gears (CMG) discriminator multi-exposure LiGA like process sacrificial layer process.
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Configuration information acquisition and matching in self-reconfiguring process of modular self-reconfigurable robots 被引量:1
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作者 任宗伟 《High Technology Letters》 EI CAS 2008年第4期411-417,共7页
Configuration information acquisition and matching are two important steps in the self-reconfiguring process of self-reconfigurable robots. The process of configuration information acquisition was introduced, and a se... Configuration information acquisition and matching are two important steps in the self-reconfiguring process of self-reconfigurable robots. The process of configuration information acquisition was introduced, and a self-reconfiguring configuration matching strategy based on graded optimization mechanism was proposed. The first-grade optimization was to search common connection between matching scheme and goal configuration. The second-grade optimization, whose object function was constructed in terms of configuration connectivity, was to search connnon topology according to the results of the first-grade optimization. The entire process of configuration information acquisition and matching was verified by an experiment and genetic algorithm (GA). The result shows the accuracy of the configuration information acquisition and the effectiveness of the configuration matching method. 展开更多
关键词 self-reconfigurable robot genetic algorithm (GA) information acquisition configuration matching graded optimization.
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Self-assembly and chemical processing of block copolymers:A roadmap towards a diverse array of block copolymer nanostructures 被引量:3
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作者 WYMAN Ian LIU GuoJun 《Science China Chemistry》 SCIE EI CAS 2013年第8期1040-1066,共27页
Block copolymers can yield a diverse array of nanostructures.Their assembly structures are influenced by their inherent structures,and the wide variety of structures that can be prepared especially becomes apparent wh... Block copolymers can yield a diverse array of nanostructures.Their assembly structures are influenced by their inherent structures,and the wide variety of structures that can be prepared especially becomes apparent when one considers the number of routes available to prepare block copolymer assemblies.Some examples include self-assembly,directed assembly,coupling,as well as hierarchical assembly,which can yield assemblies having even higher structural order.These assembly routes can also be complemented by processing techniques such as selective crosslinking and etching,the former technique leading to permanent structures,the latter towards sculpted and the combination of the two towards permanent sculpted structures.The combination of these pathways provides extremely versatile routes towards an exciting variety of architectures.This review will attempt to highlight destinations reached by LIU Guojun and coworkers following these pathways. 展开更多
关键词 block copolymers SELF-ASSEMBLY chemical processing CROSSLINKING
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