Taking three-phase electrode adjusting system of submerged arc furnace as study object which has nonlinear, time-variant, multivariable and strong coupling features, a neural adaptive PSD(proportion, sum and different...Taking three-phase electrode adjusting system of submerged arc furnace as study object which has nonlinear, time-variant, multivariable and strong coupling features, a neural adaptive PSD(proportion, sum and differential) dispersive decoupling controller was developed by combining neural adaptive PSD algorithm with dispersive decoupling network. In this work, the production technology process and control difficulties of submerged arc furnace were simply introduced, the necessity of establishing a neural adaptive PSD dispersive decoupling controller was discussed, the design method and the implementation steps of the controller are expounded in detail, and the block diagram of the controlled system is presented. By comparison with experimental results of the conventional PID controller and the adaptive PSD controller, the decoupling ability, adaptive ability, self-learning ability and robustness of the neural adaptive PSD dispersive decoupling controller have been testified effectively. The controller is applicable to the three-phase electrode adjusting system of submerged arc furnace, and it will play an important role for achieving the power balance of three-phrase electrodes, saving energy and reducing consumption in the process of smelting.展开更多
We report a theoretic study on modulating the spin polarization of charge current in a mesoscopic fourterminal device of cross structure by using the inverse spin hall effect. The scattering region of device is a two-...We report a theoretic study on modulating the spin polarization of charge current in a mesoscopic fourterminal device of cross structure by using the inverse spin hall effect. The scattering region of device is a two-dimensional electron gas (2DEG) with Rashba spin orbital interaction (RSOI), one of lead is ferromagnetic metal and other three leads are spin-degenerate normal metals. By using Landauer-Biittiker formalism, we found that when a longitudinal charge current flows through 2DEG scattering region from FM lead by external bias, the transverse current can be either a pure spin current or full-polarized charge current due to the combined effect of spin hall effect and its inverse process, and the polarization of this transverse current can be easily controlled by several device parameters such as the Fermi energy, ferromagnetic magnetization, and the RSOI constant. Our method may pave a new way to control the spin polarization of a charge current.展开更多
We adopt the nonequilibrium Green's function method to theoretically study the Kondo effect in a deformed molecule, which is treated as an electron-phonon interaction (EPI) system. The self-energy for phonon part i...We adopt the nonequilibrium Green's function method to theoretically study the Kondo effect in a deformed molecule, which is treated as an electron-phonon interaction (EPI) system. The self-energy for phonon part is calculated in the standard many-body diagrammatic expansion up to the second order in EPI strength. We find that the multiple phonon-assisted Kondo satellites arise besides the usual Kondo resonance. In the antiparallel magnetic configuration the splitting of main Kondo peak and phonon-assisted satellites only happen for asymmetrical dot-lead couplings, but it is free from the symmetry for the parallel magnetic configuration. The EPI strength and vibrational frequency can enhance the spin splitting of both main Kondo and satellites. It is shown that the suppressed zero-bias Kondo resonance can be restored by applying an external magnetic field, whose magnitude is dependent on the phononic effect remarkably. Although the asymmetry in tunnel coupling has no contribution to the restoration of spin splitting of Kondo peak, it can shrink the external field needed to switch tunneling magnetoresistance ratio between large negative dip and large positive peak.展开更多
A generalized finite element formulation is proposed for the study of the spin-dependent ballistic transport of electron through the two-dimensional quantum structures with Rashba spin-orbit interactions (SOI). The ...A generalized finite element formulation is proposed for the study of the spin-dependent ballistic transport of electron through the two-dimensional quantum structures with Rashba spin-orbit interactions (SOI). The transmission coefficient, conductance, the total and local polarization are numerically calculated and discussed as the Rashba eoefficient, the geometric sizes, and incident energy are changed in the T-shaped devices. Some interesting features are found in the proper parameter regime. The polarization has an enhancement as the Rashba coefficient becomes stronger. The polarization valley is rigid in the regime of the conductance plateaus since the local interference among the polarized multi-wave modes. The Rashba interactions coupling to geometry in sizes could form the structure-induced Fano-Rashba resonance. In the wider stub, the localized spin lattice of electron could be produced. The conductance plateaus correspond to weak polarizations. Strong polarizations appear when the stub sizes, incident energy, and the Rashba coupling coefficient are matched. The resonances are formed in a wide Fermi energy segment easily.展开更多
Gaseous dibenzo-7-phosphanorbornadiene P-sulfide anions APS (A C14H10 or anthracene) were generated via electrospray ionization, and characterized by magnetic-bottle photoelec- tron spectroscopy, velocity-map imagi...Gaseous dibenzo-7-phosphanorbornadiene P-sulfide anions APS (A C14H10 or anthracene) were generated via electrospray ionization, and characterized by magnetic-bottle photoelec- tron spectroscopy, velocity-map imaging (VMI) photoelectron spectroscopy, and quantum chemical calculations. The electron affinity (EA) and spin-orbit (SO) splitting of the APS" radical are determined from the photoelectron spectra and Franck-Condon factor simulations to be EA (2.62-4-0.05) eV and SO splitting (43-4-7) meV. VMI photoelectron images show strong and sharp peaks near the detachment threshold with an identical electron kinetic energy (eKE) of 17.9 meV at three different detachment wavelengths, which are therefore assigned to autodetachment from dipole-bound anion states. The B3LYP/6-31++G(d,p) calculations indicate APS has a dipole moment of 3.31 Debye, large enough to support a dipole-bound electron.展开更多
基金Project(61174132) supported by the National Natural Science Foundation of ChinaProject(09JJ6098) supported by the Natural Science Foundation of Hunan Province, China
文摘Taking three-phase electrode adjusting system of submerged arc furnace as study object which has nonlinear, time-variant, multivariable and strong coupling features, a neural adaptive PSD(proportion, sum and differential) dispersive decoupling controller was developed by combining neural adaptive PSD algorithm with dispersive decoupling network. In this work, the production technology process and control difficulties of submerged arc furnace were simply introduced, the necessity of establishing a neural adaptive PSD dispersive decoupling controller was discussed, the design method and the implementation steps of the controller are expounded in detail, and the block diagram of the controlled system is presented. By comparison with experimental results of the conventional PID controller and the adaptive PSD controller, the decoupling ability, adaptive ability, self-learning ability and robustness of the neural adaptive PSD dispersive decoupling controller have been testified effectively. The controller is applicable to the three-phase electrode adjusting system of submerged arc furnace, and it will play an important role for achieving the power balance of three-phrase electrodes, saving energy and reducing consumption in the process of smelting.
基金Supported by National Natural Science Foundation of China under Grant No.10704016Natural Science Foundation of Jiangsu Province under Grant Nos.BK2007100Ministry of Education of China under Grant No.MEC-20070286036
文摘We report a theoretic study on modulating the spin polarization of charge current in a mesoscopic fourterminal device of cross structure by using the inverse spin hall effect. The scattering region of device is a two-dimensional electron gas (2DEG) with Rashba spin orbital interaction (RSOI), one of lead is ferromagnetic metal and other three leads are spin-degenerate normal metals. By using Landauer-Biittiker formalism, we found that when a longitudinal charge current flows through 2DEG scattering region from FM lead by external bias, the transverse current can be either a pure spin current or full-polarized charge current due to the combined effect of spin hall effect and its inverse process, and the polarization of this transverse current can be easily controlled by several device parameters such as the Fermi energy, ferromagnetic magnetization, and the RSOI constant. Our method may pave a new way to control the spin polarization of a charge current.
基金Supported by the National Natural Science Foundation of China under Grant No. 10974058the Guangdong Natural Science Foundation under Grant No. 9451063101002088+1 种基金the Shanghai Natural Science Foundation of China under Grant No. 09ZR1421400Science and Technology Program of Shanghai Maritime University under Contract No. 2008475
文摘We adopt the nonequilibrium Green's function method to theoretically study the Kondo effect in a deformed molecule, which is treated as an electron-phonon interaction (EPI) system. The self-energy for phonon part is calculated in the standard many-body diagrammatic expansion up to the second order in EPI strength. We find that the multiple phonon-assisted Kondo satellites arise besides the usual Kondo resonance. In the antiparallel magnetic configuration the splitting of main Kondo peak and phonon-assisted satellites only happen for asymmetrical dot-lead couplings, but it is free from the symmetry for the parallel magnetic configuration. The EPI strength and vibrational frequency can enhance the spin splitting of both main Kondo and satellites. It is shown that the suppressed zero-bias Kondo resonance can be restored by applying an external magnetic field, whose magnitude is dependent on the phononic effect remarkably. Although the asymmetry in tunnel coupling has no contribution to the restoration of spin splitting of Kondo peak, it can shrink the external field needed to switch tunneling magnetoresistance ratio between large negative dip and large positive peak.
基金Supported by the National Science Foundation of China under Grant No.2006CB921605
文摘A generalized finite element formulation is proposed for the study of the spin-dependent ballistic transport of electron through the two-dimensional quantum structures with Rashba spin-orbit interactions (SOI). The transmission coefficient, conductance, the total and local polarization are numerically calculated and discussed as the Rashba eoefficient, the geometric sizes, and incident energy are changed in the T-shaped devices. Some interesting features are found in the proper parameter regime. The polarization has an enhancement as the Rashba coefficient becomes stronger. The polarization valley is rigid in the regime of the conductance plateaus since the local interference among the polarized multi-wave modes. The Rashba interactions coupling to geometry in sizes could form the structure-induced Fano-Rashba resonance. In the wider stub, the localized spin lattice of electron could be produced. The conductance plateaus correspond to weak polarizations. Strong polarizations appear when the stub sizes, incident energy, and the Rashba coupling coefficient are matched. The resonances are formed in a wide Fermi energy segment easily.
基金supported by the U.S.Department of Energy(DOE),Office of Science,Office of Basic EnergySciences,Division of Chemical Sciences,Geosciences and Biosciences,and was performed using EMSLa national scientific user facility sponsored by DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory,which is operated by Battelle Memorial Institute for the DOEsupported by the National Science Foundation under Grant(No.CHE-1664799)
文摘Gaseous dibenzo-7-phosphanorbornadiene P-sulfide anions APS (A C14H10 or anthracene) were generated via electrospray ionization, and characterized by magnetic-bottle photoelec- tron spectroscopy, velocity-map imaging (VMI) photoelectron spectroscopy, and quantum chemical calculations. The electron affinity (EA) and spin-orbit (SO) splitting of the APS" radical are determined from the photoelectron spectra and Franck-Condon factor simulations to be EA (2.62-4-0.05) eV and SO splitting (43-4-7) meV. VMI photoelectron images show strong and sharp peaks near the detachment threshold with an identical electron kinetic energy (eKE) of 17.9 meV at three different detachment wavelengths, which are therefore assigned to autodetachment from dipole-bound anion states. The B3LYP/6-31++G(d,p) calculations indicate APS has a dipole moment of 3.31 Debye, large enough to support a dipole-bound electron.