A new model for self-diffusion coefficients was proposed based oil both the concepts of molecular free volume and activation energy. The unknown parameters of this model were clearly defined and compared with the Chap...A new model for self-diffusion coefficients was proposed based oil both the concepts of molecular free volume and activation energy. The unknown parameters of this model were clearly defined and compared with the Chapman-Enskog model. At the same time a new method for calculating activation energy was devised and applied to the new model. In addition, the free volume was defined by implementing the generic van der Waals equation of state, the radial distribution function of which was obtained by using the Morsali- Goharshadi empirical formula. Under the same conditions, the new model was better than the original free volume model.展开更多
Thermodynamic analysis of the possibility of silver nanocrystalline preparation by high energy milling silver oxide was investigated. The molar Gibbs free energy function of mechanically activated samples was calculat...Thermodynamic analysis of the possibility of silver nanocrystalline preparation by high energy milling silver oxide was investigated. The molar Gibbs free energy function of mechanically activated samples was calculated from the structural defects such as amorphization, dislocation and surface energy. According to the molar Gibbs free energy function, the equilibrium temperature of mechanical reduction of silver oxide milled for 21 h was estimated at about 304 K. Consequently, at this temperature silver oxide cannot be stable and will transform to silver during the milling.展开更多
The free energy at low temperature in 1D sine-Gordon-Thirring model with impurity coupling is studied by means of functional integrals method. For massive free sine-Gordon-Thirring model, free energy is obtained from ...The free energy at low temperature in 1D sine-Gordon-Thirring model with impurity coupling is studied by means of functional integrals method. For massive free sine-Gordon-Thirring model, free energy is obtained from perturbation expansion of functional determinant. Moreover, the free energy of massive model is calculated by use of an auxiliary Bose field method.展开更多
Based on Dyson Schwinger Equations (DSEs) in the “rainbow” approximation, the dependence of quark effective mass on gluon propagator is investigated by use of three different phenomenological gluon propagators wit...Based on Dyson Schwinger Equations (DSEs) in the “rainbow” approximation, the dependence of quark effective mass on gluon propagator is investigated by use of three different phenomenological gluon propagators with two parameters, the strength parameter x and range parameter △. Our theoretical calculations for the quark effective mass Mf(p^2), defined by the self-energy functions Af(p^2) and Bi(p%2) of the DSEs, show that the dynamically running quark effective mass is strongly dependent on gluon propagator. Therefore, because gluon propagator is completely unknown, the quark effective mass cannot be exactly determined theoretically.展开更多
The free-surface Green function method is widely used in solving the radiation or diffraction problems caused by a ship or ocean structure oscillating on the waves. In the context of inviscid potential flow, hydrodyna...The free-surface Green function method is widely used in solving the radiation or diffraction problems caused by a ship or ocean structure oscillating on the waves. In the context of inviscid potential flow, hydrodynamic problems such as multi-body interaction and tank side wall effect cannot be properly dealt with based on the traditional free-surface frequency domain Green function method, in which the water viscosity is omitted and the energy dissipation effect is absent. In this paper, an open-sea Green function with viscous dissipation was presented within the theory ofvisco-potential flow. Then the tank Green function with a partial reflection from the side walls in wave tanks was formulated as a formal sum of open-sea Green functions representing the infinite images between two parallel side walls of the source in the tank. The new far-field characteristics of the tank Green function is vitally important fur improving the validity of side-wall effects evaluation, which can be used in supervising the tank model tests.展开更多
The authors offered the new formula of the thermodynamic functions in a magnetic field. The authors have also found that thermodynamic functions of internal energy dUand free energy dF changes in the magnetic field.
The Dirac equation is solved for Killingbeck potential. Under spin symmetry limit, the energy eigenvalues and the corresponding wave functions are obtained by using wave function ansatz method.
From point of view of weighted density procedure, it is guessed that a Percus-Yevick (PY) compressibility excess free energy density, appearing in the Kierlik Rosinberg type fundamental measure functional (KR-FMF)...From point of view of weighted density procedure, it is guessed that a Percus-Yevick (PY) compressibility excess free energy density, appearing in the Kierlik Rosinberg type fundamental measure functional (KR-FMF) and expressed in terms of scaled particle variables, can be substituted by a corresponding expression dictated by a more accurate Mansoori Carnahan-Starling Leland (MCSL) equation of state, while retaining the original weighting functions; it is numerically indicated that the resultant undesirable non-self-consistency between the PY type weighting function and MCSL type excess free energy density had no bad effect on the performance of the resultant augmented KR-ffMF which, on the one hand, preserves the exact low-density limit of the original KR-FMF and holds a high degree of pressure self-consistency, on the other hand, improves significantly, as expected, the predictions of density profile of hard sphere fluid at single hard wall contact location and its vicinity, and of the bulk hard sphere second order direct correlation function (DCF), obtained from functional differentiation. The FMF is made applicable to inhomogeneous non-hard sphere fluids by supplementing a functional perturbation expansion approximation truncated at the lowest order with summation of higher order terms beyond the lowest term calculated by the FMF for an effective hard sphere fluid; the resultant extended FMF only needs second order DCF and pressure of the fluid considered at coexistence state as inputs, consequently is applicable whether the considered temperature is above critical point or below critical point. The extended MCSL-augmented KR-FMF is found to be endowed with an excellent performance for predictions of density profile and surface tension by comparing the present predictions of these two quantities with available computer simulation data for inhomogeneous hard core attractive Yukawa fluid and Lennard-3ones fluid.展开更多
In the framework of the Skyrme-Hartree-Fock approach with 36 sets of the TI J parameterizations,the tensor force effect on the evolution of the single-proton states in the calcium isotopes is systematically investigat...In the framework of the Skyrme-Hartree-Fock approach with 36 sets of the TI J parameterizations,the tensor force effect on the evolution of the single-proton states in the calcium isotopes is systematically investigated.It is shown that the single-proton states with higher angular momenta are influenced significantly by the tensor force and the trend in the evolution of somesingle-particle energy differences with the mass number of the isotopes depends sensitively on a parameter βT associated with the intensity of the tensor force.To understand this phenomenon,we analyze the spin-orbit potentials and the radial wave functions of relevant single-proton orbits in detail.In addition,it is found that some TI J interactions could cause the 2s1/21d3/2 energy level inversion in 48Ca.展开更多
文摘A new model for self-diffusion coefficients was proposed based oil both the concepts of molecular free volume and activation energy. The unknown parameters of this model were clearly defined and compared with the Chapman-Enskog model. At the same time a new method for calculating activation energy was devised and applied to the new model. In addition, the free volume was defined by implementing the generic van der Waals equation of state, the radial distribution function of which was obtained by using the Morsali- Goharshadi empirical formula. Under the same conditions, the new model was better than the original free volume model.
文摘Thermodynamic analysis of the possibility of silver nanocrystalline preparation by high energy milling silver oxide was investigated. The molar Gibbs free energy function of mechanically activated samples was calculated from the structural defects such as amorphization, dislocation and surface energy. According to the molar Gibbs free energy function, the equilibrium temperature of mechanical reduction of silver oxide milled for 21 h was estimated at about 304 K. Consequently, at this temperature silver oxide cannot be stable and will transform to silver during the milling.
基金The project supported by the Natural Science Foundation of Sichuan Normal University
文摘The free energy at low temperature in 1D sine-Gordon-Thirring model with impurity coupling is studied by means of functional integrals method. For massive free sine-Gordon-Thirring model, free energy is obtained from perturbation expansion of functional determinant. Moreover, the free energy of massive model is calculated by use of an auxiliary Bose field method.
文摘Based on Dyson Schwinger Equations (DSEs) in the “rainbow” approximation, the dependence of quark effective mass on gluon propagator is investigated by use of three different phenomenological gluon propagators with two parameters, the strength parameter x and range parameter △. Our theoretical calculations for the quark effective mass Mf(p^2), defined by the self-energy functions Af(p^2) and Bi(p%2) of the DSEs, show that the dynamically running quark effective mass is strongly dependent on gluon propagator. Therefore, because gluon propagator is completely unknown, the quark effective mass cannot be exactly determined theoretically.
基金Supported by NSFC Project(51009037)"111"Program(B07019)
文摘The free-surface Green function method is widely used in solving the radiation or diffraction problems caused by a ship or ocean structure oscillating on the waves. In the context of inviscid potential flow, hydrodynamic problems such as multi-body interaction and tank side wall effect cannot be properly dealt with based on the traditional free-surface frequency domain Green function method, in which the water viscosity is omitted and the energy dissipation effect is absent. In this paper, an open-sea Green function with viscous dissipation was presented within the theory ofvisco-potential flow. Then the tank Green function with a partial reflection from the side walls in wave tanks was formulated as a formal sum of open-sea Green functions representing the infinite images between two parallel side walls of the source in the tank. The new far-field characteristics of the tank Green function is vitally important fur improving the validity of side-wall effects evaluation, which can be used in supervising the tank model tests.
文摘The authors offered the new formula of the thermodynamic functions in a magnetic field. The authors have also found that thermodynamic functions of internal energy dUand free energy dF changes in the magnetic field.
文摘The Dirac equation is solved for Killingbeck potential. Under spin symmetry limit, the energy eigenvalues and the corresponding wave functions are obtained by using wave function ansatz method.
基金Supported by the National Natural Science Foundation of China under Grant No.20973202
文摘From point of view of weighted density procedure, it is guessed that a Percus-Yevick (PY) compressibility excess free energy density, appearing in the Kierlik Rosinberg type fundamental measure functional (KR-FMF) and expressed in terms of scaled particle variables, can be substituted by a corresponding expression dictated by a more accurate Mansoori Carnahan-Starling Leland (MCSL) equation of state, while retaining the original weighting functions; it is numerically indicated that the resultant undesirable non-self-consistency between the PY type weighting function and MCSL type excess free energy density had no bad effect on the performance of the resultant augmented KR-ffMF which, on the one hand, preserves the exact low-density limit of the original KR-FMF and holds a high degree of pressure self-consistency, on the other hand, improves significantly, as expected, the predictions of density profile of hard sphere fluid at single hard wall contact location and its vicinity, and of the bulk hard sphere second order direct correlation function (DCF), obtained from functional differentiation. The FMF is made applicable to inhomogeneous non-hard sphere fluids by supplementing a functional perturbation expansion approximation truncated at the lowest order with summation of higher order terms beyond the lowest term calculated by the FMF for an effective hard sphere fluid; the resultant extended FMF only needs second order DCF and pressure of the fluid considered at coexistence state as inputs, consequently is applicable whether the considered temperature is above critical point or below critical point. The extended MCSL-augmented KR-FMF is found to be endowed with an excellent performance for predictions of density profile and surface tension by comparing the present predictions of these two quantities with available computer simulation data for inhomogeneous hard core attractive Yukawa fluid and Lennard-3ones fluid.
基金supported by the National Natural Science Foundation of China (Grant Nos.10975190,11275271 and 11075213)the Funds for Creative Research Groups of China (Grant No.11021504)+2 种基金the Doctoral Funds of Guizhou Normal College (Grant No.12BS020)the Natural Science Foundation of Guizhou Province of China (Grant No.2013GZ62432)the Natural Science Foundation of Hebei Province of China (Grant No.2012210043)
文摘In the framework of the Skyrme-Hartree-Fock approach with 36 sets of the TI J parameterizations,the tensor force effect on the evolution of the single-proton states in the calcium isotopes is systematically investigated.It is shown that the single-proton states with higher angular momenta are influenced significantly by the tensor force and the trend in the evolution of somesingle-particle energy differences with the mass number of the isotopes depends sensitively on a parameter βT associated with the intensity of the tensor force.To understand this phenomenon,we analyze the spin-orbit potentials and the radial wave functions of relevant single-proton orbits in detail.In addition,it is found that some TI J interactions could cause the 2s1/21d3/2 energy level inversion in 48Ca.