马家沟河水变清整治对策初探

马家沟河贯穿哈尔滨市城区。伴随城市经济的发展，人口的增加，昔日清盈的天然河道，已变为浊臭的污水沟。

Experimental Study on Minimization of Sludge Production by Ozonation Process

Based on the hypothesis of reducing sludge production under cryptic growth conditions, ozone was used as cell lysis agent to treat excess sludge,and then the ozonated supernatant was returned to the aeration tank. The results show that COD and NH+4-N removal efficiencies in ozonation process were 87.96% and 84.42%, respectively. Meanwhile, a low excess sludge yield coefficient of 0. 113 ( g SS/g COD removed) was obtained. Compared with that of the control test, the process configuration decreased the excess sludge production by 51.3%.

Activated Sludge Ozonation to Reduce Sludge Production in MBR

The total experimental period was divided into two stages. At the first stage, a series of batch studies were carried out to get an understanding of the effect of ozouation on sludge properties. At the following stages, three MBRs with different amounts of activated sludge to be ozonated were run in parallel for a long period to evaluate the influence of sludge ozonation on sludge yield and permeate quality. Through batch study, it was found that ozone could disrupt the cell walls and caused the release of plasm from the cells, then the amounts of soluble organics in the solution increased with ozouation time. With the rise of soluble organics, the amount of soluble organics to be mineralized increased as well, which would reduce the soluble organics content. For the counteraction between these two aspects, a pseudo-balanee could be achieved, and soluble organics would vary in a limited range. Sludge ozonation also increased the contents of nitrogen and phosphorus in the solution. In addition, ozouation was effective in improving sludge settling property. On the basis of batch study, a suitable ozone dosage of 0.16 kgO3/kgMLSS was determined. Three systems were run in parallel for a total period of 39 days, it was demonstrated that a part of activated sludge ozonation could reduce sludge production significantly, and biological perfonnanee of mineralization and nitrification would not be inhibited due to sludge ozouation. Experimental results proved that the combination of ozonation unit with MBR unit could achieve an excellent quality of permeate as well as a small quantity of sludge production, and economic analysis indicated that an additional ozonation operating cost for treatment of both wastewater and sludge was only 0.096Yuan （US$ 0.011,5 ）/m^3 wastewater.

Improved Performance of Membrane Bioreactor by Sludge Ozonation for Reduction of Excess Sludge Production

To seek for an alternative solution for the treatment and disposal of excess activated sludge,a hybrid system of membrane bioreactor(MBR)coupled with ozonation process(i.e.,ozonation run)was set up to treat the domestic wastewater.A reference run without ozonation was also preformed as a control.The optimal ozone dose of 0.16mg O3·mg MLVSS-1 used for the sludge solubilization in the ozonation run was firstly determined through the batch sludge ozonation tests.A 40-day continuous operation of the two parallel systems demonstrated that circulation of ozonized sludge as lysate did not impact the performance of MBR in terms of organic and ammonia removal.On the contrary,an improvement in TN removal(by 7.7%)and sludge reduction(by 54%)was observed in the ozonation-combined MBR,and it was furthermore illustrated by the calculation of the mass balance based on the COD and TN substances.In addition,ozonation did not deteriorate the sludge activities for the ozonation run,indicating that not much inert organic materials built up in the bioreactor.Decreased VSS/SS ratio and lower amount of filamentous bacteria after ozonation treatment on the other hand improved the sludge settleability,as lower and constant Sluge Volume Index(SVI)values were detected in the ozonation run.

Experimental study on zero excess sludge production process with ozonation unit in MBR process

In order to investigate the influence factors of zero excess activated sludge (EAS) process by ozonation, a 100 L membrane bioreactor coupled with a sludge ozonation unit (MBR-SO) was performed for 80 d without EAS wasting. Some mathematical models were developed to elucidate the relationship between process parameters and the operating effects. It is considered that the sludge lysing ratio (ξ), produced COD per unit mass lysed MLSS (η), observed sludge yield coefficient (Yobs) and intrinsic yield coefficient for COD produced by lysed sludge (Y2) significantly affect the flowrate to ozonation unit (q). When q is 0.0067 times of influent flowrate (Q) and ξ is about 0.72 for each batch ozonation, a relatively stable MLSS concentration of 8168 mg/L and zero Yobs are achieved in the MBR-SO system. The calculation of sludge disintegration number indicates that the high ξ can apparently decrease the sludge amount needed for ozonation. At the same ozone dose, the low input ozone concentration and high flowrate can enhance the sludge lysing effects and a low energy consumption of 0.041 Yuan/m3 wastewater is obtained.