The paper presents results of phenol oxidized under the conditions of high temperature created during collapse of cavitation bubbles.The degradation efficiency has been greatly improved by using cavitation water jets ...The paper presents results of phenol oxidized under the conditions of high temperature created during collapse of cavitation bubbles.The degradation efficiency has been greatly improved by using cavitation water jets combined with H2O2 as demonstrated in laboratory tests.Various factors affecting phenol removal ratio were ex-amined and the degradation mechanism was revealed by high performance liquid chromatography(HPLC).The re-sults showed that 99.85% of phenol was mineralized when phenol concentration was 100 mg·L-1 with pH value of 3.0,H2O2 concentration of 300 mg·L-1,confining pressure of 0.5 MPa,and pumping pressure of 20 MPa.The in-termediate products after phenol oxidation were composed of catechol,hydroquinone and p-benzoquinone.Finally,phenol was degraded into maleic acid and acetic acid.Furthermore,a dynamic model of phenol oxidation via cavi-tation water jets combined with H2O2 has been developed.展开更多
According to the standard of GB/T1500.3-2008 and the guidelines of ISO/REMCO, the preparation of National Certified Reference Materials （CRMs） of active compounds was composed of the following two aspects： preparat...According to the standard of GB/T1500.3-2008 and the guidelines of ISO/REMCO, the preparation of National Certified Reference Materials （CRMs） of active compounds was composed of the following two aspects： preparation and certification. This paper presents an example of the preparation of biochanin A to illustrate the preparation of National CRMs of active compounds from natural products. Firstly, the target compound was extracted and purified from crude materials. Then, its chemical structure was identified by UV spectrum, IR spectrum, ESI-MS, and NMR. The purity of the compound was determined by HPLC with the area normalization method. The certified value assessed by comparing the purity values from six independent qualified laboratories and the value of uncertainty were given. Thermal analysis, residual solvent, homogeneity testing and stability testing was tested in the process.展开更多
This paper proposes a new and distribution-free test called ＂Group Contingency＂ test （GC, for short） for testing two or several independent samples. Compared with traditional nonparametric tests, GC test tends to ...This paper proposes a new and distribution-free test called ＂Group Contingency＂ test （GC, for short） for testing two or several independent samples. Compared with traditional nonparametric tests, GC test tends to explore more information based on samples, and it＇s location-, scale-, and shapesensitive. The authors conduct some simulation studies comparing GC test with Wilcoxon rank sum test （W）, Kolmogorov-Smirnov test （KS） and Wald-Wolfowitz runs test （WW） for two sample case, and with Kruskal-Wallis （KW） for testing several samples. Simulation results reveal that GC test usually outperforms other methods.展开更多
基金Supported by the National Natural Science Foundation of China (50921063,51104191)the Natural Science Foundationof Chongqing (2009BA6047)
文摘The paper presents results of phenol oxidized under the conditions of high temperature created during collapse of cavitation bubbles.The degradation efficiency has been greatly improved by using cavitation water jets combined with H2O2 as demonstrated in laboratory tests.Various factors affecting phenol removal ratio were ex-amined and the degradation mechanism was revealed by high performance liquid chromatography(HPLC).The re-sults showed that 99.85% of phenol was mineralized when phenol concentration was 100 mg·L-1 with pH value of 3.0,H2O2 concentration of 300 mg·L-1,confining pressure of 0.5 MPa,and pumping pressure of 20 MPa.The in-termediate products after phenol oxidation were composed of catechol,hydroquinone and p-benzoquinone.Finally,phenol was degraded into maleic acid and acetic acid.Furthermore,a dynamic model of phenol oxidation via cavi-tation water jets combined with H2O2 has been developed.
基金The Natural Science Foundation of China (20872083)the Key Science and Technology Program of Shandong Province and the State Key Laboratory of Crop Biology (2008kf05)
文摘According to the standard of GB/T1500.3-2008 and the guidelines of ISO/REMCO, the preparation of National Certified Reference Materials （CRMs） of active compounds was composed of the following two aspects： preparation and certification. This paper presents an example of the preparation of biochanin A to illustrate the preparation of National CRMs of active compounds from natural products. Firstly, the target compound was extracted and purified from crude materials. Then, its chemical structure was identified by UV spectrum, IR spectrum, ESI-MS, and NMR. The purity of the compound was determined by HPLC with the area normalization method. The certified value assessed by comparing the purity values from six independent qualified laboratories and the value of uncertainty were given. Thermal analysis, residual solvent, homogeneity testing and stability testing was tested in the process.
基金This research is supported-by the National Natural Science Foundation of China under Grant No. 10731010 and Ph.D. Program Foundation of Ministry of Education of China under Grant No. 20090001110005.
文摘This paper proposes a new and distribution-free test called ＂Group Contingency＂ test （GC, for short） for testing two or several independent samples. Compared with traditional nonparametric tests, GC test tends to explore more information based on samples, and it＇s location-, scale-, and shapesensitive. The authors conduct some simulation studies comparing GC test with Wilcoxon rank sum test （W）, Kolmogorov-Smirnov test （KS） and Wald-Wolfowitz runs test （WW） for two sample case, and with Kruskal-Wallis （KW） for testing several samples. Simulation results reveal that GC test usually outperforms other methods.
