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南岭地区钨锡铌钽花岗岩及其成矿作用 被引量:159
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作者 陈骏 陆建军 +5 位作者 陈卫锋 王汝成 马东升 朱金初 张文兰 季峻峰 《高校地质学报》 CAS CSCD 北大核心 2008年第4期459-473,共15页
在晚侏罗世时,南岭地区发生了与花岗岩有关的钨锡铌钽大规模成矿作用。依据花岗岩的岩石学、地球化学及其矿化特征,可将南岭地区含钨锡铌钽花岗岩划分为三个主要类型:含钨花岗岩、含锡钨花岗岩和含钽铌花岗岩。含钨花岗岩的地球化学特... 在晚侏罗世时,南岭地区发生了与花岗岩有关的钨锡铌钽大规模成矿作用。依据花岗岩的岩石学、地球化学及其矿化特征,可将南岭地区含钨锡铌钽花岗岩划分为三个主要类型:含钨花岗岩、含锡钨花岗岩和含钽铌花岗岩。含钨花岗岩的地球化学特征可归纳为铝过饱和,低Ba+Sr和TiO2,轻重稀土比值低,铕亏损强烈,富Y和Rb,Rb/Sr比值高,分异强烈。含锡钨花岗岩总体特征表现为TiO2含量高,准铝质—弱过铝质,轻重稀土比值和CaO/(K2O+Na2O)比值高,富高场强元素、稀土、Ba+Sr和Rb,低Rb/Sr比值,分异演化程度较低。含钽铌花岗岩的地球化学特征主要为TiO2含量和CaO/(K2O+Na2O)比值低,Al2O3/TiO2和Rb/Sr比值明显偏高,强过铝质,贫Ba+Sr、稀土和高场强元素,铕亏损强烈,明显富Rb和Nb,高度分异演化。三类含矿花岗岩具有明显不同的演化特征,成矿作用与它们的演化密切相关。黑云母花岗岩主要与锡成矿作用有关,二云母花岗岩和白云母花岗岩主要产生钨矿化或锡钨共生矿化,钠长石花岗岩主要与钽铌或锡(钨)钽铌矿化有关。总结了南岭锡钨钽铌矿床的重要类型,提出了绿泥石化花岗岩型锡矿新类型,指出南岭地区要特别注意在含锡钨花岗岩中寻找此类锡矿和云英岩-石英脉型锡钨矿。 展开更多
关键词 含矿花岗岩 地球化学 花岗岩演化 钨-锡-铌-钽矿床类型 南岭
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赣南樟东坑钨矿成矿花岗岩及矿化特征 被引量:9
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作者 黄小娥 李光来 +4 位作者 郭家松 张敏 胡志国 华仁民 韦星林 《地质与勘探》 CAS CSCD 北大核心 2012年第4期685-692,共8页
樟东坑钨矿为崇-余-犹地区典型的花岗岩外接触带石英脉型钨钼矿床之一,矿区隐伏花岗岩分主体与"火焰状"脉体两种岩相产出,都与钨钼矿化有关,为成矿母岩。矿区花岗岩岩石化学总体特征:富硅、铝,贫铁、镁,钙中等,高碱、富钾,分... 樟东坑钨矿为崇-余-犹地区典型的花岗岩外接触带石英脉型钨钼矿床之一,矿区隐伏花岗岩分主体与"火焰状"脉体两种岩相产出,都与钨钼矿化有关,为成矿母岩。矿区花岗岩岩石化学总体特征:富硅、铝,贫铁、镁,钙中等,高碱、富钾,分异指数DI较高,ACNK值以>1为主,为酸性-超酸性、分异程度较高的钙碱性-碱性岩系,准铝质-过铝质壳源岩石重熔改造型花岗岩;其地球化学特征:微量元素富Rb、Th、U、K、Ta、Y等低场强元素,而贫Ba、Nb、Sr、P、Ti等高场强元素,稀土元素总量较低、略富轻稀土,Eu严重亏损,稀土配分曲线呈"海鸥型",进一步显现壳型花岗岩特征,且岩浆演化程度较高。矿区钨钼矿化分为石英脉型和岩体型两类,受花岗岩侵入与分异演化控制,具有"上钨下钼"、"上脉下体"的矿化特征。樟东坑火焰状蚀变细粒花岗岩脉型钨钼矿化为赣南崇-余-犹脉钨矿区近年发现的新矿化类型,在赣南具有较大的找矿前景。 展开更多
关键词 “上脉下体” “上钨下钼” 花岗岩演化 岩体型矿化 樟东坑钨矿 赣南
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喜马拉雅夏如淡色花岗岩-伟晶岩的矿物学特征 被引量:2
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作者 程飞越 谢磊 陈小明 《南京大学学报(自然科学版)》 CAS CSCD 北大核心 2022年第6期1087-1106,共20页
喜马拉雅夏如岩体出露大量淡色花岗岩-伟晶岩,主要包括(含电气石-石榴子石)白云母花岗岩和花岗质伟晶岩,局部岩石与铌钽钨等稀有金属成矿作用相关,包含富含铌钽钨的氧化物,如铌铁矿族矿物、骑田岭矿、黑钨矿、铌铁金红石等.为了查明夏... 喜马拉雅夏如岩体出露大量淡色花岗岩-伟晶岩,主要包括(含电气石-石榴子石)白云母花岗岩和花岗质伟晶岩,局部岩石与铌钽钨等稀有金属成矿作用相关,包含富含铌钽钨的氧化物,如铌铁矿族矿物、骑田岭矿、黑钨矿、铌铁金红石等.为了查明夏如稀有金属矿化花岗岩-伟晶岩的岩石学、矿物学特征,更好地了解夏如岩体稀有金属成矿特征,对夏如岩体中出现矿化痕迹的样品进行研究,包括含黑钨矿的白云母花岗岩、含有铌钽钨氧化物的白云母花岗岩和含有铌钽氧化物的伟晶岩作为研究对象,同时还选取典型的未出现稀有金属矿物的白云母花岗岩(简称未矿化白云母花岗岩)进行对比研究.研究主要通过全岩地球化学主量和微量元素成分,造岩矿物和副矿物的产状、主量和微量元素成分特征进行对比.随着样品中铌钽氧化物矿物含量的出现/增加,电气石和石榴子石的含量也明显增加.这些花岗岩-伟晶岩富集SiO_(2)(72.29~75.53 wt.%),富Al_(2)O_(3)(13.17~15.94 wt.%),富碱(K_(2)O+Na_(2)O 8.0~9.8 wt.%),贫CaO,MgO和FeO,它们微量元素含量接近,含铌钽伟晶岩具有较高的Nb和Ta含量.花岗岩-伟晶岩的稀土配分曲线相似,具有明显的Eu负异常,但三种具有矿化痕迹的花岗质岩石中的稀土总量(平均21×10^(-6))明显低于未矿化白云母花岗岩的稀土总量(平均98×10^(-6)),且具有更明显的四分组效应.矿物学研究工作显示,未矿化白云母花岗岩与含钨白云母花岗岩中的主要组成矿物成分相似,含铌钽钨白云母花岗岩与含铌钽伟晶岩中的主要组成矿物成分相似,其中白云母的Al_(2)O_(3)和FeO含量,石榴子石的Mn/(Mn+Fe)比值和Eu负异常、电气石的Mg/(Mg+Fe)值都显示了含铌钽钨白云母花岗岩和含铌钽伟晶岩比未矿化白云母花岗岩和含钨白云母花岗岩具有更高的岩浆演化程度.出现铌钽氧化物的花岗岩-伟晶岩中锆石的结构指示了岩浆晚期流体活动,岩浆演化和流体活动的共同影响导致Zr/Hf值的降低.因此,本次研究表明花岗岩-伟晶岩全岩成分指示流体活动更有效,而白云母、电气石和石榴子石的成分特征指示岩浆演化过程和演化程度更有效. 展开更多
关键词 淡色花岗岩 造岩矿物 花岗岩演化 矿物学指标
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浙东南石平川花岗岩体LA-ICP-MS锆石U-Pb年代学及构造意义 被引量:38
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作者 李艳军 魏俊浩 +5 位作者 姚春亮 鄢云飞 谭俊 付乐兵 潘锦勃 李伟 《地质论评》 CAS CSCD 北大核心 2009年第5期673-684,共12页
石平川钾长花岗岩体位于浙江沿海火山岩带的中南部,LA-ICP-MS锆石U-Pb定年结果为102.5±1.2Ma(MSDW=2.1),形成于早白垩世末期。岩相学及化学成分显示其属高钾钙碱性岩系,具有高硅富钾和铝低铁、镁、磷和钛特征,SiO2含量为74.79%~77.... 石平川钾长花岗岩体位于浙江沿海火山岩带的中南部,LA-ICP-MS锆石U-Pb定年结果为102.5±1.2Ma(MSDW=2.1),形成于早白垩世末期。岩相学及化学成分显示其属高钾钙碱性岩系,具有高硅富钾和铝低铁、镁、磷和钛特征,SiO2含量为74.79%~77.79%,K2O为4.26%~7.97%,铝指数A/CNK=0.98~1.10,属准铝质—弱过铝质岩石。富集Rb、Th、U和K,亏损Sr、Ba、Nb、P和Ti,REE具有中等负Eu异常(Eu/Eu*=0.33~0.50),总体呈现LREE富集的右倾"V"型配分模式。岩石[n(87Sr)/n(86Sr)]i值为0.70801~0.71012(t=102.5Ma),εNd(t)值为-8.63^-8.76,显示壳—幔混合成因特征。矿物组成及地球化学特征显示石平川岩体为高演化I型花岗岩。微量元素显示石平川岩体具有后碰撞花岗岩的特征,侵位于早白垩世末期的张性构造环境,其形成可能与印度板块北向漂移所导致的古太平洋板块碰撞弧后引张构造有关。 展开更多
关键词 LA-ICPMS锆石U-Pb年代 演化I型花岗岩 弧后伸展 石平川花岗岩 浙江
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磷灰石单晶体同步辐射X射线荧光探针成分分析 被引量:5
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作者 汤云晖 韩春明 +2 位作者 保增宽 黄宇营 何伟 《岩矿测试》 CAS CSCD 2007年第5期367-371,共5页
采用同步辐射X荧光(SRXRF)探针技术对河北峪耳崖和甘肃大水两地花岗岩中单颗粒磷灰石的化学成分进行了分析。结果显示,磷灰石含有P、Cl、S、K、Ca、Mn、Fe、La、Ce、Nd、Sm、Gd、Yb、Sr、Y、Zr、U、Th等多种元素,峪耳崖磷灰石富含Mn、Fe... 采用同步辐射X荧光(SRXRF)探针技术对河北峪耳崖和甘肃大水两地花岗岩中单颗粒磷灰石的化学成分进行了分析。结果显示,磷灰石含有P、Cl、S、K、Ca、Mn、Fe、La、Ce、Nd、Sm、Gd、Yb、Sr、Y、Zr、U、Th等多种元素,峪耳崖磷灰石富含Mn、Fe,大水磷灰石则富含As。峪耳崖花岗岩为S型,大水花岗岩为I型,两地磷灰石在稀土元素(REE)含量上具有明显差别:大水磷灰石呈右倾的REE配分模式和明显的轻稀土(LREE)富集;而峪耳崖呈现上凸的REE配分模式和LREE亏损。依据磷灰石的REE配分模式可有效地区分不同类型的花岗岩,以此作为花岗岩岩浆演化的指示。 展开更多
关键词 磷灰石 同步辐射X射线荧光探针分析 花岗岩演化
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铌与钽的某些地球化学问题 被引量:110
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作者 赵振华 熊小林 +1 位作者 王强 乔玉楼 《地球化学》 CAS CSCD 北大核心 2008年第4期304-320,共17页
针对地球圈层之间Nb、Ta质量不平衡的难题,较系统收集分析了我国基性岩墙(脉)群、太古宙基性火山岩、碱性岩、大火成岩省火山岩,俯冲带中富Nb玄武岩、高压变质岩、花岗岩类的Nb、Ta含量、比值、相关同位素组成以及Nb、Ta实验地球化学资... 针对地球圈层之间Nb、Ta质量不平衡的难题,较系统收集分析了我国基性岩墙(脉)群、太古宙基性火山岩、碱性岩、大火成岩省火山岩,俯冲带中富Nb玄武岩、高压变质岩、花岗岩类的Nb、Ta含量、比值、相关同位素组成以及Nb、Ta实验地球化学资料。这些资料表明,Nb、Ta在这些岩类中的分布呈现非常不均匀变化,除花岗岩外,上述岩石的Nb/Ta比值均高于或近于球粒陨石值17.5。花岗岩中的幔源斜长花岗岩及与裂谷、热点环境有关的碱性花岗岩Nb/Ta比值近于地球平均值,而普通S型及I型花岗岩,特别是高演化花岗岩,Nb/Ta比值均明显低于球粒陨石(<10),甚至呈现Nb/Ta≤1。这些资料表明,在不均匀的地幔中可能存在呈布丁状分布的Nb/Ta比值高于球粒陨石的储源。金红石的稳定性及Nb、Ta分配系数实验资料不支持地球深部存在高Nb/Ta比值的含金红石榴辉岩。 展开更多
关键词 地球化学 金红石分配系数 基性岩墙群 大火成岩省 演化花岗岩
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岩石古放射性生热率的校正及其地球化学意义 被引量:12
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作者 章邦桐 凌洪飞 +1 位作者 陈培荣 吴俊奇 《矿物岩石地球化学通报》 CAS CSCD 北大核心 2010年第2期181-184,共4页
岩石放射性生热率是研究油气沉积盆地地热及花岗岩体热演化史的一个重要参数,但由现今采样分析所测得的放射性元素含量计算得出的是当今的放射性生热率。因此,本文根据辐射衰变定律及U、Th和K的放射性生热参数,导出三种不同计量单位(μW... 岩石放射性生热率是研究油气沉积盆地地热及花岗岩体热演化史的一个重要参数,但由现今采样分析所测得的放射性元素含量计算得出的是当今的放射性生热率。因此,本文根据辐射衰变定律及U、Th和K的放射性生热参数,导出三种不同计量单位(μWm-3,μJg-1a-1,HGU)校正岩石古放射性生热率的公式。它们可应用于沉积盆地中古地层放射性生热率的计算和校正,也适用于铀矿床成矿古水热系统热源及花岗岩体热演化史的研究。 展开更多
关键词 岩石古放射性生热率 校正 成矿古水热系统 沉积盆地 地热 花岗岩体热演化
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Experimental investigation on damage evolution behaviour of a granitic rock under loading and unloading 被引量:8
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作者 戴兵 赵国彦 +1 位作者 H.KONIETZKY P.L.P.WASANTHA 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第5期1213-1225,共13页
In-situ rock failures can result from stress changes due to pure loading and/or unloading. Understanding of the damage evolution behavior in brittle rocks during loading and unloading is imperative for the designs of ... In-situ rock failures can result from stress changes due to pure loading and/or unloading. Understanding of the damage evolution behavior in brittle rocks during loading and unloading is imperative for the designs of rock structures. In this paper, we investigate the damage evolution characteristics of a granitic rock during loading and unloading after a series of triaxial experiments performed at different confining pressures. The axial stress-axial strain variations of the tested specimens revealed that the specimens undergoing unloading fail with a lower axial strain compared to the specimens failed purely by loading. Higher confining pressures were observed to exacerbate the difference. Volumetric strain versus axial strain curves indicated that the curves reverse the trend with the beginning of major damage of specimens. We suggest here a new form of equation to describe the secant modulus variation of brittle rocks against the axial stress for the unloading process. Failure mechanisms of tested specimens showed two distinct patterns, namely, specimens under pure loading failed with a single distinct shear fracture while for the unloading case specimens displayed multiple intersecting fractures. In addition, analysis of the evolution of dissipation and elastic energy during deformation of the specimens under loading and unloading conditions showed differentiable characteristics. Moreover, we evaluated the variations of two damage indices defined based on the energy dissipation and secant modulus evolution during deformation and observed that both of them satisfactorily distinguish key stages of damage evolution. 展开更多
关键词 damage evolution loading and unloading granitic rock triaxial testing
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Geomorphosites in Granitic Environments: An Example from Northern Sardinia (Italy)
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作者 Sergio Ginesu Francesco Secchi 《Journal of Environmental Science and Engineering(B)》 2015年第7期388-394,共7页
A rare geomorphosite and a pillow-like structure appearing as mingling structures due to that mafic and acidic magma interactions are described. Despite the occurrence of spectacular forms in the granitic basement of ... A rare geomorphosite and a pillow-like structure appearing as mingling structures due to that mafic and acidic magma interactions are described. Despite the occurrence of spectacular forms in the granitic basement of Sardinia, the morphosites of geological interest linked to the complex evolution of pluton emplacement are still poorly understood. The Fizza Ona outcrop, located near the northeastern coast, is a good example of a geomorphosite in the inner zone developed at the edge of different plutonic units. This outcrop is a well-exposed, pillow-like horizon of less than 5 m in thickness, observable in the field for at least 200 m and underlined by the occurrence of a large tafoni form. In detail, the pillow-like horizon consists of sub-roundly to sub-rounded elements of granitic to micropegmatitic rocks of up to 100 cm in diameter, which is dispersed in the fine-grained granitic host-rock matrix. The outcrop represents a particular example of the emplacement mechanism of granitic magmas in the Sardinian batholith. One aim of this work is the construction of a document for the competent authorities to protection and preservation of this outcrop as a cultural heritage for the history of the geological evolution. 展开更多
关键词 GRANITOIDS geomorphosites granitic intrusions Sardinia.
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Granitoid magmatism in the Qinling orogen, central China and its bearing on orogenic evolution 被引量:66
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作者 WANG XiaoXia WANG Tao ZHANG ChengLi 《Science China Earth Sciences》 SCIE EI CAS CSCD 2015年第9期1497-1512,共16页
The Qinling orogen is a typical composite orogen for understanding multi-stages of magmatism and orogenic processes. Many studies have been carried out on the magmatic rocks in the Qinling orogen but their petrogenesi... The Qinling orogen is a typical composite orogen for understanding multi-stages of magmatism and orogenic processes. Many studies have been carried out on the magmatic rocks in the Qinling orogen but their petrogenesis is still controversial. This pa- per presents a review of all granitoid rocks based on previous and new studies of geochronology and geochemistry. Four dis- tinct periods of granitoid magmatism, Neoproterozoic (979-711 Ma), Paleozoic (507-400 Ma), Early Mesozoic (250-185 Ma) and Late Mesozoic (160-100 Ma), have been recognized from the Qinling orogen according to zircon U-Pb ages, intrusion as- sociations and deformation, as well as regional geology. The Neoproterozoic granitic rocks consist of three stages at 979-911, 894-815 and 759-711 Ma, respectively, corresponding to strongly deformed S-type, weakly deformed I-type and A-type gran- itoids. They can be interpreted as magmatic occurrences in syn-collisional, post-collisional and extensional settings, respec- tively, in response to old continental terranes of the Neoproterozoic tectonomagmatic events in the old continents of China, such as South China and Tarim cratons. Although this continental terrane would be involved in the Phanerozoic Qinling orog- eny, the Neoproterozoic magmatic rocks are not the products of the Qinling orogenic processes. The Paleozoic magmatic rocks can be classified into three stages at 507-470, 460-422 and 415-400 Ma, respectively. The first-stage magmatism is temporal- ly associated with ultra-high pressure metamorphism in the North Qinling terrane. These magmatic rocks are interpreted as magmatic occurrences in subductional, syn-collisional and post-collisional settings, respectively. The Early Mesozoic mag- matic rocks occur in two stages at 252-185 and 225-200 Ma, respectively. The first-stage granitoids are mainly represented by I-type quartz diorites and granodiorites, and the second stage by granodiorites and monzogranites with the 1- to A-type charac- teristics and some with rapakivi textures. Their emplacement ages and geochemical parameters such as A/CNK, K2O/Na2O ra- tios and εNd(t) values do not show any polarity change in perpendicular to subduction/collision zone. Therefore, all these Early Mesozoic granitoids are unlikely the product of continental subduction as some researchers suggested. Instead, they are plausi- bly related to the subduction of the Mianlue Ocean and the subsequent collision between the South China Craton and the South Qinling terrane. The Late Mesozoic granitoids were emplaced mainly at two stages of 160-130 and 120-100 Ma, and charac- terized by the evolution from I- to I-A- and A-type granitoids. These characteristics are consistent with the granitoid magmatic evolution from contractional to extensional settings during the Jurassic/Cretaceous in eastern China. Accordingly, the Late Mesozoic granitoid rocks in the Qinling orogen probably have a similar petrogenetic mechanism to those of the huge magmatic belt along the western Pacific margin, i.e., intra-continent magmatism related to a far-field effect of the subduction of Paleo-Pacific plate. 展开更多
关键词 GRANITOID zircon age magmatism evolution TECTONICS Qinling orogen
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Chronology and petrogenesis of the Hejiazhuang granitoid pluton and its constraints on the Early Triassic tectonic evolution of the South Qinling Belt 被引量:9
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作者 YANG PengTao LIU ShuWen +3 位作者 LI QiuGen WANG ZongQi ZHANG Fan WANG Wei 《Science China Earth Sciences》 SCIE EI CAS 2014年第2期232-246,共15页
The Hejiazhuang pluton is located in the South Qinling Tectonic Belt (SQTB) in the north side of the MianxianLueyang Su ture Zone, and consists dominantly of granodiorites. LAICPMS zircon UPb dating and LuHf isotopi... The Hejiazhuang pluton is located in the South Qinling Tectonic Belt (SQTB) in the north side of the MianxianLueyang Su ture Zone, and consists dominantly of granodiorites. LAICPMS zircon UPb dating and LuHf isotopic analyses reveal that these granodiorites of the Hejiazhaung pluton emplaced at 248 Ma, and show a large variation in zircon eHt(t) values from 4.8 to 8.8. These granodiorite samples are attributed to highK to midK calcalkaline series, and characterized by high SiO2 (66.6±70.0%), A1203 (15.04±16.10%) and Na20 (3.74±4.33%) concentrations, with high Mg# (54.2±61.7). All samples have high Sr (627±751 ppm), Cr (553±73 ppm) and Ni (17.2182 ppm), but low Y (5.42-8.41 ppm) and Yb (0.59-0.74 ppm) concentrations with high Sr/Y ratios (84.90±120.66). They also display highly fractionated REE patterns with (La/Yb)N ratios of 18.93-4.0 and positive Eu anomalies (0"Eu=1.102.22) in the chondritenormalized REE patterns. In the primitive mantle normalized spidergrams, these samples exhibit enrichment in LILEs but depletion in Nb, Ta, P and Ti. These geochemical fea tures indicate that the granodioritic magma of the Hejiazhuang pluton was derived from the partial melting of hybrid sources comprising the subducted oceanic slab and sediments, and the melts were polluted by the mantle wedge materials during their ascent. The emplacement ages and petrogenesis of the Hejiazhuang pluton prove that the initial subduction of the Mianlue oceanic crust occurred at 248 Ma ago, and the SQTB was still under subduction tectonic setting in the Early Triassic. 展开更多
关键词 granodiorites in Hejiazhuang pluton zircon U-Pb-Hf isotopic systematics petrogenesis and tectonic setting evolutionof South Qinling Tectonic Belt
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