异丙苯法生产苯酚丙酮工艺技术路线分析及建议

1 前言北京燕山石油化工公司1970年开始采用异丙苯法生产苯酚、丙酮(1万t/a 小苯酚装置),1986年又引进日本三井石油化学公司的异丙苯法生产苯酚丙酮技术,在化工二厂建设投产年产8万吨苯酚丙酮装置。几年来生产了约30万吨苯酚、丙酮产品,创利税5亿多元,

Toluene degradation by a water/silicone oil mixture for the design of two phase partitioning bioreactors

Toluene degradation performances were studied in a 10 L Two-Phase Partitioning Bioreactor(TPPB).The liquid phase consisted of a mixture of water and PDMS 50(Poly Di Methyl Siloxane,i.e.silicone oil,viscosity of 46 m Pa·s) in the volume ratio of 75%/25%.Two series of experiments were carried out:in the first,the reactor was sequentially supplied with toluene whereas in the second,toluene was continuously supplied.Activated sludge from the wastewater treatment plant of Beaurade(Rennes,France) was used at an initial concentration of 0.5 dry mass g·(mixture L)^(-1).The elimination capacity(EC) was investigated as well as the change in biomass concentration over time.Toluene biodegradation was very ef ficient(removal ef ficiency,RE=100%) for toluene flows ranging from 0.2 to 1.2 ml·h^(-1),corresponding to elimination capacities of up to 104 g·m^(-3)·h^(-1).For a toluene flow of 1.2 ml·h^(-1),the biomass concentration measured at the end of the experiment was 4.7 dry mass g·(mixture L)^(-1).The oxygen concentration in the liquid phase was clearly not a limiting factor in these operating conditions.Based on these results,an extrapolation leading to the design of a large-scale pilot TPPB can now be considered to study toluene degradation performances in industrial conditions.

Crystal Structure and Molecular Structure of Binuclear Copper(Ⅱ) Complex, [Cu (C_5H_5NO) (C_6H_5COO)_2]_2

At room temperature, dibenzoyl peroxide and pyridine N-oxide reacted with metallic copper powder in a mixed solvent(dichloromethane, trichloromethane and tetrahydrofuran), resulting in a binuclear copper(Ⅱ) complex. [Cu (C_5H_5NO)-(C_6H_5COO)_2]_2. The structure of the complex was characterized by elemental analyses.IR spectra and X-ray single crystal analysis. The crystal is triclinic, space group P1,with cell parameters . a= 9. 262(4) ,b= 10. 697(2) , c=10. 881 (3 )A , a=59. 60( 2 ),β= 74. 83 ( 3 ) .Y = 72. 80 ( 2 )°. V= 880. 0 A￣3 . D_c = 1 . 5 20 g/cm￣3 . Z = 1 . μ= 1 2. 7 cm-1, R=0. 044 ,R_w=0. 048 for 3477 reflections with I>3σ(I), M_r=805. 78. Each copper(Ⅱ) atom is coordinated by four bridging bidentate benzoate ligands and one pyridine M-oxide.

Preparation and Spectrophotometric Study of Reagent 2-[2-（6-chloro benzothiazolyl） azo]-Resorcinol as an Analytical Reagent for Determination of Nickel （11） and Copper （11） Ions

The present paper describes the preparation of new organic reagent 2-[2-（6-chloro benzothiazolyl） azo]-resorcinol （6-CIBTAR = LH2） and used for the spectrophotometric determination of traces microgram amount of nickel （II） and copper （II） was found to form Ni（II）-CIBTAR at pH 7.5 giving a green coloured complex with maximum absorption at wavelength 636 nm and copper （II） was found to from Cu（II）-CIBTAR at pH 6.5 giving green bluish coloured complex with maximum absorption at wavelength 648 nm. The molar absorptivity （~） of the complexes are 0.3695 ~ 104 L.moll-cml and 0.3933 ~ 154 L＇mol＇l.cm1 for Ni（II） and Cu（II） respectively. Calibration curves for the determination of nickel（II） and copper （II） conformed to beers law over the concentration rang of （1-20） μg.mL-1. The DL （detection limit）, RSD （relative standard deviations）, RE （relative errors） and recovery for Ni（II） and Cu（II） complexes were found to be D.L = 0.45, 0.61; R.S.D% = 1.81, 2.04; Erei% = 1.3, 0.86 and Re% = 98.7, 99.14 respectively. The analytical data show the metal to reagent ratio （mole ratio method; M：L） in Ni（II） and Cu（II） complexes are 1：2.

Polymer light-emitting devices based on europium(Ⅲ) complex with 11-bromo-dipyrido[3,2-a:2′,3′-c]phenazine

Polymer light-emitting diodes(PLEDs) containing Eu(DBM)3(Br DPPz)(DBM is dibenzoylmethane, and Br DPPz is 11- bromo-dipyrido[3,2-a:2′,3′-c]phenazine) doped in a blend of poly(9,9-dioctylfluorene)(PFO) and 2-tert-butylphenyl-5- biphenyl-1,3,4-oxadiazole(PBD) as the host matrix were reported. Eu(DBM)3(Br DPPz) exhibited high thermal stability and intense UV-Vis absorption. Narrow-bandwidth red emission at 612 nm with a full width at half-maximum(FWHM) of 14.0 nm was observed from Eu(DBM)3(Br DPPz) in these double-layered PLEDs at dopant concentrations from 1 wt% to 8 wt%. For the PLED containing 1 wt% Eu(DBM)3(Br DPPz), a maximum luminance of 829 cd/m2 at 153.5 m A/cm2, highest external quantum efficiency of 1.70% at 2.1 m A/cm2 and maximum luminance of 0.74 cd/A at 4.31 m A/cm2 were obtained.

Crystal structures and thermal decomposition kinetics of lanthanide complexes with 3,4,5-trimethoxybenzoic acid and 1,10-phenanthroline

A series of lanthanide complexes with the 3,4,5-trimethoxybenzoic acid （3,4,5-tmoba） and 1,10-phenanthroline（phen）, [Ln（3,4,5-tmoba）3phen]2（Ln = Pr（l）, Nd （2） and Ho（3））, have been synthesized and characterized by a series of techniques including elemental analysis, IR spectra, X-ray crystallography and TG/DSC-FTIR technology. The three complexes have two kinds of coordination modes, in which the Pr3＋ and Nd3＋ cations are nine-coordinated and the Ho3＋ cation is eight-coordinated. The three-dimensional IR accumulation spectra of gaseous products for complexes 1-3 were analyzed and the gaseous products were identified by the typical IR spectra obtained from the 3D surface graphs. Meanwhile, we obtained the activation energy E of the first steps of complexes 1-3 by the integral isoconversional non-linear （NL-INT） method and discussed the non-isothermal kinetics of complexes 1-3 using the Malek method. Finally, SB（m, n） was defined as the kinetic method of the first-step thermal decomposition. The thermodynamic parameters △G≠, △H≠ and △S≠ of activation at the peak temperature were also calculated.