The binuclear complex Sm2(C12H8N2)2(C6H5COO)6 has been prepared and structurally analyzed by single crystal Xray diffraction. The complex crystallizes in the triclinic system, space group P1 , with a=10.833(2), b=11...The binuclear complex Sm2(C12H8N2)2(C6H5COO)6 has been prepared and structurally analyzed by single crystal Xray diffraction. The complex crystallizes in the triclinic system, space group P1 , with a=10.833(2), b=11.937(2), c=12.448(3) , = 104.97(3), = 93.63(3), = 113.27(3), V=1403.5 3, Dc=1.64g/cm3, =21.42cm-1, F(000)=690, Z=1, final R=0.037, Rw=0.077 for 4855 observed reflections I>2(I) and 5703 independent reflections. In the molecule, each Sm atom is coordinated by seven O atoms and two N atoms forming an irregular coordination polyhedron.展开更多
文摘The binuclear complex Sm2(C12H8N2)2(C6H5COO)6 has been prepared and structurally analyzed by single crystal Xray diffraction. The complex crystallizes in the triclinic system, space group P1 , with a=10.833(2), b=11.937(2), c=12.448(3) , = 104.97(3), = 93.63(3), = 113.27(3), V=1403.5 3, Dc=1.64g/cm3, =21.42cm-1, F(000)=690, Z=1, final R=0.037, Rw=0.077 for 4855 observed reflections I>2(I) and 5703 independent reflections. In the molecule, each Sm atom is coordinated by seven O atoms and two N atoms forming an irregular coordination polyhedron.
