A large set of commercially available amino compounds were assessed toward binding with cucurbit[10]uril(CB[10]),with the purpose of facilitating the isolation of pure CB[10].We found that the addition of a specific g...A large set of commercially available amino compounds were assessed toward binding with cucurbit[10]uril(CB[10]),with the purpose of facilitating the isolation of pure CB[10].We found that the addition of a specific guest into a relevant mixture of CB[n]allowed the displacement of CB[5]from CB[10]?CB[5].Subsequent washing of the resulting(G=guest)with dimethyl sulfoxide(DMSO),enabled to get pure CB[10]in a facile and highly efficient way.展开更多
基金supported by the National Natural Science Foundation of China (21472143, 21604066)Thousand Youth Talents Program of China (D1118031)Wuhan University of Science and Technology
文摘A large set of commercially available amino compounds were assessed toward binding with cucurbit[10]uril(CB[10]),with the purpose of facilitating the isolation of pure CB[10].We found that the addition of a specific guest into a relevant mixture of CB[n]allowed the displacement of CB[5]from CB[10]?CB[5].Subsequent washing of the resulting(G=guest)with dimethyl sulfoxide(DMSO),enabled to get pure CB[10]in a facile and highly efficient way.
