In order to present a new method for analyzing the reliability of a two-link flexible robot manipulator,Lagrange dynamics differential equations of the two-link flexible robot manipulator were established by using the...In order to present a new method for analyzing the reliability of a two-link flexible robot manipulator,Lagrange dynamics differential equations of the two-link flexible robot manipulator were established by using the integrated modal method and the multi-body system dynamics method.By using the Monte Carlo method,the random sample values of the dynamic parameters were obtained and Lagrange dynamics differential equations were solved for each random sample value which revealed their displacement,speed and acceleration.On this basis,dynamic stresses and deformations were obtained.By taking the maximum values of the stresses and the deformations as output responses and the random sample values of dynamic parameters as input quantities,extremum response surface functions were established.A number of random samples were then obtained by using the Monte Carlo method and then the reliability was analyzed by using the extremum response surface method.The results show that the extremum response surface method is an efficient and fast reliability analysis method with high-accuracy for the two-link flexible robot manipulator.展开更多
A hydrologic model consists of several parameters which are usually calibrated based on observed hy-drologic processes. Due to the uncertainty of the hydrologic processes, model parameters are also uncertain, which fu...A hydrologic model consists of several parameters which are usually calibrated based on observed hy-drologic processes. Due to the uncertainty of the hydrologic processes, model parameters are also uncertain, which further leads to the uncertainty of forecast results of a hydrologic model. Working with the Bayesian Forecasting System (BFS), Markov Chain Monte Carlo simulation based Adaptive Metropolis method (AM-MCMC) was used to study parameter uncertainty of Nash model, while the probabilistic flood forecasting was made with the simu-lated samples of parameters of Nash model. The results of a case study shows that the AM-MCMC based on BFS proposed in this paper is suitable to obtain the posterior distribution of the parameters of Nash model according to the known information of the parameters. The use of Nash model and AM-MCMC based on BFS was able to make the probabilistic flood forecast as well as to find the mean and variance of flood discharge, which may be useful to estimate the risk of flood control decision.展开更多
In the reliability analysis of slope, the performance functions derived from the most available stability analysis procedures of slopes are usually implicit and cannot be solved by first-order second-moment approach. ...In the reliability analysis of slope, the performance functions derived from the most available stability analysis procedures of slopes are usually implicit and cannot be solved by first-order second-moment approach. A new reliability analysis approach was presented based on three-dimensional Morgenstem-Price method to investigate three-dimensional effect of landslide in stability analyses. To obtain the reliability index, Support Vector Machine (SVM) was applied to approximate the performance function. The time-consuming of this approach is only 0.028% of that using Monte-Carlo method at the same computation accuracy. Also, the influence of time effect of shearing strength parameters of slope soils on the long-term reliability of three-dimensional slopes was investigated by this new approach. It is found that the reliability index of the slope would decrease by 52.54% and the failure probability would increase from 0.000 705% to 1.966%. In the end, the impact of variation coefficients of c andfon reliability index of slopes was taken into discussion and the changing trend was observed.展开更多
Based on nonlinear failure criterion,a three-dimensional failure mechanism of the possible collapse of deep tunnel is presented with limit analysis theory.Support pressure is taken into consideration in the virtual wo...Based on nonlinear failure criterion,a three-dimensional failure mechanism of the possible collapse of deep tunnel is presented with limit analysis theory.Support pressure is taken into consideration in the virtual work equation performed under the upper bound theorem.It is necessary to point out that the properties of surrounding rock mass plays a vital role in the shape of collapsing rock mass.The first order reliability method and Monte Carlo simulation method are then employed to analyze the stability of presented mechanism.Different rock parameters are considered random variables to value the corresponding reliability index with an increasing applied support pressure.The reliability indexes calculated by two methods are in good agreement.Sensitivity analysis was performed and the influence of coefficient variation of rock parameters was discussed.It is shown that the tensile strength plays a much more important role in reliability index than dimensionless parameter,and that small changes occurring in the coefficient of variation would make great influence of reliability index.Thus,significant attention should be paid to the properties of surrounding rock mass and the applied support pressure to maintain the stability of tunnel can be determined for a given reliability index.展开更多
Measurement uncertainty plays an important role in laser tracking measurement analyses. In the present work, the guides to the expression of uncertainty in measurement(GUM) uncertainty framework(GUF) and its supplemen...Measurement uncertainty plays an important role in laser tracking measurement analyses. In the present work, the guides to the expression of uncertainty in measurement(GUM) uncertainty framework(GUF) and its supplement, the Monte Carlo method, were used to estimate the uncertainty of task-specific laser tracker measurements. First, the sources of error in laser tracker measurement were analyzed in detail, including instruments, measuring network fusion, measurement strategies, measurement process factors(such as the operator), measurement environment, and task-specific data processing. Second, the GUM and Monte Carlo methods and their application to laser tracker measurement were presented. Finally, a case study involving the uncertainty estimation of a cylindricity measurement process using the GUF and Monte Carlo methods was illustrated. The expanded uncertainty results(at 95% confidence levels) obtained with the Monte Carlo method are 0.069 mm(least-squares criterion) and 0.062 mm(minimum zone criterion), respectively, while with the GUM uncertainty framework, none but the result of least-squares criterion can be got, which is 0.071 mm. Thus, the GUM uncertainty framework slightly underestimates the overall uncertainty by 10%. The results demonstrate that the two methods have different characteristics in task-specific uncertainty evaluations of laser tracker measurements. The results indicate that the Monte Carlo method is a practical tool for applying the principle of propagation of distributions and does not depend on the assumptions and limitations required by the law of propagation of uncertainties(GUF). These features of the Monte Carlo method reduce the risk of an unreliable measurement of uncertainty estimation, particularly in cases of complicated measurement models, without the need to evaluate partial derivatives. In addition, the impact of sampling strategy and evaluation method on the uncertainty of the measurement results can also be taken into account with Monte Carlo method, which plays a guiding role in measurement planning.展开更多
The combination of Morgenstern-Price Method (MPM) with Response Surface Method (RSM) improves the eonventional RSM by replacing Finite-Element Method (FEM) with MPM, which is a type of reliability analysis metho...The combination of Morgenstern-Price Method (MPM) with Response Surface Method (RSM) improves the eonventional RSM by replacing Finite-Element Method (FEM) with MPM, which is a type of reliability analysis method-RSM based on MPM, and makes the computing process simpler. The stability of the slope was re-evaluated by use of Monte Carlo method (MCM) and the result contrasted with the fore is the conclusion. The reliability analysis of the artificial slope in Donggang Power Station was carried on, and obtained the reliable charaeteristics, which provided basis for the project.展开更多
Several algorithms were proposed relating to the development of a framework of the perturbation-based stochastic finite element method (PSFEM) for large variation nonlinear dynamic problems. For this purpose, algorith...Several algorithms were proposed relating to the development of a framework of the perturbation-based stochastic finite element method (PSFEM) for large variation nonlinear dynamic problems. For this purpose, algorithms and a framework related to SFEM based on the stochastic virtual work principle were studied. To prove the validity and practicality of the algorithms and framework, numerical examples for nonlinear dynamic problems with large variations were calculated and compared with the Monte-Carlo Simulation method. This comparison shows that the proposed approaches are accurate and effective for the nonlinear dynamic analysis of structures with random parameters.展开更多
To further test whether polynitriprismanes are capable of being potential high energy density materials (HEDMs), extensive theoretical calculations were carried out to investigate on a series of polynitrotriprisman...To further test whether polynitriprismanes are capable of being potential high energy density materials (HEDMs), extensive theoretical calculations were carried out to investigate on a series of polynitrotriprismanes (PNNPs): C6H6-.(NO2). (n=1-6) Heats of formation (HOFs), strain energies (SE), and disproportionation energy (DE) were obtained using B3LYP/6-311+G(2df, 2p)//B3LYP/6-31G* method by designing different isodesmic reactions, respectively. Detonation properties of PNNPs were obtained by the well-known KAMLET-JACOBS equations, using the predicted densities (p) obtained by Monte Carlo method and HOFs. It is found that they increase as the number of nitro groups n varies from 1 to 6, and PNNPs with n〉4 have excellent detonation properties The relative stability and the pyrolysis mechanism of PNNPs were evaluated by the calculated bond dissociation energy (BDE). The comparison of BDE suggests that rupturing the C--C bond is the trigger for thermolysis of PNNPs. The computed BDE for cleavage of C--C bond (88.5 kJ/mol) further demonstrates that only the hexa-nitrotriprismane can be considered to be the target of HEDMs.展开更多
To overcome the excessive computational cost and/or bad accuracy of traditional approaches,the probabilistic density evolution method(PDEM) is introduced.The dynamic reliability of a double-layer cylindrical latticed ...To overcome the excessive computational cost and/or bad accuracy of traditional approaches,the probabilistic density evolution method(PDEM) is introduced.The dynamic reliability of a double-layer cylindrical latticed shell is evaluated by applying PDEM and Monte Carlo Method(MCM) respectively,and four apparent wave velocities(100 m/s,500 m/s,800 m/s and 1 200 m/s) and five thresholds(0.1 m,0.2 m,0.3 m,0.4 m and 0.5 m) are taken into consideration.Only the difference between threshold and maximal deformation...展开更多
In this paper, a sensing model for the coverage analysis of wireless sensor networks is provided. Using this model and Monte Carlo method, the ratio of private range to sensing range required to obtain the desired cov...In this paper, a sensing model for the coverage analysis of wireless sensor networks is provided. Using this model and Monte Carlo method, the ratio of private range to sensing range required to obtain the desired coverage can be derived considering the scale of deployment area and the number of sensor nodes. Base on the coverage analysis, an energy-efficient distributed node scheduling scheme is proposed to prolong the network lifetime while maintaining the desired sensing coverage, which does not need the geographic or neighbor information of nodes. The proposed scheme can also handle uneven distribution, and it is robust against node failures. Theoretical and simulation results demonstrate its efficiency and usefulness.展开更多
Efficient modelling approaches capable of predicting the behavior and effects of nanoparticles in cement-based materials are required for conducting relevant experiments.From the microstructural characterization of a ...Efficient modelling approaches capable of predicting the behavior and effects of nanoparticles in cement-based materials are required for conducting relevant experiments.From the microstructural characterization of a cement-nanoparticle system,this paper investigates the potential of cell-based weighted random-walk method to establish statistically significant relationships between chemical bonding and diffusion processes of nanoparticles within cement matrix.LaSr_(0.5)C_(0.5)O_(3)(LSCO)nanoparticles were employed to develop a discrete event system that accounts for the behavior of individual cells where nanoparticles and cement components were expected to interact.The stochastic model is based on annihilation(loss)and creation(gain)of a bond in the cell.The model considers both chemical reactions and transport mechanism of nanoparticles from cementitious cells,along with cement hydration process.This approach may be useful for simulating nanoparticle transport in complex 2D cement-based materials systems.展开更多
Presented is a new testing system based on using the factor models and self-organizing feature maps as well as the method of filtering undesirable environment influence. Testing process is described by the factor mode...Presented is a new testing system based on using the factor models and self-organizing feature maps as well as the method of filtering undesirable environment influence. Testing process is described by the factor model with simplex structure, which represents the influences of genetics and environmental factors on the observed parameters - the answers to the questions of the test subjects in one case and for the time, which is spent on responding to each test question to another. The Monte Carlo method is applied to get sufficient samples for training self-organizing feature maps, which are used to estimate model goodness-of-fit measures and, consequently, ability level. A prototype of the system is implemented using the Raven's Progressive Matrices (Advanced Progressive Matrices) - an intelligence test of abstract reasoning. Elimination of environment influence results is performed by comparing the observed and predicted answers to the test tasks using the Kalman filter, which is adapted to solve the problem. The testing procedure is optimized by reducing the number of tasks using the distribution of measures to belong to different ability levels after performing each test task provided the required level of conclusion reliability is obtained.展开更多
The current situation and difficulties of the structural system reliability analysis are mentioned. Then on the basis of Monte Carlo method and computer simulation, a new analysis method reduced expanding load method ...The current situation and difficulties of the structural system reliability analysis are mentioned. Then on the basis of Monte Carlo method and computer simulation, a new analysis method reduced expanding load method (RELM) is presented, which can be used to solve structural reliability problems effectively and conveniently. In this method, the uncertainties of loads, structural material properties and dimensions can be fully considered. If the statistic parameters of stochastic variables are known, by using this method, the probability of failure can be estimated rather accurately. In contrast with traditional approaches,RELM method gives a much better understanding of structural failure frequency and its reliability index β is more meaningful.To illustrate this new idea, a specific example is given.展开更多
Three simple analytic expressions satisfying the limitation condition at low densities for the radial distribution function of hard spheres are developed in terms of a polynomial expansion of nonlinear base functions ...Three simple analytic expressions satisfying the limitation condition at low densities for the radial distribution function of hard spheres are developed in terms of a polynomial expansion of nonlinear base functions and the Carnahan-Starling equation of state. The simplicity and precision for these expressions are superior to the well-known Percus Yevick expression. The coefficients contained in these expressions have been determined by fitting the Monte Carlo data for the first coordination shell, and by fitting both the Monte Carlo data and the numerical results of PercusYevick expression for the second coordination shell. One of the expressions has been applied to develop an analytic equation of state for the square-well fluid, and the numerical results are in good agreement with the computer simulation data.展开更多
基金Project(2006AA04Z405) supported by the National High Technology Research and Development Program of ChinaProject(3102019) supported by Beijing Municipal Natural Science Foundation,China
文摘In order to present a new method for analyzing the reliability of a two-link flexible robot manipulator,Lagrange dynamics differential equations of the two-link flexible robot manipulator were established by using the integrated modal method and the multi-body system dynamics method.By using the Monte Carlo method,the random sample values of the dynamic parameters were obtained and Lagrange dynamics differential equations were solved for each random sample value which revealed their displacement,speed and acceleration.On this basis,dynamic stresses and deformations were obtained.By taking the maximum values of the stresses and the deformations as output responses and the random sample values of dynamic parameters as input quantities,extremum response surface functions were established.A number of random samples were then obtained by using the Monte Carlo method and then the reliability was analyzed by using the extremum response surface method.The results show that the extremum response surface method is an efficient and fast reliability analysis method with high-accuracy for the two-link flexible robot manipulator.
基金Under the auspices of National Natural Science Foundation of China (No. 50609005)Chinese Postdoctoral Science Foundation (No. 2009451116)+1 种基金Postdoctoral Foundation of Heilongjiang Province (No. LBH-Z08255)Foundation of Heilongjiang Province Educational Committee (No. 11451022)
文摘A hydrologic model consists of several parameters which are usually calibrated based on observed hy-drologic processes. Due to the uncertainty of the hydrologic processes, model parameters are also uncertain, which further leads to the uncertainty of forecast results of a hydrologic model. Working with the Bayesian Forecasting System (BFS), Markov Chain Monte Carlo simulation based Adaptive Metropolis method (AM-MCMC) was used to study parameter uncertainty of Nash model, while the probabilistic flood forecasting was made with the simu-lated samples of parameters of Nash model. The results of a case study shows that the AM-MCMC based on BFS proposed in this paper is suitable to obtain the posterior distribution of the parameters of Nash model according to the known information of the parameters. The use of Nash model and AM-MCMC based on BFS was able to make the probabilistic flood forecast as well as to find the mean and variance of flood discharge, which may be useful to estimate the risk of flood control decision.
基金Project(50878082) supported by the National Natural Science Foundation of ChinaProject(200631880237) supported by the Science and Technology Program of West Transportation of the Ministry of Transportation of ChinaKey Project(09JJ3104) supported by the Natural Science Foundation of Hunan Province, China
文摘In the reliability analysis of slope, the performance functions derived from the most available stability analysis procedures of slopes are usually implicit and cannot be solved by first-order second-moment approach. A new reliability analysis approach was presented based on three-dimensional Morgenstem-Price method to investigate three-dimensional effect of landslide in stability analyses. To obtain the reliability index, Support Vector Machine (SVM) was applied to approximate the performance function. The time-consuming of this approach is only 0.028% of that using Monte-Carlo method at the same computation accuracy. Also, the influence of time effect of shearing strength parameters of slope soils on the long-term reliability of three-dimensional slopes was investigated by this new approach. It is found that the reliability index of the slope would decrease by 52.54% and the failure probability would increase from 0.000 705% to 1.966%. In the end, the impact of variation coefficients of c andfon reliability index of slopes was taken into discussion and the changing trend was observed.
基金Project (2013CB036004) supported by National Basic Research Program of China
文摘Based on nonlinear failure criterion,a three-dimensional failure mechanism of the possible collapse of deep tunnel is presented with limit analysis theory.Support pressure is taken into consideration in the virtual work equation performed under the upper bound theorem.It is necessary to point out that the properties of surrounding rock mass plays a vital role in the shape of collapsing rock mass.The first order reliability method and Monte Carlo simulation method are then employed to analyze the stability of presented mechanism.Different rock parameters are considered random variables to value the corresponding reliability index with an increasing applied support pressure.The reliability indexes calculated by two methods are in good agreement.Sensitivity analysis was performed and the influence of coefficient variation of rock parameters was discussed.It is shown that the tensile strength plays a much more important role in reliability index than dimensionless parameter,and that small changes occurring in the coefficient of variation would make great influence of reliability index.Thus,significant attention should be paid to the properties of surrounding rock mass and the applied support pressure to maintain the stability of tunnel can be determined for a given reliability index.
基金Project(51318010402)supported by General Armament Department Pre-Research Program of China
文摘Measurement uncertainty plays an important role in laser tracking measurement analyses. In the present work, the guides to the expression of uncertainty in measurement(GUM) uncertainty framework(GUF) and its supplement, the Monte Carlo method, were used to estimate the uncertainty of task-specific laser tracker measurements. First, the sources of error in laser tracker measurement were analyzed in detail, including instruments, measuring network fusion, measurement strategies, measurement process factors(such as the operator), measurement environment, and task-specific data processing. Second, the GUM and Monte Carlo methods and their application to laser tracker measurement were presented. Finally, a case study involving the uncertainty estimation of a cylindricity measurement process using the GUF and Monte Carlo methods was illustrated. The expanded uncertainty results(at 95% confidence levels) obtained with the Monte Carlo method are 0.069 mm(least-squares criterion) and 0.062 mm(minimum zone criterion), respectively, while with the GUM uncertainty framework, none but the result of least-squares criterion can be got, which is 0.071 mm. Thus, the GUM uncertainty framework slightly underestimates the overall uncertainty by 10%. The results demonstrate that the two methods have different characteristics in task-specific uncertainty evaluations of laser tracker measurements. The results indicate that the Monte Carlo method is a practical tool for applying the principle of propagation of distributions and does not depend on the assumptions and limitations required by the law of propagation of uncertainties(GUF). These features of the Monte Carlo method reduce the risk of an unreliable measurement of uncertainty estimation, particularly in cases of complicated measurement models, without the need to evaluate partial derivatives. In addition, the impact of sampling strategy and evaluation method on the uncertainty of the measurement results can also be taken into account with Monte Carlo method, which plays a guiding role in measurement planning.
文摘The combination of Morgenstern-Price Method (MPM) with Response Surface Method (RSM) improves the eonventional RSM by replacing Finite-Element Method (FEM) with MPM, which is a type of reliability analysis method-RSM based on MPM, and makes the computing process simpler. The stability of the slope was re-evaluated by use of Monte Carlo method (MCM) and the result contrasted with the fore is the conclusion. The reliability analysis of the artificial slope in Donggang Power Station was carried on, and obtained the reliable charaeteristics, which provided basis for the project.
文摘Several algorithms were proposed relating to the development of a framework of the perturbation-based stochastic finite element method (PSFEM) for large variation nonlinear dynamic problems. For this purpose, algorithms and a framework related to SFEM based on the stochastic virtual work principle were studied. To prove the validity and practicality of the algorithms and framework, numerical examples for nonlinear dynamic problems with large variations were calculated and compared with the Monte-Carlo Simulation method. This comparison shows that the proposed approaches are accurate and effective for the nonlinear dynamic analysis of structures with random parameters.
基金Projects(2006DFA41090,2007DFA40680) supported by the International Cooperation Project on Traditional Chinese Medicines of Ministry of Science and Technology of ChinaProject(20475066) supported by the National Natural Science Foundation of China
文摘To further test whether polynitriprismanes are capable of being potential high energy density materials (HEDMs), extensive theoretical calculations were carried out to investigate on a series of polynitrotriprismanes (PNNPs): C6H6-.(NO2). (n=1-6) Heats of formation (HOFs), strain energies (SE), and disproportionation energy (DE) were obtained using B3LYP/6-311+G(2df, 2p)//B3LYP/6-31G* method by designing different isodesmic reactions, respectively. Detonation properties of PNNPs were obtained by the well-known KAMLET-JACOBS equations, using the predicted densities (p) obtained by Monte Carlo method and HOFs. It is found that they increase as the number of nitro groups n varies from 1 to 6, and PNNPs with n〉4 have excellent detonation properties The relative stability and the pyrolysis mechanism of PNNPs were evaluated by the calculated bond dissociation energy (BDE). The comparison of BDE suggests that rupturing the C--C bond is the trigger for thermolysis of PNNPs. The computed BDE for cleavage of C--C bond (88.5 kJ/mol) further demonstrates that only the hexa-nitrotriprismane can be considered to be the target of HEDMs.
基金Supported by National Natural Science Foundation of China (No.50478094)
文摘To overcome the excessive computational cost and/or bad accuracy of traditional approaches,the probabilistic density evolution method(PDEM) is introduced.The dynamic reliability of a double-layer cylindrical latticed shell is evaluated by applying PDEM and Monte Carlo Method(MCM) respectively,and four apparent wave velocities(100 m/s,500 m/s,800 m/s and 1 200 m/s) and five thresholds(0.1 m,0.2 m,0.3 m,0.4 m and 0.5 m) are taken into consideration.Only the difference between threshold and maximal deformation...
基金Supported by China Scholarship Council(No.201306255014)
文摘In this paper, a sensing model for the coverage analysis of wireless sensor networks is provided. Using this model and Monte Carlo method, the ratio of private range to sensing range required to obtain the desired coverage can be derived considering the scale of deployment area and the number of sensor nodes. Base on the coverage analysis, an energy-efficient distributed node scheduling scheme is proposed to prolong the network lifetime while maintaining the desired sensing coverage, which does not need the geographic or neighbor information of nodes. The proposed scheme can also handle uneven distribution, and it is robust against node failures. Theoretical and simulation results demonstrate its efficiency and usefulness.
基金Project(93021714)supported by the Iran National Science Foundation。
文摘Efficient modelling approaches capable of predicting the behavior and effects of nanoparticles in cement-based materials are required for conducting relevant experiments.From the microstructural characterization of a cement-nanoparticle system,this paper investigates the potential of cell-based weighted random-walk method to establish statistically significant relationships between chemical bonding and diffusion processes of nanoparticles within cement matrix.LaSr_(0.5)C_(0.5)O_(3)(LSCO)nanoparticles were employed to develop a discrete event system that accounts for the behavior of individual cells where nanoparticles and cement components were expected to interact.The stochastic model is based on annihilation(loss)and creation(gain)of a bond in the cell.The model considers both chemical reactions and transport mechanism of nanoparticles from cementitious cells,along with cement hydration process.This approach may be useful for simulating nanoparticle transport in complex 2D cement-based materials systems.
文摘Presented is a new testing system based on using the factor models and self-organizing feature maps as well as the method of filtering undesirable environment influence. Testing process is described by the factor model with simplex structure, which represents the influences of genetics and environmental factors on the observed parameters - the answers to the questions of the test subjects in one case and for the time, which is spent on responding to each test question to another. The Monte Carlo method is applied to get sufficient samples for training self-organizing feature maps, which are used to estimate model goodness-of-fit measures and, consequently, ability level. A prototype of the system is implemented using the Raven's Progressive Matrices (Advanced Progressive Matrices) - an intelligence test of abstract reasoning. Elimination of environment influence results is performed by comparing the observed and predicted answers to the test tasks using the Kalman filter, which is adapted to solve the problem. The testing procedure is optimized by reducing the number of tasks using the distribution of measures to belong to different ability levels after performing each test task provided the required level of conclusion reliability is obtained.
文摘The current situation and difficulties of the structural system reliability analysis are mentioned. Then on the basis of Monte Carlo method and computer simulation, a new analysis method reduced expanding load method (RELM) is presented, which can be used to solve structural reliability problems effectively and conveniently. In this method, the uncertainties of loads, structural material properties and dimensions can be fully considered. If the statistic parameters of stochastic variables are known, by using this method, the probability of failure can be estimated rather accurately. In contrast with traditional approaches,RELM method gives a much better understanding of structural failure frequency and its reliability index β is more meaningful.To illustrate this new idea, a specific example is given.
基金The project supported by National Natural Science Foundation of China under Grant Nos.19904002 and 10299040by the Science and Technology Foundation for the Youth of the University of Electronic Science and Technology of China under Grant No.YF020703
文摘Three simple analytic expressions satisfying the limitation condition at low densities for the radial distribution function of hard spheres are developed in terms of a polynomial expansion of nonlinear base functions and the Carnahan-Starling equation of state. The simplicity and precision for these expressions are superior to the well-known Percus Yevick expression. The coefficients contained in these expressions have been determined by fitting the Monte Carlo data for the first coordination shell, and by fitting both the Monte Carlo data and the numerical results of PercusYevick expression for the second coordination shell. One of the expressions has been applied to develop an analytic equation of state for the square-well fluid, and the numerical results are in good agreement with the computer simulation data.