In this paper,organic montmorillonite(OMMT)was added into crumb rubber modified asphalt(CRMA)to improve its high temperature performance,anti-aging performance and storage stability.The effects of different OMMT conte...In this paper,organic montmorillonite(OMMT)was added into crumb rubber modified asphalt(CRMA)to improve its high temperature performance,anti-aging performance and storage stability.The effects of different OMMT content on properties of CRMA were studied.The rutting factor obtained by dynamic shear rheological(DSR)test was adopted to evaluate the high-temperature performance.The creep stiffness and m value determined by the bending beam rheometer(BBR)test were employed to evaluate the low-temperature performance.The softening point,ductility,rutting factor before and after rolling thin film ovens test(RTFOT)and pressure aging vessel test(PAV)were compared to characterize the aging properties.Moreover,the segregation test after being reserved for 48 h and 7 d was conducted,and the softening point and rutting factor of upper and lower layers of segregation pipe were adopted to evaluate the storage stability.The results indicated that the high-temperature performance and anti-aging performance were developed with the increasing content of OMMT,while the low-temperature performance deteriorated.The storage stability was improved with the increasing content of OMMT before the content exceeded 4%,after which the storage stability declined.Taking account of all factors,it is suggested that the optimum content of OMMT is 3%−4%.展开更多
The consumption ofthermoset resins as building polymers is approximately over one million tone word wide. The thermoset resins are proven construction materials for the technical and highly demanding applications of t...The consumption ofthermoset resins as building polymers is approximately over one million tone word wide. The thermoset resins are proven construction materials for the technical and highly demanding applications of the transportation, electrical and building part industry. Heat stability, high thermal, low shrinkage, excellent mechanical properties are typical for their type of polymers. Above applications in addition to the mechanical properties also require good flame retardants of the materials. Undertaken activities refer to official draft, laws and legal recommendations in UE states. This paper presents positive effect of reduced flammability of thermoset resins （unsaturated polyester and epoxy resins） thanks to the use of nanocomposites containing multi-ingredient halogen-flee flame retardants which combine conventional phosphorus/nitrogen modifiers interacting with nanofillers （oMMT （organomodified montmorillonite）, EG （expandable graphite）, graphene, GO （graphene oxide）, nSi （nanosilica））.展开更多
Composites of montmorillonite clay and sawdust were prepared with the desired result being having new materials which burn longer than unmodified sawdust. The three forms of clay used for preparation of composites wer...Composites of montmorillonite clay and sawdust were prepared with the desired result being having new materials which burn longer than unmodified sawdust. The three forms of clay used for preparation of composites were unmodified montmorillonite, mono-ionic montmorillonite and organically modified montmorillonite. Montmorillonite clay was converted to mono-ionic clay by ion exchange with sodium using a sodium chloride solution. The mono-ionic clay was organically modified with an organic surfactant, methyl triphenyl phosphonium bromide. Nanocomposites were then prepared by combining the modified and raw forms of the clay with sawdust. The solution blending method was used to make the nanocomposites. The samples were analysed using thermogravimetric analysis and cone calorimetry. The studies showed that the nanocomposite which was made from sawdust and 1% organically modified clay had the most improved results in terms of burning time and thermal stability, as well as giving a calorific value closest to unmodified sawdust and the least amount of residue.展开更多
Lithium-based montmorillonite(Li-MMT)was prepared by inorganic modification of sodiumbased montmorillonite(Na-MMT)using the ion-exchange method under microwave-enhanced conditions.The ionic conductivity of Li-MMT was ...Lithium-based montmorillonite(Li-MMT)was prepared by inorganic modification of sodiumbased montmorillonite(Na-MMT)using the ion-exchange method under microwave-enhanced conditions.The ionic conductivity of Li-MMT was explored at different temperatures,humidities,and exchange ratios.The results showed that the modified materials all exhibited temperature-and humidity-dependent changes in ionic conductivity.When the mass ratio of Na-MMT and anhydrous lithium chloride(LiCl)was 1∶1,Li-MMT exhibited excellent ionic conductivity,with an ionic conductivity of 9.81×10^(-5)S·cm^(-1)for Na-MMT at 40%RH(relative humidity)and 60℃,and ionic conductivity of 4.15×10^(-4)S·cm^(-1)for Li-MMT-1(exchange ratio of Na-MMT and anhydrous LiCl was 1∶1).This modification method is simple and inexpensive as well as provides an effective method to improve the electrical conductivity of Na-MMT.展开更多
基金Supported by the National Natural Science Foundation of China(5097806750778049+3 种基金51121062)the Ministry of Science and Technology of China(2009AA06Z3102009ZX074240052009ZX07424-006)
基金Projects(51838001,51878070,51908069)supported by the National Natural Science Foundation of China。
文摘In this paper,organic montmorillonite(OMMT)was added into crumb rubber modified asphalt(CRMA)to improve its high temperature performance,anti-aging performance and storage stability.The effects of different OMMT content on properties of CRMA were studied.The rutting factor obtained by dynamic shear rheological(DSR)test was adopted to evaluate the high-temperature performance.The creep stiffness and m value determined by the bending beam rheometer(BBR)test were employed to evaluate the low-temperature performance.The softening point,ductility,rutting factor before and after rolling thin film ovens test(RTFOT)and pressure aging vessel test(PAV)were compared to characterize the aging properties.Moreover,the segregation test after being reserved for 48 h and 7 d was conducted,and the softening point and rutting factor of upper and lower layers of segregation pipe were adopted to evaluate the storage stability.The results indicated that the high-temperature performance and anti-aging performance were developed with the increasing content of OMMT,while the low-temperature performance deteriorated.The storage stability was improved with the increasing content of OMMT before the content exceeded 4%,after which the storage stability declined.Taking account of all factors,it is suggested that the optimum content of OMMT is 3%−4%.
文摘The consumption ofthermoset resins as building polymers is approximately over one million tone word wide. The thermoset resins are proven construction materials for the technical and highly demanding applications of the transportation, electrical and building part industry. Heat stability, high thermal, low shrinkage, excellent mechanical properties are typical for their type of polymers. Above applications in addition to the mechanical properties also require good flame retardants of the materials. Undertaken activities refer to official draft, laws and legal recommendations in UE states. This paper presents positive effect of reduced flammability of thermoset resins （unsaturated polyester and epoxy resins） thanks to the use of nanocomposites containing multi-ingredient halogen-flee flame retardants which combine conventional phosphorus/nitrogen modifiers interacting with nanofillers （oMMT （organomodified montmorillonite）, EG （expandable graphite）, graphene, GO （graphene oxide）, nSi （nanosilica））.
文摘Composites of montmorillonite clay and sawdust were prepared with the desired result being having new materials which burn longer than unmodified sawdust. The three forms of clay used for preparation of composites were unmodified montmorillonite, mono-ionic montmorillonite and organically modified montmorillonite. Montmorillonite clay was converted to mono-ionic clay by ion exchange with sodium using a sodium chloride solution. The mono-ionic clay was organically modified with an organic surfactant, methyl triphenyl phosphonium bromide. Nanocomposites were then prepared by combining the modified and raw forms of the clay with sawdust. The solution blending method was used to make the nanocomposites. The samples were analysed using thermogravimetric analysis and cone calorimetry. The studies showed that the nanocomposite which was made from sawdust and 1% organically modified clay had the most improved results in terms of burning time and thermal stability, as well as giving a calorific value closest to unmodified sawdust and the least amount of residue.
基金supported by the National Natural Science Foundation of China(22322102)Science and Technology Project of State Grid Jilin Electric Power Co.,Ltd(2023-07).
文摘Lithium-based montmorillonite(Li-MMT)was prepared by inorganic modification of sodiumbased montmorillonite(Na-MMT)using the ion-exchange method under microwave-enhanced conditions.The ionic conductivity of Li-MMT was explored at different temperatures,humidities,and exchange ratios.The results showed that the modified materials all exhibited temperature-and humidity-dependent changes in ionic conductivity.When the mass ratio of Na-MMT and anhydrous lithium chloride(LiCl)was 1∶1,Li-MMT exhibited excellent ionic conductivity,with an ionic conductivity of 9.81×10^(-5)S·cm^(-1)for Na-MMT at 40%RH(relative humidity)and 60℃,and ionic conductivity of 4.15×10^(-4)S·cm^(-1)for Li-MMT-1(exchange ratio of Na-MMT and anhydrous LiCl was 1∶1).This modification method is simple and inexpensive as well as provides an effective method to improve the electrical conductivity of Na-MMT.
