High purity (99.999% or 5N, mass fraction) indium (In) was obtained through vacuum distillation using a 2N (99%) In as input material under a dynamic vacuum of 5 Pa. The glow discharge mass spectrometry (GDMS)...High purity (99.999% or 5N, mass fraction) indium (In) was obtained through vacuum distillation using a 2N (99%) In as input material under a dynamic vacuum of 5 Pa. The glow discharge mass spectrometry (GDMS) was applied for the analysis of input material and the distilled indium. The results indicate that high-volatile impurities namely Cd, Zn, T1 and Pb can be removed from the indium matrix at the low fraction stage of 1 223 K for 120 min; Low-volatile impurities such as Fe, Ni, Cu, Sn can be reduced at the high fraction stage of 1 323 K for 120 min. The separation coefficient ,8i and activity coefficient Yi of impurities are calculated according to the experiments to fill the inadequate data of the thermodynamics.展开更多
Daily climate data at 110 stations during 1961-2010 were selected to examine the changing characteristics of climate factors and extreme climate events in South China. The annual mean surface air temperature has incre...Daily climate data at 110 stations during 1961-2010 were selected to examine the changing characteristics of climate factors and extreme climate events in South China. The annual mean surface air temperature has increased significantly by 0.16℃ per decade, most notably in the Pearl River Delta and in winter. The increase rate of the annual extreme minimum temperature (0.48℃ per decade) is over twice that of the annual extreme maximum temperature (0.20℃ per decade), and the increase of the mean temperature is mainly the result of the increase of the extreme minimum temperature. The increase rate of high-temperature days (1.1 d per decade) is close to the decrease rate of low-temperature days (-1.3 d per decade). The rainfall has not shown any significant trend, but the number of rainy days has decreased and the rain intensity has increased. The regional mean sunshine duration has a significant decreasing trend of -40.9 h per decade, and the number of hazy days has a significant increasing trend of 6.3 d per decade. The decrease of sunshine duration is mainly caused by the increase of total cloud, not by the increase of hazy days in South China. Both the regional mean pan evaporation and mean wind speed have significant decreasing trends of -65.9 mm per decade and -0.11 m s-1 per decade, respectively. The decrease of both sunshine duration and mean wind speed plays an important role in the decrease of pan evaporation. The number of landing tropical cyclones has an insignificant decreasing trend of -0.6 per decade, but their intensities show a weak increasing trend. The formation location of tropical cyclones landing in South China has converged towards 10-19°N, and the landing position has shown a northward trend. The date of the first landfall tropical cyclone postpones 1.8 d per decade, and the date of the last landfall advances 3.6 d per decade, resulting in reduction of the typhoon season by 5.4 d per decade.展开更多
When a liquid undergoes sudden reduction in the surrounding pressure below its saturation pressure, the liquid then enters in a metastable state. In order to regain equilibrium, part of the liquid evaporates quickly i...When a liquid undergoes sudden reduction in the surrounding pressure below its saturation pressure, the liquid then enters in a metastable state. In order to regain equilibrium, part of the liquid evaporates quickly in a phenomenon called "flash evaporation", and the excess sensible heat contained in the liquid is converted into latent heat of vaporization. Therefore, temperatures of both the liquid and the generated vapor decline to the saturation temperature for the reduced pressure. As the heat and mass transfer occur in direct contact between the liquid and its own vapors, the process involves a very high heat transfer rate which makes it suitable for exchanging heat between sources of relatively small temperature difference. Moreover, dispensability of the heat exchange surfaces in this process is a considerable advantage as these surfaces constitute major part of the total system expenses in addition to the associated maintenance problems, especially when dealing with corrosive fluids such like seawater in the thermal desalination processes and in the OTEC (ocean thermal energy conversion) systems. This paper reports on the heat flux variation profiles during the flash evaporation of superheated water jets at various flow conditions. Heat flax was found to grow with time attaining a peak value before it starts to decrease monotonically.展开更多
Thickness of falling water film out of tubes is one of critical factors of heat transfer of evaporative air cooler. A new method of resistance measurement was developed to measure thickness of the film. When the resis...Thickness of falling water film out of tubes is one of critical factors of heat transfer of evaporative air cooler. A new method of resistance measurement was developed to measure thickness of the film. When the resistance probe on the tip of micrometer touches the surface and bottom of the film, two corresponding sudden reductions of resistance occurs, and the difference of two graduations on the micrometer displays the thickness of the film. The film thickness of eleven angles was measured in five kinds of water flows and results varies from 0.8933mm to 1.7233 mm. Mean thickness and mean heat transfer coefficient of the film out of the tube was calculated.展开更多
The coke plant of a steel plant corresponds to the area that transforms a blend of coal into coke for using in blast furnace and steam to power plant. The coking plant of ThyssenKrupp CSA uses the heat recovery techno...The coke plant of a steel plant corresponds to the area that transforms a blend of coal into coke for using in blast furnace and steam to power plant. The coking plant of ThyssenKrupp CSA uses the heat recovery technology with stamping charger for stamping and preparation a blend of coals for charging and coking. Stamping technology adds several benefits to the process, such as increased density, homogeneity and alignment of the coal cake charged into the oven, as well as provides better control of the coking process, improves parameters of coke quality and allows coal blending with lower coking power, thereby reducing the production cost of coke and power generation. Through the automation of stamping charger, it is possible to evaluate and calculate the stamped coal density charged and the productivity gains this system provides.展开更多
The paper presents a general distributed model of a vertical U-tube direct expansion heat exchanger coupled with the ground. This model is developed for studying the dynamic thermal behavior of a buried heat exchanger...The paper presents a general distributed model of a vertical U-tube direct expansion heat exchanger coupled with the ground. This model is developed for studying the dynamic thermal behavior of a buried heat exchanger which is an integral part of a so-called direct expansion heat pump. The transient conservative equations of mass, momentum and energy considering single and two-phase flow of refrigerant are derived and presented. The diffusive heat exchange with the ground is treated using an analytical approach to treat short-time scale response of vertical boreholes based on an imposed temperature. The thermal interference between the two pipes of the heat exchanger is also considered. The mathematical equations of the model are numerically presented using a control volume formulation and the solution of the system of equations is obtained by successive iterations. The dynamic behavior of the evaporator is simulated and the numerical results are analyzed regarding spatial parameters distribution and thermal interference influence.展开更多
Interfacial solar-steam generation is a promising and cost-effective technology for both desalination and wastewater treatment.This process uses a photothermal evaporator to absorb sunlight and convert it into heat fo...Interfacial solar-steam generation is a promising and cost-effective technology for both desalination and wastewater treatment.This process uses a photothermal evaporator to absorb sunlight and convert it into heat for water evaporation.However solar-steam generation can be somewhat inefficient due to energy losses via conduction,convection and radiation.Thus,efficient energy management is crucial for optimizing the performance of solar-steam generation.Here,via elaborate design of the configuration of photothermal materials,as well as warm and cold evaporation surfaces,performance in solar evaporation was significantly enhanced.This was achieved via a simultaneous reduction in energy loss with a net increase in energy gain from the environment,and recycling of the latent heat released from vapor condensation,diffusive reflectance,thermal radiation and convection from the evaporation surface.Overall,by using the new strategy,an evaporation rate of 2.94 kg m^-2 h^-1,with a corresponding energy efficiency of solar-steam generation beyond theoretical limit was achieved.展开更多
基金Project(2009AA003) supported by Science and Technology Innovation Plan of Yunnan Province, China
文摘High purity (99.999% or 5N, mass fraction) indium (In) was obtained through vacuum distillation using a 2N (99%) In as input material under a dynamic vacuum of 5 Pa. The glow discharge mass spectrometry (GDMS) was applied for the analysis of input material and the distilled indium. The results indicate that high-volatile impurities namely Cd, Zn, T1 and Pb can be removed from the indium matrix at the low fraction stage of 1 223 K for 120 min; Low-volatile impurities such as Fe, Ni, Cu, Sn can be reduced at the high fraction stage of 1 323 K for 120 min. The separation coefficient ,8i and activity coefficient Yi of impurities are calculated according to the experiments to fill the inadequate data of the thermodynamics.
基金supported by the Special Climate Change Research Program of China Meteorological Administration (No. CCSF-09-11, CCSF-09-03, CCSF2011-25, and CCSF201211)the Science and Technology Planning Project of Guangdong province (No.2011A030200021)
文摘Daily climate data at 110 stations during 1961-2010 were selected to examine the changing characteristics of climate factors and extreme climate events in South China. The annual mean surface air temperature has increased significantly by 0.16℃ per decade, most notably in the Pearl River Delta and in winter. The increase rate of the annual extreme minimum temperature (0.48℃ per decade) is over twice that of the annual extreme maximum temperature (0.20℃ per decade), and the increase of the mean temperature is mainly the result of the increase of the extreme minimum temperature. The increase rate of high-temperature days (1.1 d per decade) is close to the decrease rate of low-temperature days (-1.3 d per decade). The rainfall has not shown any significant trend, but the number of rainy days has decreased and the rain intensity has increased. The regional mean sunshine duration has a significant decreasing trend of -40.9 h per decade, and the number of hazy days has a significant increasing trend of 6.3 d per decade. The decrease of sunshine duration is mainly caused by the increase of total cloud, not by the increase of hazy days in South China. Both the regional mean pan evaporation and mean wind speed have significant decreasing trends of -65.9 mm per decade and -0.11 m s-1 per decade, respectively. The decrease of both sunshine duration and mean wind speed plays an important role in the decrease of pan evaporation. The number of landing tropical cyclones has an insignificant decreasing trend of -0.6 per decade, but their intensities show a weak increasing trend. The formation location of tropical cyclones landing in South China has converged towards 10-19°N, and the landing position has shown a northward trend. The date of the first landfall tropical cyclone postpones 1.8 d per decade, and the date of the last landfall advances 3.6 d per decade, resulting in reduction of the typhoon season by 5.4 d per decade.
文摘When a liquid undergoes sudden reduction in the surrounding pressure below its saturation pressure, the liquid then enters in a metastable state. In order to regain equilibrium, part of the liquid evaporates quickly in a phenomenon called "flash evaporation", and the excess sensible heat contained in the liquid is converted into latent heat of vaporization. Therefore, temperatures of both the liquid and the generated vapor decline to the saturation temperature for the reduced pressure. As the heat and mass transfer occur in direct contact between the liquid and its own vapors, the process involves a very high heat transfer rate which makes it suitable for exchanging heat between sources of relatively small temperature difference. Moreover, dispensability of the heat exchange surfaces in this process is a considerable advantage as these surfaces constitute major part of the total system expenses in addition to the associated maintenance problems, especially when dealing with corrosive fluids such like seawater in the thermal desalination processes and in the OTEC (ocean thermal energy conversion) systems. This paper reports on the heat flux variation profiles during the flash evaporation of superheated water jets at various flow conditions. Heat flax was found to grow with time attaining a peak value before it starts to decrease monotonically.
基金Acknowledgments: The study is one of branches of a key project of Chinese National Programs for Foundation Research and Development, thanks for the supporting from the National Nature Science Foundation. The new method to measure thickness of wager film has applied an utility model patent in China (No. 200620098211.4).
文摘Thickness of falling water film out of tubes is one of critical factors of heat transfer of evaporative air cooler. A new method of resistance measurement was developed to measure thickness of the film. When the resistance probe on the tip of micrometer touches the surface and bottom of the film, two corresponding sudden reductions of resistance occurs, and the difference of two graduations on the micrometer displays the thickness of the film. The film thickness of eleven angles was measured in five kinds of water flows and results varies from 0.8933mm to 1.7233 mm. Mean thickness and mean heat transfer coefficient of the film out of the tube was calculated.
文摘The coke plant of a steel plant corresponds to the area that transforms a blend of coal into coke for using in blast furnace and steam to power plant. The coking plant of ThyssenKrupp CSA uses the heat recovery technology with stamping charger for stamping and preparation a blend of coals for charging and coking. Stamping technology adds several benefits to the process, such as increased density, homogeneity and alignment of the coal cake charged into the oven, as well as provides better control of the coking process, improves parameters of coke quality and allows coal blending with lower coking power, thereby reducing the production cost of coke and power generation. Through the automation of stamping charger, it is possible to evaluate and calculate the stamped coal density charged and the productivity gains this system provides.
文摘The paper presents a general distributed model of a vertical U-tube direct expansion heat exchanger coupled with the ground. This model is developed for studying the dynamic thermal behavior of a buried heat exchanger which is an integral part of a so-called direct expansion heat pump. The transient conservative equations of mass, momentum and energy considering single and two-phase flow of refrigerant are derived and presented. The diffusive heat exchange with the ground is treated using an analytical approach to treat short-time scale response of vertical boreholes based on an imposed temperature. The thermal interference between the two pipes of the heat exchanger is also considered. The mathematical equations of the model are numerically presented using a control volume formulation and the solution of the system of equations is obtained by successive iterations. The dynamic behavior of the evaporator is simulated and the numerical results are analyzed regarding spatial parameters distribution and thermal interference influence.
基金financial support from Australian Research Council(ARC Future Fellowship FT190100485)University of South Australia(Foundation Fellow)China Scholarship Council and Huasheng Graphite Co.,Ltd。
文摘Interfacial solar-steam generation is a promising and cost-effective technology for both desalination and wastewater treatment.This process uses a photothermal evaporator to absorb sunlight and convert it into heat for water evaporation.However solar-steam generation can be somewhat inefficient due to energy losses via conduction,convection and radiation.Thus,efficient energy management is crucial for optimizing the performance of solar-steam generation.Here,via elaborate design of the configuration of photothermal materials,as well as warm and cold evaporation surfaces,performance in solar evaporation was significantly enhanced.This was achieved via a simultaneous reduction in energy loss with a net increase in energy gain from the environment,and recycling of the latent heat released from vapor condensation,diffusive reflectance,thermal radiation and convection from the evaporation surface.Overall,by using the new strategy,an evaporation rate of 2.94 kg m^-2 h^-1,with a corresponding energy efficiency of solar-steam generation beyond theoretical limit was achieved.