铯蒸气点火型TEC的研究

一、概 述 TEC是一种利用热阴极发射电子效应的将热能直接转换为电能的器件,其工作原理如图1所示。热阴极发射的电子被冷阳极接收后,经外电路作功回到阴极。这样,电子在两个热源之间形成闭合循环,直接将热能转变为电能。

蒸气双效型溴化锂吸收式制冷机的应用

1 前言我厂原采用离心式制冷机组制取化产回收工序中使用的冷水。由于离心式制冷机电耗大,而且近几年来故障多,维修费用高,加之离心式制冷机使用的氟利昂制冷剂会对臭氧层造成破坏,因此,我厂在2002年5月在33孔焦炉扩容改造工程中,采用2台蒸气双效型溴化锂吸收式制冷机取代了原来的3台离心式制冷机。2

KZL4——1.3AⅡ型蒸气锅炉提高出力的措施

KZL4—1.3AII型锅炉是快装、单锅筒、纵置式、链条炉中比较具有代表性的一种。链条炉产生至今已有百余年历史,是一种结构比较完善的层燃炉,由于其加煤、清渣、除灰等主要操作过程都实现了机械化,且运行稳定可靠,不仅在中小电厂和容量较大的供热锅炉中普遍使用,而且在1t/h以上的小型锅炉上广泛使用。

SIMULATION OF THE PHYSIOLOGICAL RESPONSES OF C 3 PLANT LEAVES TO ENVIRONMENTAL FACTORS BY A MODEL WHICH COMBINES STOMATAL CONDUCTANCE, PHOTOSYNTHESIS AND TRANSPIRATION

Transpiration element is included in the integrated stomatal conductance photosynthesis model by considering gaseous transfer processes, so the present model is capable to simulate the influence of boundary layer conductance. Leuning in his revised Ball's model replaced relative humidity with VPD s (the vapor pressure deficit from stomatal pore to leaf surface) and thereby made the relation with transpiration more straightforward, and made it possible for the regulation of transpiration and the influence of boundary layer conductance to be integrated into the combined model. If the differences in water vapor and CO 2 concentration between leaf and ambient air are considered, VPD s , the evaporative demand, is influenced by stomatal and boundary layer conductance. The physiological responses of photosynthesis, transpiration, and stomatal function, and the changes of intercellular CO 2 and water use efficiency to environmental factors, such as wind speed, photon flux density, leaf temperature and ambient CO 2, are analyzed. It is shown that if the boundary layer conductance drops to a level comparable with stomatal conductance, the results of simulation by the model presented here differ significantly from those by the previous model, and, in some cases, are more realistic than the latter.

Calculation of Vapour Pressure of Metals by Statistical-Mechanical Method With the Debye Model

Statistical expression of vapour pressure equations of metals is derived from the Debye model.The statistical distribution of T_(-p) ensemble is presented in an in-elab- orate mode and the partition function is defined.The vapour pressure of eleven metals have been calculated with the Debye equation and compared with those given by the E- instein equation and empirical equation.Comparison of results of calculation from dif- ferent methods show their evident accordance within the same orders of magnitude.

电熨斗的种类和性能

在小电家类电子产品中,电熨斗亦在现代家庭中普及应用,给人们的日常生活提供了极大的便利。电熨斗的种类较多,目前流行的主要有普通型、调湿型、PTC 型、喷雾汽型、电解蒸气型等几大类别。电熨斗工作原理基本相同,即利用电流的热效应,使电熨斗底部达到所需的温度,并以不同的湿度、喷水、喷雾功能,从而使衣织物平整挺括。

Ni nanoparticles supported on carbon as efficient catalysts for steam reforming of toluene(model tar)

This paper investigated the influences of surface properties of carbon support and nickel precursors(nickel nitrate, nickel chloride and nickel acetate) on Ni nanoparticle sizes and catalytic performances for steam reforming of toluene. Treatment with nitric acid helped to increase the amount of functional groups on the surface and hydrophilic nature of carbon support, leading to a homogeneous distribution of Ni nanoparticles. The thermal decomposition products of nickel precursor also played an important role, Ni nanoparticles supported on carbon treated with acid using nickel nitrate as the precursor exhibited the smallest mean diameter of 4.5 nm. With the loading amount increased from 6 wt% to 18 wt%, the mean particle size of Ni nanoparticles varied from4.5 nm to 9.1 nm. The as-prepared catalyst showed a high catalytic activity and a good stability for toluene steam reforming: 98.1% conversion of toluene was obtained with the Ni content of 12 wt% and the S/C ratio of3, and the conversion only decreased to 92.0% after 700 min. Because of the high activity, good stability, and low cost, the as-prepared catalyst opens up new opportunities for tar removing.

Numerical Study of Steam-Water Separators with Wave-type Vanes

Droplet behavior in the wave-type flow channel is discussed, especially with the secondary .droplet generation due to impingement of droplets on the wall considered. A numerical method is suggested to simulate tile droplet behavior in the flow field. Calculations are compared With experimental data on the ; pressure drop and separating efficiency. Good agreement exists between the calculations and air-water experiments. The numerical method developed gives a reasonable description of the droplet deposition and secondary droplet generation, and it can be applied to predict the performance of wave-type vane separators.

Kinetic model on coke oven gas with steam reforming

The effects of factors such as the molar ratio of H2O to CH4 (n(H2O)/n(CH4)), methane conversion temperature and time on methane conversion rate were investigated to build kinetic model for reforming of coke-oven gas with steam. The results of experiments show that the optimal conditions for methane conversion are that the molar ratio of H2O to CH4 varies from 1.1 to 1.3 and the conversion temperature varies from 1 223 to 1 273 K. The methane conversion rate is more than 95% when the molar ratio of H2O to CH4 is 1.2, the conversion temperature is above 1 223 K and the conversion time is longer than 0.75 s. Kinetic model of methane conversion was proposed. All results demonstrate that the calculated values by the kinetic model accord with the experimental data well, and the error is less than 1.5%.

Effects of Climatic Change on Evapotranspiration in Zhalong Wetland,Northeast China

Evapotranspiration （ET） process of plants is controlled by several factors. Besides the physiological factors of plants, height, density, LAI （leaf area index）, etc., the change of meteorological factors, such as radiation, temperature, wind and precipitation, can influence ET process evidently, thus remodeling the spatial and temporal distribution of ET. In order to illuminate the effects of meteorological factors on wetland ET, the ET of Zhalong Wetland was calculated from 1961 to 2000, the statistical relationships （models） between ET and maximum temperature （Tmax）, minimum temperature （Tmin）, precipitation （P） and wind speed at 2m height （U2） were established, and the sensitivity analysis of the variables in the model was performed. The results show that Tmax and Tmin are two dominating factors that influence ET markedly, and the difference of rising rate between Tmax and Tmin determines the change trend of ET. With the climatic scenarios of four General Circulation Models （GCMs）, the ET from 2001 to 2060 was predicted by the statistical model. Compared to the period of 1961-2000, the water consumption by ET will increase greatly in the future. According to the scenarios, the rise of Tmax （about 1.5℃ to 3.3℃） and Tmin （about 1.7℃ to 3.5℃） will cause an additional water consumotion of 14.0%- 17.8% for reed swami）. The ecological water demand in Zhalong Wetland will become more severe.

Investigation of Calcium Sulfide Regeneration with Steam

Harmless treatment of CaS from coal gas desusulfurization and other industries is of very importance for the environmental protection. In this paper, the experimental investigation of calcium sulfide regeneration with steam at atmospheric pressure was carded out using TGA, fixed bed reactor and SEM-EDX analysis. The results show that the reaction mechanism of CaS with steam varies with temperature. The reaction occurs obviously at the temperature above 630℃ and the dominant products include CaSO4 （or CaSO3） and H2S, as the temperature is over 850℃, the primary products become CaO, SO2 and H2S. The CaS regeneration reaction will strongly depend on the temperature and the data over 900℃ can be fitted by the Shrinking-Core Model （SCM）.

Influence of the synthesis method parameters used to prepare nickel-based catalysts on the catalytic performance for the glycerol steam reforming reaction

The influence of the synthesis method parameters used to prepare nickel-based catalysts on the catalytic performance for the glycerol steam reforming reaction was studied.A series of Al2O3-supported Ni catalysts were synthesized,with nickel loading of 8 wt%,using the incipient wetness,wet impregnation,and modified equilibrium deposition filtration methods.The catalysts＇ surface and bulk properties were determined by inductively coupled plasma（ICP）,N2 adsorption-desorption isotherms（BET）,X-ray diffraction（XRD）,scanning electron microscopy（SEM）,transmission electron microscopy（TEM）,and temperature-programmed reduction（TPR）.Used catalysts were characterized by techniques such as elemental analysis and SEM in order to determine the level of carbon that was deposited and catalyst morphology.The results indicated that the synthesis method affected the textural,structural and surface properties of the catalysts,differentiating the dispersion and the kind of nickel species on alumina＇s surface.The formation of nickel aluminate phases was confirmed by the XRD and TPR analysis and the β-peak of the Ni/Al-edf catalyst was higher than in the other two catalysts,indicating that the nickel aluminate species of this catalyst were more reducible.Both Ni/Al-wet and Ni/Al-edf catalysts showed increasing CO2 selectivities and approximately constant CO selectivities for temperatures above 550℃,indicating that these catalysts successfully catalyze the water gas shift reaction.It was also confirmed that the Ni/Al-edf catalyst had the highest values for glycerol to gaseous products conversion,hydrogen yield,allyl alcohol,acetaldehyde,and acetic acid selectivities at 650℃ and the lowest carbon deposition of the catalysts tested.The correlation of the catalysts＇ structural properties,dispersion and reducibility with catalytic performance reveals that the EDF method can provide catalysts with higher specific surface area and active phase＇s dispersion,that are easier to reduce,more active and selective to hydrogen production,and more resistant to carbon deposition.

Simulation of Continuous Esterification Process of Polyester Polyols

Based on the kinetic and thermodynamic equations, a comprehensive mathematical model for the con- tinuous esterification process of polyester polyols was developed, which was carried out in an innovational bub- bling reactive distillation tower （BRDT） at atmospheric pressure. In this new type of reactor, direct esterification between ethylene glycol and adipic acid was accomplished efficiently and rapidly. A bench BRDT with the height of 2 m was applied for the esteriflcation process of l^oly （ethylene adlpate） （P＇EA）. In the continuous operation, Hn- ear oligomers were discharged from the bottom of the column, while water passed a few column trays and a pack- ing section as a condensation byproduct. The influence of major operating conditions on reactor performance was also simulated. Simulation results were in good agreement with experimental data, providing a strategy for devel- oping and optimizing this process.

Flow characteristics by particle image velocimetry in liquefied natural gas vaporizer model with several baffles

Shell-and-tube vaporizers are the most commonly used and dominated types of vaporizers in liquefied natural gas （LNG） realm. Due to efficient performance, shell-side flow in this type of vaporizers has received considerable attention and has been investigated extensively. However, the detailed flow structure in the shell needs to be determined for reliable and effective design. Therefore, the objective of this study was to clarify the flow structure in shell by particle image velocimetry （PIV）. Experiments were conducted using two types of model; 15% baffle cut having inlet and outlet positions !n the direction of 90° to the cut and 30% baffle cut having inlet and outlet positions in the direction of 180° to the cut. Each test section is 169 mm in inner diameter and 344.6 mm in length. The flow features were characterized in different baffle cuts with regards to the velocity vector field and velocity distribution. The results show that the flow characteristics of 15% baffle cut type vaporizer are comparable to those of 30% baffle cut type vaporizer.

A simplified adsorption model for water vapor adsorption on activated carbon

A simplified model was developed to describe the water vapor adsorption on activated carbon. The development of the simplified model was started from the original model proposed by DO and his co-workers. Two different kinds of carbon materials were prepared for water vapor adsorption, and the adsorption experiments were conducted at different temperatures(20-50 °C) and relative humidities(5%-99%) to test the model. It is shown that the amount of adsorbed water vapor in micropore decreases with the temperature increasing, and the water molecules form larger water clusters around the functional group as the temperature is up to a higher value. The simplified model describes reasonably well for all the experimental data. According to the fitted values, the parameters of simplified model were represented by the temperature and then the model was used to calculate the water vapor adsorption amount at 25 °C and 35 °C. The results show that the model can get relatively accurate values to calculate the water vapor adsorption on activated carbon.

Mathematical Modelling of the Transient Response of Pipeline

Steam pipelines applied in power units operate at high pressures and temperatures.In addition,to stress from the pipeline pressure also arise high thermal stresses in transient states such as start-up,shutdown or a load change of the power unit.Time-varying stresses are often the cause of the occurrence of fatigue cracks since the plastic deformations appear at the stress concentration regions.To determine the transient temperature of the steam along the steam flow path and axisymmetric temperature distribution in the pipeline wall,a numerical model of pipeline heating was proposed.To determine the transient temperature of the steam and pipeline wall the finite volume method(FVM) was used Writing the energy conservation equations for control areas around all the nodes gives a system of ordinary differential equations with respect to time.The system of ordinary differential equations of the first order was solved by the Runge-Kutta method of the fourth order to give the time-temperature changes at the nodes lying in the area of the wall and steam.The steam pressure distribution along pipeline was determined from the solution of the momentum conservation equation.Based on the calculated temperature distribution,thermal stresses were determined.The friction factor was calculated using the correlations of Churchill and Haaland,which were proposed for pipes with a rough inner surface.To assess the accuracy of the proposed model,numerical calculations were also performed for the thin-walled pipe,and the results were compared to the exact analytical solution.Comparison of the results shows that the accuracy of the proposed model of pipeline heating is very satisfactory.The paper presents examples of the determination of the transient temperature of the steam and the wall.

Theoretical and Computational Analyses of LNG Evaporator

Theoretical and numerical analysis on the fluid flow and heat transfer inside a LNG evaporator is conducted in this work. Methane is used instead of LNG as the operating fluid. This is because; methane constitutes over 80% of natural gas. The analytical calculations are performed using simple mass and energy balance equations. The analytical calculations are made to assess the pressure and temperature variations in the steam tube. Multiphase numerical simulations are performed by solving the governing equations(basic flow equations of continuity, momentum and energy equations) in a portion of the evaporator domain consisting of a single steam pipe. The flow equations are solved along with equations of species transport. Multiphase modeling is incorporated using VOF method. Liquid methane is the primary phase. It vaporizes into the secondary phase gaseous methane. Steam is another secondary phase which flows through the heating coils. Turbulence is modeled by a two equation turbulence model. Both the theoretical and numerical predictions are seen to match well with each other. Further parametric studies are planned based on the current research.

Experimental study on the ignition and combustion characteristics of a magnesium particle in water vapor

Magnesium is of interest for underwater propulsion due to the superior ignition behavior of magnesium particles and the highly exothermic Mg-water reaction.In this work,the ignition and combustion characteristics of an individual millimeter-sized magnesium particle in water vapor were studied.In order to build an atmosphere of water vapor,an experiment system was established and validated by the experiments of magnesium particle in air.The ignition and combustion of a single magnesium particle were accomplished in a combustor filled with water vapor.The surface changes of the particle during the ignition and a steady-state vapor phase combustion were observed.Based on the data obtained,ignition mechanism was analyzed and ignition temperature was determined.The steady-state combustion of the sample was controlled by diffusion in gas phase,and a one-dimensional,spherically symmetric quasi-steady model was adopted to describe the process.The dependence of burning time on the diameter was investigated,and the conclusion that burning time is proportional to the square of the metal sample diameter was drawn.