BUCHI K-370自动定氮仪蒸馏程序相关参数的试验研究

为了分析BUCHI K-370全自动定氮仪相关参数即蒸汽力度,蒸馏时间的设置使之最适合生物制品中蛋白质含量的测定。分别选用蒸汽力度90%、80%,蒸馏时间190s、170s配对进行硫酸铵回收试验同时对每次回收试验后氨的残留量进行分析比较。再将选出的测定参数对人血白蛋白国家标准品中的蛋白质进行测定。采用蒸汽力度90%,蒸馏时间190s时硫酸铵回收率为100.08%,RSD最小,为0.28%,回收试验后氨残留量最小;且测得标准品的蛋白质含量与真实值对比无显著差异。结果表明采用蒸汽力度90%,蒸馏时间190s最适合生物制品中蛋白含量的测定。

Vapor Pressure Measurement of Water+1,3-Dimethylimidazolium Tetrafluoroborate System

In absorption cycles,ionic liquid(IL)1,3-dimethylimidazolium tetrafluoroborate([Dmim]BF4)may be a promising absorbent of working pair using water as refrigerant.The vapor pressures of[Dmim]BF4 aqueous solution were measured with the boiling-point method in the temperature range from 312.25 to 403.60 K and in the mass concentration range of 65%to 90%of[Dmim]BF4.The experimental data were correlated with an Antoine-type equation and the Non-Random Two-Liquid(NRTL)model,and the average absolute deviations between the experimental and calculated values were 1.06%and 1.15%,respectively.For the[Dmim]BF4 aqueous solution,the experimental vapor pressures show negative deviations from the calculated data with Raoult's law.For higher mass concentration of the IL,the deviation is more negative.In addition,the vapor pressures,the hydrophilicity and the solubility of[Dmim]BF4 aqueous solutions were compared with those of[Dmim]Cl aqueous solutions and [Bmim]BF4 aqueous solutions at IL-mole fraction of 0.20.

Optimal Analysis of Pure Low-Temperature Waste Heat Recovery Generation System

In this paper, a detailed thermodynamic analysis of the pure low-temperature waste heat recovery generation system is presented. The parameters affecting the system performance are compared to obtain the most significant ones; furthermore, parameter values are optimized for the largest power generating capability of the system. It is found that the most important parameters are inlet flue gas temperature, steam pressure and the pinch point temperature difference. There is an optimal superheated steam pressure value for giving the maximum generation power per unit flue gas. With the increase of inlet flue gas temperature, the generating power increases and the optimized steam pressure rises as well. However, with increase in pinch point temperature difference, the generating power decreases and the optimized steam pressure decreases as well. The theoretical calculation provides a theoretical basis for the parameters optimization in the design of the pure low-temperature waste heat recovery eeneration swtem

Skeletal Isomerization of 1-Hexene over MCM-22 Zeolite Catalyst

The performance of MCM-22 zeolite for catalytic isomerization of 1-hexene has been studied. At a n(H2)/n(1-hexene) ratio of 8, the influence of steam treatment temperature, reaction temperature and reaction pressure on the performance of MCM-22 zeolite for catalytic skeletal isomerization of 1-hexene was examined. The experimental results showed that at a steam treatment temperature of 500℃, a reaction temperature of 270℃, a space velocity of 1.0 h-1 and a reaction pressure of 0.2 MPa, the MCM-22 zeolite exhibited excellent performance for catalytic skeletal isomerization of 1-hexene with the i-hexene yield reaching 66.15%. Compared with other commonly used molecular sieve catalysts, the MCM-22 zeolite catalyst exhibited better catalytic performance for skeletal isomerization of 1-hexene.

Investigations on the Heat Flux Rates in Superheated Water Jet Evaporators

When a liquid undergoes sudden reduction in the surrounding pressure below its saturation pressure, the liquid then enters in a metastable state. In order to regain equilibrium, part of the liquid evaporates quickly in a phenomenon called ＂flash evaporation＂, and the excess sensible heat contained in the liquid is converted into latent heat of vaporization. Therefore, temperatures of both the liquid and the generated vapor decline to the saturation temperature for the reduced pressure. As the heat and mass transfer occur in direct contact between the liquid and its own vapors, the process involves a very high heat transfer rate which makes it suitable for exchanging heat between sources of relatively small temperature difference. Moreover, dispensability of the heat exchange surfaces in this process is a considerable advantage as these surfaces constitute major part of the total system expenses in addition to the associated maintenance problems, especially when dealing with corrosive fluids such like seawater in the thermal desalination processes and in the OTEC （ocean thermal energy conversion） systems. This paper reports on the heat flux variation profiles during the flash evaporation of superheated water jets at various flow conditions. Heat flax was found to grow with time attaining a peak value before it starts to decrease monotonically.

Experimental study on the performance of a rotational supercavitating evaporator for desalination

Efforts have been made on experimental research of a supercavitation device for desalination, which is named rotational supercavitating evaporator （RSCE）. The RSCE is characterised by the simple construction and responsive capacity control, and only requires rough filtration of the source water for scaling- and fouling-free operations. The present study has been conducted for the water flow at temperature of around 22-30℃ and atmospheric pressure as the first step for investigation of the performance characteristics of RSCE. The multiply factor extremal experiments conducted with the Box-Wilson＇s method have revealed the salinity of the condensate, the temperature of steam inside the supercavity, and dependence of the shape of supercavity on the rate of steam extraction and rotation speed of impeller. The shape of impeller and the expected supercavitating effects it generates have been confirmed by experimental results at the rotation speed of 5430 rpm （round per minute）. The design of the steam extraction openings has been approved during the evacuation of steam. The experimental dependencies have been obtained in form of statistically valid regression equations, which can be used for engineering design of RSCE.