The purpose of this study is to investigate the catalytic effects of alkali and alkaline earth metallic species （AAEM） on char conversion during the gasification in steam and the changes in ex-situ char reactivity i...The purpose of this study is to investigate the catalytic effects of alkali and alkaline earth metallic species （AAEM） on char conversion during the gasification in steam and the changes in ex-situ char reactivity in oxygen after the gasification in steam using different forms （i.e. H-form, Na-form） of Shengli brown coal. The surface area, AAEM concentration and carbon crystallite of chars were obtained to understand the change in char reactivity. It was found that not only Na concentration and carbon structure were the main factors governing the char reactivity in the atmosphere of steam and oxygen, but also they interacted each other. The presence of Na could facilitate the formation of disordering carbon structure in char, and the amorphous carbon structure would in turn affect the distribution of Na and thus its catalytic performance. The surface area and pore volume had very little relationship with the char＇s reactivity. Addi- tionally, the morphology of chars from different forms of coals were observed using scanning electron microscope （SEM）.展开更多
Since the combustion system of coal-fired boiler in thermal power plant is characterized as time varying, strongly coupled, and nonlinear, it is hard to achieve a satisfactory performance by the conventional proportio...Since the combustion system of coal-fired boiler in thermal power plant is characterized as time varying, strongly coupled, and nonlinear, it is hard to achieve a satisfactory performance by the conventional proportional integral derivative (PID) control scheme. For the characteristics of the main steam pressure in coal-fired power plant boiler, the sliding mode control system with Smith predictive structure is proposed to look for performance and robustness improvement. First, internal model control (IMC) and Smith predictor (SP) is used to deal with the time delay, and sliding mode controller (SMCr) is designed to overcome the model mismatch. Simulation results show the effectiveness of the proposed controller compared with conventional ones.展开更多
To optimize the technological parameter of underground coal gasification （UCG）, the experimental results of air gasification, air-steam gasification, oxygen-enrichment steam gasification, pure oxygen steam gasificat...To optimize the technological parameter of underground coal gasification （UCG）, the experimental results of air gasification, air-steam gasification, oxygen-enrichment steam gasification, pure oxygen steam gasification and two-stage gasification were studied contrastively based on field trial at the Huating UCG project. The results indicate that the average low heat value of gas from air experiment is the lowest （4.1 MJ/Nm3） and the water gas from two-stage gasification experiment is the highest （10.72 MJ/Nm3）. The gas productivity of air gasification is the highest and the pure oxygen steam gasification is the lowest. The gasification efficiency of air gasification, air-steam gasification, oxygen-enriched steam gasification, pure oxygen steam gasification and two-stage gasification is listed in ascending order, ranging from 69.88% to 84.81%. Described a contract study on results of a field test using steam and various levels of oxygen enrichment of 21%, 32%, 42% and 100%. The results show that, with the increasing of O2 content in gasifying agents, the gas caloricity rises, and the optimal O2 concentration range to increase the gas caloricity is 30%-40%. Meanwhile, the consumption of O2 and steam increase, and the air consumption and steam decomposition efficiency fall.展开更多
Harmless treatment of CaS from coal gas desusulfurization and other industries is of very importance for the environmental protection. In this paper, the experimental investigation of calcium sulfide regeneration with...Harmless treatment of CaS from coal gas desusulfurization and other industries is of very importance for the environmental protection. In this paper, the experimental investigation of calcium sulfide regeneration with steam at atmospheric pressure was carded out using TGA, fixed bed reactor and SEM-EDX analysis. The results show that the reaction mechanism of CaS with steam varies with temperature. The reaction occurs obviously at the temperature above 630℃ and the dominant products include CaSO4 （or CaSO3） and H2S, as the temperature is over 850℃, the primary products become CaO, SO2 and H2S. The CaS regeneration reaction will strongly depend on the temperature and the data over 900℃ can be fitted by the Shrinking-Core Model （SCM）.展开更多
The coke plant of a steel plant corresponds to the area that transforms a blend of coal into coke for using in blast furnace and steam to power plant. The coking plant of ThyssenKrupp CSA uses the heat recovery techno...The coke plant of a steel plant corresponds to the area that transforms a blend of coal into coke for using in blast furnace and steam to power plant. The coking plant of ThyssenKrupp CSA uses the heat recovery technology with stamping charger for stamping and preparation a blend of coals for charging and coking. Stamping technology adds several benefits to the process, such as increased density, homogeneity and alignment of the coal cake charged into the oven, as well as provides better control of the coking process, improves parameters of coke quality and allows coal blending with lower coking power, thereby reducing the production cost of coke and power generation. Through the automation of stamping charger, it is possible to evaluate and calculate the stamped coal density charged and the productivity gains this system provides.展开更多
文摘The purpose of this study is to investigate the catalytic effects of alkali and alkaline earth metallic species （AAEM） on char conversion during the gasification in steam and the changes in ex-situ char reactivity in oxygen after the gasification in steam using different forms （i.e. H-form, Na-form） of Shengli brown coal. The surface area, AAEM concentration and carbon crystallite of chars were obtained to understand the change in char reactivity. It was found that not only Na concentration and carbon structure were the main factors governing the char reactivity in the atmosphere of steam and oxygen, but also they interacted each other. The presence of Na could facilitate the formation of disordering carbon structure in char, and the amorphous carbon structure would in turn affect the distribution of Na and thus its catalytic performance. The surface area and pore volume had very little relationship with the char＇s reactivity. Addi- tionally, the morphology of chars from different forms of coals were observed using scanning electron microscope （SEM）.
基金Supported by the National Natural Science Foundation of China (61174059, 60934007, 61233004)the National Basic Research Program of China (2013CB035406)Shanghai Rising-Star Tracking Program (11QH1401300)
文摘Since the combustion system of coal-fired boiler in thermal power plant is characterized as time varying, strongly coupled, and nonlinear, it is hard to achieve a satisfactory performance by the conventional proportional integral derivative (PID) control scheme. For the characteristics of the main steam pressure in coal-fired power plant boiler, the sliding mode control system with Smith predictive structure is proposed to look for performance and robustness improvement. First, internal model control (IMC) and Smith predictor (SP) is used to deal with the time delay, and sliding mode controller (SMCr) is designed to overcome the model mismatch. Simulation results show the effectiveness of the proposed controller compared with conventional ones.
文摘To optimize the technological parameter of underground coal gasification （UCG）, the experimental results of air gasification, air-steam gasification, oxygen-enrichment steam gasification, pure oxygen steam gasification and two-stage gasification were studied contrastively based on field trial at the Huating UCG project. The results indicate that the average low heat value of gas from air experiment is the lowest （4.1 MJ/Nm3） and the water gas from two-stage gasification experiment is the highest （10.72 MJ/Nm3）. The gas productivity of air gasification is the highest and the pure oxygen steam gasification is the lowest. The gasification efficiency of air gasification, air-steam gasification, oxygen-enriched steam gasification, pure oxygen steam gasification and two-stage gasification is listed in ascending order, ranging from 69.88% to 84.81%. Described a contract study on results of a field test using steam and various levels of oxygen enrichment of 21%, 32%, 42% and 100%. The results show that, with the increasing of O2 content in gasifying agents, the gas caloricity rises, and the optimal O2 concentration range to increase the gas caloricity is 30%-40%. Meanwhile, the consumption of O2 and steam increase, and the air consumption and steam decomposition efficiency fall.
基金Project 2002AA529080 supported by National High-Tech Research and Development Program of China (Progam 863)
文摘Harmless treatment of CaS from coal gas desusulfurization and other industries is of very importance for the environmental protection. In this paper, the experimental investigation of calcium sulfide regeneration with steam at atmospheric pressure was carded out using TGA, fixed bed reactor and SEM-EDX analysis. The results show that the reaction mechanism of CaS with steam varies with temperature. The reaction occurs obviously at the temperature above 630℃ and the dominant products include CaSO4 （or CaSO3） and H2S, as the temperature is over 850℃, the primary products become CaO, SO2 and H2S. The CaS regeneration reaction will strongly depend on the temperature and the data over 900℃ can be fitted by the Shrinking-Core Model （SCM）.
文摘The coke plant of a steel plant corresponds to the area that transforms a blend of coal into coke for using in blast furnace and steam to power plant. The coking plant of ThyssenKrupp CSA uses the heat recovery technology with stamping charger for stamping and preparation a blend of coals for charging and coking. Stamping technology adds several benefits to the process, such as increased density, homogeneity and alignment of the coal cake charged into the oven, as well as provides better control of the coking process, improves parameters of coke quality and allows coal blending with lower coking power, thereby reducing the production cost of coke and power generation. Through the automation of stamping charger, it is possible to evaluate and calculate the stamped coal density charged and the productivity gains this system provides.
