Five different kinds of hydrophilic organic salts were used to modify commercial activated carbon in order to prepare hydrophilic carbon materials. Properties of the samples were analyzed by surface area analyzer and ...Five different kinds of hydrophilic organic salts were used to modify commercial activated carbon in order to prepare hydrophilic carbon materials. Properties of the samples were analyzed by surface area analyzer and SEM-EDX. The hydrophilic organic salts with different properties were introduced into activated carbon and significantly affected the properties of the samples.During adsorption experiments, the water vapor adsorption amount in modified samples increases by 0.57-17.12 times in temperature range from 303 to 323 K and at relative pressure below 0.50. Water molecules combined with surface hydrophilic groups through H-bonding exhibit good thermo stability. The effects of temperature, oxygen content and properties of the hydrophilic organic salts on water vapor adsorption were studied. It is indicated that water vapor adsorption in modified samples is mainly affected by the surface oxygen content. The carboxylate radicals in the hydrophilic organic salts greatly affect the micropore structure of the modified samples, while the metal ions in them exhibit limited influence. Different adsorption capacity of modified samples can be explained with the electronegativity of elements presented by Pauling.展开更多
The mode splitting in a system with Doppler-broadened high-density two-level atoms in the presence of magnetic field inside a relatively long optical cavity is studied in the superstrong coupling regime(atoms-cavity c...The mode splitting in a system with Doppler-broadened high-density two-level atoms in the presence of magnetic field inside a relatively long optical cavity is studied in the superstrong coupling regime(atoms-cavity coupling strength g√N is near or larger than the cavity free-spectral range?FSR).The effect of a magnetic field applied along the quantization axis is used to break the polarization degeneracy of the cavity and thereby introduce birefringence(or Faraday rotation)into the medium.The cavity modes are further split in the presence of the magnetic field compared with the normal case of the multi-normal-mode splitting of the two-level system near the D2 line of87Rb.The dependence of the mode splitting on the magnetic field and the temperature is studied.The theoretical analysis according to the linear dispersion theory can provide a good explanation.展开更多
基金Projects(21376274,51206192)supported by the National Natural Science Foundation of China
文摘Five different kinds of hydrophilic organic salts were used to modify commercial activated carbon in order to prepare hydrophilic carbon materials. Properties of the samples were analyzed by surface area analyzer and SEM-EDX. The hydrophilic organic salts with different properties were introduced into activated carbon and significantly affected the properties of the samples.During adsorption experiments, the water vapor adsorption amount in modified samples increases by 0.57-17.12 times in temperature range from 303 to 323 K and at relative pressure below 0.50. Water molecules combined with surface hydrophilic groups through H-bonding exhibit good thermo stability. The effects of temperature, oxygen content and properties of the hydrophilic organic salts on water vapor adsorption were studied. It is indicated that water vapor adsorption in modified samples is mainly affected by the surface oxygen content. The carboxylate radicals in the hydrophilic organic salts greatly affect the micropore structure of the modified samples, while the metal ions in them exhibit limited influence. Different adsorption capacity of modified samples can be explained with the electronegativity of elements presented by Pauling.
基金supported by the National Basic Research Program of China(Grant No.2011CB921601)the National Natural Science Foundation of China(Grant No.11234008)+1 种基金the NSFC Project for Excellent Research Team(Grant Nos.61121064 and 11234008)the Doctoral Program Founda-tion of the Ministry of Education China(Grant No.20111401130001)
文摘The mode splitting in a system with Doppler-broadened high-density two-level atoms in the presence of magnetic field inside a relatively long optical cavity is studied in the superstrong coupling regime(atoms-cavity coupling strength g√N is near or larger than the cavity free-spectral range?FSR).The effect of a magnetic field applied along the quantization axis is used to break the polarization degeneracy of the cavity and thereby introduce birefringence(or Faraday rotation)into the medium.The cavity modes are further split in the presence of the magnetic field compared with the normal case of the multi-normal-mode splitting of the two-level system near the D2 line of87Rb.The dependence of the mode splitting on the magnetic field and the temperature is studied.The theoretical analysis according to the linear dispersion theory can provide a good explanation.
