From the chemical catalysis viewpoint,the excellent performance of CNTs in adsorption-activation of H2 and in promoting spillover of adsorbed H-species is very attractive,in addition to their nanosize channels,sp2-C c...From the chemical catalysis viewpoint,the excellent performance of CNTs in adsorption-activation of H2 and in promoting spillover of adsorbed H-species is very attractive,in addition to their nanosize channels,sp2-C constructed surfaces,and high thermal/electrical conductivity.This review examines some recent progresses of CNTs as a novel support or promoter of catalysts for certain hydrogenation or dehydrogenation reactions,e.g.,hydrogenation-conversion of syngas to yield alcohols and decomposition or steam-reforming of methanol to generate H2,mainly based on recent work carried out in our laboratory.展开更多
Steam channeling is one of the main barriers for EOR after steam flooding.In order to enhance the oil recovery in steam flooded reservoirs,steam channel volumes should be precisely known.In this paper,a set of methods...Steam channeling is one of the main barriers for EOR after steam flooding.In order to enhance the oil recovery in steam flooded reservoirs,steam channel volumes should be precisely known.In this paper,a set of methods has been established in order to study steam channeling quantitatively by using dynamic data.Firstly,steam channeling wells are identified through curves of watercut and temperature.Then,considering the hysteresis phenomenon,channeling relations are identified with the correlation coefficients between injection wells and production wells under different conditions.Lastly,an analytic model,in which steam condensation,pressure and temperature are considered,is established to calculate the steam channel volumes.A production well named L31615 in some block in Henan Oilfield in China is systematically analyzed by using the method established.The whole block is further analyzed,and the distribution map of steam channels and the steam channel volumes are obtained.The results show that steam channeling does not only occur inside a well group,but also sometimes occurs between wells in different well groups.The calculation of the steam channel volumes provides a theoretical basis for bringing a remedial action like plugging into operation.展开更多
An experimental study of heat transfer characteristics in superheated steam cooled rectangular channels with parallel ribs was conducted.The distribution of the heat transfer coefficient on the rib-roughed channel was...An experimental study of heat transfer characteristics in superheated steam cooled rectangular channels with parallel ribs was conducted.The distribution of the heat transfer coefficient on the rib-roughed channel was measured by IR camera.The blockage ratio(e/Dh) of the tested channel is 0.078 and the aspect ratio(W/H) is fixed at3.0.Influences of the rib pitch-to-height ratio(P/e) and the rib angle on heat transfer for steam cooling were investigated.In this paper,the Reynolds number(Re) for steam ranges from 3070 to 14800,the rib pitch-to-height ratios were 8,10 and 12,and rib angles were 90°,75°,60°,and 45°.Based on results above,we have concluded that:In case of channels with 90° tranverse ribs,for larger rib pitch models(the rib pitch-to-height ratio=10 and12),areas with low heat transfer coefficient in front of rib is larger and its minimum is lower,while the position of the region with high heat transfer coefficient nearly remains the same,but its maximun of heat transfer coefficient becomes higher.In case of channels with inclined ribs,heat transfer coefficients on the surface decrease along the direction of each rib and show an apparent nonuniformity,consequently the regions with low Nusselt number values closely following each rib expand along the aforementioned direction and that of relative high Nusselt number values vary inversely.For a square channel with 90° ribs at Re= 14800,wider spacing rib configurations(the rib pitch-to-height ratio=10 and 12) give an area-averaged heat transfer on the rib-roughened surface about8.4%and 11.4%more than P/e=8 model,respectively;for inclined parallel ribs with different rib angles at Re=14800,the area-averaged heat transfer coefficients of 75°,60° and 45° ribbed surfaces increase by 20.1%,42.0%and 44.4%in comparison with 90° rib angle model.45° angle rib-roughened channel leads to a maximal augmentation of the area-averaged heat transfer coefficient in all research objects in this paper.展开更多
基金supported by the National Basic Research Program of China(2011CBA00508)the National Natural Science Foundation of China(20923004)the Program for Changjiang Scholars and Innovative Research Team in University(IRT1036)
文摘From the chemical catalysis viewpoint,the excellent performance of CNTs in adsorption-activation of H2 and in promoting spillover of adsorbed H-species is very attractive,in addition to their nanosize channels,sp2-C constructed surfaces,and high thermal/electrical conductivity.This review examines some recent progresses of CNTs as a novel support or promoter of catalysts for certain hydrogenation or dehydrogenation reactions,e.g.,hydrogenation-conversion of syngas to yield alcohols and decomposition or steam-reforming of methanol to generate H2,mainly based on recent work carried out in our laboratory.
基金supported by China National Science and Technology Major Project(Grant No.2011ZX05009-004-05)the National Natural Science Foundation of China(Grant No.51274212)
文摘Steam channeling is one of the main barriers for EOR after steam flooding.In order to enhance the oil recovery in steam flooded reservoirs,steam channel volumes should be precisely known.In this paper,a set of methods has been established in order to study steam channeling quantitatively by using dynamic data.Firstly,steam channeling wells are identified through curves of watercut and temperature.Then,considering the hysteresis phenomenon,channeling relations are identified with the correlation coefficients between injection wells and production wells under different conditions.Lastly,an analytic model,in which steam condensation,pressure and temperature are considered,is established to calculate the steam channel volumes.A production well named L31615 in some block in Henan Oilfield in China is systematically analyzed by using the method established.The whole block is further analyzed,and the distribution map of steam channels and the steam channel volumes are obtained.The results show that steam channeling does not only occur inside a well group,but also sometimes occurs between wells in different well groups.The calculation of the steam channel volumes provides a theoretical basis for bringing a remedial action like plugging into operation.
基金funded by the National Natural Science Foundation of China(Funding No.51206109)
文摘An experimental study of heat transfer characteristics in superheated steam cooled rectangular channels with parallel ribs was conducted.The distribution of the heat transfer coefficient on the rib-roughed channel was measured by IR camera.The blockage ratio(e/Dh) of the tested channel is 0.078 and the aspect ratio(W/H) is fixed at3.0.Influences of the rib pitch-to-height ratio(P/e) and the rib angle on heat transfer for steam cooling were investigated.In this paper,the Reynolds number(Re) for steam ranges from 3070 to 14800,the rib pitch-to-height ratios were 8,10 and 12,and rib angles were 90°,75°,60°,and 45°.Based on results above,we have concluded that:In case of channels with 90° tranverse ribs,for larger rib pitch models(the rib pitch-to-height ratio=10 and12),areas with low heat transfer coefficient in front of rib is larger and its minimum is lower,while the position of the region with high heat transfer coefficient nearly remains the same,but its maximun of heat transfer coefficient becomes higher.In case of channels with inclined ribs,heat transfer coefficients on the surface decrease along the direction of each rib and show an apparent nonuniformity,consequently the regions with low Nusselt number values closely following each rib expand along the aforementioned direction and that of relative high Nusselt number values vary inversely.For a square channel with 90° ribs at Re= 14800,wider spacing rib configurations(the rib pitch-to-height ratio=10 and 12) give an area-averaged heat transfer on the rib-roughened surface about8.4%and 11.4%more than P/e=8 model,respectively;for inclined parallel ribs with different rib angles at Re=14800,the area-averaged heat transfer coefficients of 75°,60° and 45° ribbed surfaces increase by 20.1%,42.0%and 44.4%in comparison with 90° rib angle model.45° angle rib-roughened channel leads to a maximal augmentation of the area-averaged heat transfer coefficient in all research objects in this paper.