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分光光度法测定外购生铁中砷的含量
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作者 马林泽 段家华 严海 《昆明冶金高等专科学校学报》 CAS 2013年第1期26-28,共3页
介绍了砷锑钼蓝光度法测定外购生铁中砷含量,在现有分析方法上加以改进,在称样之前将生铁粉在高温马弗炉内灼烧1 h左右除去C。之后,对溶样温度控制范围在200℃左右,溶样过程的冒烟时间进行了实验和比较,并研究了抗坏血酸保存时间对测定... 介绍了砷锑钼蓝光度法测定外购生铁中砷含量,在现有分析方法上加以改进,在称样之前将生铁粉在高温马弗炉内灼烧1 h左右除去C。之后,对溶样温度控制范围在200℃左右,溶样过程的冒烟时间进行了实验和比较,并研究了抗坏血酸保存时间对测定结果的影响,确定了线性范围和测定检出限,将其它方法定值过的样品与测定结果进行比较,证明方法可行。通过实验,本方法的准确率在国家标准范围内,砷的相对标准偏差<4%,适用于外购生铁中砷含量的测定。 展开更多
关键词 蓝分光光度法 砷测定 生铁
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Effects of Silicon at Different Concentrations on Morphology and Photosynthetic Physiological Mechanism of Japonica Rice 被引量:1
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作者 陈亮 蔡丽萍 +2 位作者 周彬 石妍 饶梦 《Agricultural Science & Technology》 CAS 2012年第9期1877-1880,1907,共5页
[Objective] The aim was to explore effects of silicon at different concentrations on morphology and photosynthetic physiological mechanism of japonica rice. [Method] Seedlings of japonica rice were treated with silico... [Objective] The aim was to explore effects of silicon at different concentrations on morphology and photosynthetic physiological mechanism of japonica rice. [Method] Seedlings of japonica rice were treated with silicon at different concentrations (0, 30, 80, 130 and 180 mg/L of sodium silicate); silicon contents were measured with Molybdenum blue spectrophotometric method in root, stem and leaf; plant height, root length and number in different treatment groups were measured with tools; chlorophyll a and b, and a/b in leaf and stem of rice in different groups were measured. [Result] Silicon contents in vegetative organs were as follows: stem〉leaf〉 root; when silicon was 80 mg/L, japonica ecotype was shortest; when silicon was 30 mg/L, root length of the rice was shortest and root number was least; when silicon was 30 mg/L, contents of chlorophyll a and b were highest and chlorophyll a/b achieved the peak when silicon was 80 mg/L. [Conclusion] Silicon at proper concen- tration would improve lodging-resistance and efficiency of photosynthesis, further enhancing yield of japonica rice. 展开更多
关键词 Japonica ecotype Silicon concentration Morphological characteristics Photosynthetic efficiency
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煤中砷的测定及影响因素分析 被引量:1
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作者 张莉 《煤炭与化工》 CAS 2018年第6期151-152,155,共3页
采用砷目蓝分光光度法测定煤中砷含量。实验研究了试剂的配置、锌粒大小、显色反应时间及比色液放置时间对测定过程及结果的影响。结果表明,检测试剂需要现配,控制锌粒粒度为3~5 mm,在沸水浴中的显色反应时间为20~25 min,冷却后比色液... 采用砷目蓝分光光度法测定煤中砷含量。实验研究了试剂的配置、锌粒大小、显色反应时间及比色液放置时间对测定过程及结果的影响。结果表明,检测试剂需要现配,控制锌粒粒度为3~5 mm,在沸水浴中的显色反应时间为20~25 min,冷却后比色液的放置时间<3 h,以确保测定结果的准确性。 展开更多
关键词 煤中砷 测定 砷目蓝分光光度法 影响因素
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Spatio-temporal distribution of dissolved sulfide in China marginal seas
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作者 吴晓丹 吴斌 +1 位作者 宋金明 李学刚 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2014年第5期1145-1156,共12页
With sulfide increasingly recognized as an important parameter to assess the oxidation-reduction level in aqueous enviromnent, research on its geochemical behavior is becoming important. Water samples collected in Boh... With sulfide increasingly recognized as an important parameter to assess the oxidation-reduction level in aqueous enviromnent, research on its geochemical behavior is becoming important. Water samples collected in Bohai Sea (1-19 August, 2010), Yellow Sea (20-30 November, 2010) and East China Sea (3-17 June, 2010 and 1-10 November, 2010) were used to determine the occurrence and distribution of dissolved sulfide by methylene blue spectrophotometric method. Results show that: (1) horizontally, concentration of dissolved sulfide significantly varied from the coastal region to the open sea and profoundly influenced by physical processes. High values occurred in the river-sea boundary zone "marginal filter" due to rich riverine input, frequent upwelling and active exchange in shelf edge. Terrestrial input from adjacent rivers and the current cycling contributed to the high sulfide appeared in western Bohai Sea, eastern Shandong Peninsula, and northeast of Changjiang (Yangtze) River estuary. Especially, relative higher sulfide values occurred in Yellow Sea, which is consistent with the variation of salinity largely due to the hydrodynamic feature; (2) vertically, measurement of dissolved sulfide in bottom water was higher and more variable than that in surface water caused by the wind-induced resuspension and dissimilatory sulfate reduction. Moreover, nutrient-type profile clearly identified that oxidation plays a major role in the biogeochemistry cycle of sulfide in water; (3) seasonally, investigation for East China Sea in June and November reflected seasonal variation of Changjiang River Diluted Water, Kuroshio Current, and Taiwan Warm Current. Concentration in June was much higher than that sampled in November at most stations. Mean concentration of dissolved sulfide varied seasonally from 2.26 μg/L (June) to 1.16 μg/L (November) in surface and 3.00 μg/L (June) to 1.56 μg/L (November) in bottom. Progress in the field is slow and more effort is needed to ensure the accuracy and reliability of determination and estimate the natural or anthropogenic contribution of dissolved sulfide in ecosystems. 展开更多
关键词 dissolved sulfide geochemical behavior China marginal seas CURRENT RESUSPENSION NUTRIENT
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