Oxidation process of Co(C 6 H 11 O) 2 PS 2 2 and substitute-reduction reaction of Co C 6 H 11 O) 2 PS 2 3 with pyridine have been studied by spectrophotome tric methods,respectively.The equ ilibrium constant was found...Oxidation process of Co(C 6 H 11 O) 2 PS 2 2 and substitute-reduction reaction of Co C 6 H 11 O) 2 PS 2 3 with pyridine have been studied by spectrophotome tric methods,respectively.The equ ilibrium constant was found to be K=0.63±0.02(mol·dm -3 ) -3 .The crystal structure of Co 6 H 11 O) 2 PS 2 2·2Py has been determined by X-ray diff-raction method.The crystal belongs to triclinic system,space groupP1,with cell parameters:a=6.944(2)?,b=9.277(3)?,c=15.981(6)?,α=91.79(3)°,β=99.55(3)°,γ=94.44(3)°,V=1011.2(6)? 3 ,Z =2,M r =803.94,D c =1.320Mg ·m -3 ,F(000)=425,μ=0.747mm -1 ,final R=0.0700and w R=0.1988for 3626re-flections with I≥2σ(I).The cobalt atom in the title complex has a octahedral geometry with four Co-S bonds and two Co-N bonds.The central atom P is t etrahedrally surrounded by two sulp hur atoms and two oxygen atoms in the dicyclohexyldithiophosphate liga nd.The six carbon atoms of cyclohexyl take the chair conformation.展开更多
利用水热合成法合成了分子组成为(C6H11NH3)5H(P2Mo5O23)4H2O的杂多化合物, 用单晶X-ray衍射方法测定了它的结构,该晶体属于单斜晶系,空间群P21/c, a = 12.830(3), b = 14.848(3), c = 25.258(5) ? b = 92.95(3), Mr = 1483.62, V = 48...利用水热合成法合成了分子组成为(C6H11NH3)5H(P2Mo5O23)4H2O的杂多化合物, 用单晶X-ray衍射方法测定了它的结构,该晶体属于单斜晶系,空间群P21/c, a = 12.830(3), b = 14.848(3), c = 25.258(5) ? b = 92.95(3), Mr = 1483.62, V = 4805.1(17) 3, Z = 4, Dc = 2.051 g/cm3, m = 1.431 mm-1, F(000) = 3000, I >2s(I) 的可观察衍射点4426个, 最终结构偏差因子R = 0.0464, wR = 0.0801, S = 0.731。在[P2Mo5O23]6-杂多阴离子中5个MoO6八面体通过共边和共角相连, 形成1个近似的五角平面骨架, 2个PO4四面体加在五角平面的两侧。热性质研究表明杂多阴离子骨架在547.4 ℃左右分解。展开更多
文摘Oxidation process of Co(C 6 H 11 O) 2 PS 2 2 and substitute-reduction reaction of Co C 6 H 11 O) 2 PS 2 3 with pyridine have been studied by spectrophotome tric methods,respectively.The equ ilibrium constant was found to be K=0.63±0.02(mol·dm -3 ) -3 .The crystal structure of Co 6 H 11 O) 2 PS 2 2·2Py has been determined by X-ray diff-raction method.The crystal belongs to triclinic system,space groupP1,with cell parameters:a=6.944(2)?,b=9.277(3)?,c=15.981(6)?,α=91.79(3)°,β=99.55(3)°,γ=94.44(3)°,V=1011.2(6)? 3 ,Z =2,M r =803.94,D c =1.320Mg ·m -3 ,F(000)=425,μ=0.747mm -1 ,final R=0.0700and w R=0.1988for 3626re-flections with I≥2σ(I).The cobalt atom in the title complex has a octahedral geometry with four Co-S bonds and two Co-N bonds.The central atom P is t etrahedrally surrounded by two sulp hur atoms and two oxygen atoms in the dicyclohexyldithiophosphate liga nd.The six carbon atoms of cyclohexyl take the chair conformation.
