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微乳液1-(2-吡啶偶氮)-2-萘酚分光光度法测定蔬菜样品中的钴 被引量:11
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作者 马同森 张顺利 《分析化学》 SCIE EI CAS CSCD 北大核心 1999年第7期825-827,共3页
以十二烷基硫酸钠-溴代十六烷基三甲胺(SDS-CIMAB)复合微乳液为介质,对Co(Ⅱ)-1-(2-吡啶偶氮)-2-萘酚的显色反应条件进行了研究.结果表明该体系的λ_(max)=580nm,ε_(580)=3.4×10~4L·mol·cm^(-1),Co(Ⅱ)测定的线性范围为... 以十二烷基硫酸钠-溴代十六烷基三甲胺(SDS-CIMAB)复合微乳液为介质,对Co(Ⅱ)-1-(2-吡啶偶氮)-2-萘酚的显色反应条件进行了研究.结果表明该体系的λ_(max)=580nm,ε_(580)=3.4×10~4L·mol·cm^(-1),Co(Ⅱ)测定的线性范围为0~2.40mg/L.回收率在96%~103%之间,该法选择性好,用于蔬菜中Co(Ⅱ)含量的测定,得到了满意的结果. 展开更多
关键词 微乳液 分光光度法 蔬菜样 PAN 测定
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环境水样及蔬菜中NO_2^-和NO_3^-的流动注射光度法同时测定 被引量:5
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作者 高楼军 张志琪 《环境科学》 EI CAS CSSCI CSCD 北大核心 1998年第3期84-86,共3页
将流动注射技术引入N-(1-萘基)乙烯二胺光度法测定NO-2分析体系,采用单阀双带注入镀镉锌片还原柱带隔离的阀体流路,建立了同时测定微量NO-2和NO-3的分析方法.NO-2-N的测定范围为0.01—2.0μg/ml... 将流动注射技术引入N-(1-萘基)乙烯二胺光度法测定NO-2分析体系,采用单阀双带注入镀镉锌片还原柱带隔离的阀体流路,建立了同时测定微量NO-2和NO-3的分析方法.NO-2-N的测定范围为0.01—2.0μg/ml,NO-3-N的测定范围为0.05—5.0μg/ml,分析速度为30样/h.方法应用于环境水样及蔬菜中NO-2和NO-3的同时测定,结果满意. 展开更多
关键词 流动注射分析 环境水 蔬菜样 光度法 水质监测
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反相高效液相色谱法测定蔬菜鲜样中硝酸盐 被引量:5
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作者 杨华梅 《现代预防医学》 CAS 北大核心 2008年第3期543-544,554,共3页
[目的]采用反相高效液相色谱-二极管阵列检测器法测定蔬菜鲜样中硝酸盐含量。[方法]选择四丁基溴化铵(TBA.Br)作为离子对试剂,与硝酸根阴离子形成中性缔合物,在甲醇-1.25mmol/L混合磷酸盐流动相中,被非极性键合相柱(ODS)分离并定量检出... [目的]采用反相高效液相色谱-二极管阵列检测器法测定蔬菜鲜样中硝酸盐含量。[方法]选择四丁基溴化铵(TBA.Br)作为离子对试剂,与硝酸根阴离子形成中性缔合物,在甲醇-1.25mmol/L混合磷酸盐流动相中,被非极性键合相柱(ODS)分离并定量检出。[结果]在此检测条件下,硝酸盐有很好的线性(r=0.9999),最小检出限为0.01mg/L,相对标准差小于5%,回收率在87.6%~99.4%之间。[结论]该法适用于不同硝酸盐量的蔬菜样品测定。 展开更多
关键词 反相高效液相色谱 蔬菜 硝酸盐
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新双试剂多巴胺—3-甲基-2-苯并噻唑啉酮腙盐酸盐快速测定蔬菜鲜样中的硝态氮
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作者 王峰 《食品工业科技》 CAS CSCD 北大核心 2008年第10期264-265,271,共3页
研究了双试剂多巴胺—3-甲基-2-苯并噻唑啉酮腙盐酸盐(MBTH)与硝酸根离子的显色反应条件。在14.4mol.L-1的H2SO4介质中,双显色剂与硝酸根离子形成稳定的红色复合物,此复合物的颜色可稳定6h,NO3--N含量在0.04~0.80mg.L-1范围内符合朗伯... 研究了双试剂多巴胺—3-甲基-2-苯并噻唑啉酮腙盐酸盐(MBTH)与硝酸根离子的显色反应条件。在14.4mol.L-1的H2SO4介质中,双显色剂与硝酸根离子形成稳定的红色复合物,此复合物的颜色可稳定6h,NO3--N含量在0.04~0.80mg.L-1范围内符合朗伯-比尔定律,复合物的λmax=530nm,表观摩尔消光系数ε530=1.37×104L.mol-1.cm-1。该方法用于蔬菜鲜样中硝酸盐含量的测定,与传统的酚二磺酸法比较,无显著性差异。新方法具有快速、简便、可靠性强的特点,具有较大的推广价值。 展开更多
关键词 多巴胺 3-甲基-2-苯并噻唑啉酮腙盐酸盐 分光光度法 硝态氮 蔬菜
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Heavy Metal Transfer from Soil to Vegetable in Southern Jiangsu Province, China 被引量:47
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作者 HAO Xiu-Zhen ZHOU Dong-Mei +3 位作者 HUANG De-Qian CANG Long ZHANG Hai-Lin WANG Hui 《Pedosphere》 SCIE CAS CSCD 2009年第3期305-311,共7页
Vegetable fields in peri-urban areas receive large amounts of extraneous heavy metals because of rapid urbanization and industrialization in China. The concentrations of Cu, Zn, and Pb in 30 soil samples and 32 vegeta... Vegetable fields in peri-urban areas receive large amounts of extraneous heavy metals because of rapid urbanization and industrialization in China. The concentrations of Cu, Zn, and Pb in 30 soil samples and 32 vegetable samples, collected from 30 different sites in southern Jiangsu Province of China, were measured and their transfer from soil to vegetable was determined. The results showed that the soil samples had wide ranges of pH (4.25-7.85) and electrical conductivity (EC) (0.24-3.42 dS m^-1). Among the soil samples, there were four soil samples containing higher Cu and two soil samples containing higher Zn concentrations than those specified in the Chinese Soil Environmental Quality Standard II. However, no vegetable sample was found to contain a high level of Cu or Zn. In contrast, one vegetable sample contained 0.243 mg Pb kg^-1 FW, which was above the Chinese Food Hygiene Standard, whereas the corresponding soil Pb concentration was lower than the Chinese Soil Environmental Quality Standard II. The transfer coefficients of Cu of all vegetable samples exceeded the suggested coefficient range, implying that extraneous Cu had high mobility and bioavallability to vegetables. There was no significant correlation between extractable soil heavy metal concentrations with four kinds of extractants and soil pH, EC, heavy metal concentrations in vegetables and soils, except that soil pH correlated well with the extractable soil Cu, Zn, and Pb concentrations with 1.0 mol L-1 NH4NO3. Moreover, diethylenetriamine pentaacetic acid (DTPA) extraction method was a more efficient method of extracting heavy metals from the soils independent of soil pH and EC than other three methods used. 展开更多
关键词 heavy metal SOIL transfer coefficients VEGETABLE
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Utilizing Landsat TM Imagery to Map Greenhouses in Qingzhou, Shandong Province, China 被引量:15
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作者 ZHAOGeng-Xing LIJing +2 位作者 LITao YUEYu-De T.WARNER 《Pedosphere》 SCIE CAS CSCD 2004年第3期363-369,共7页
To build a rapid and accurate method for greenhouse vegetable landinformation extraction using an index model derived from TM digital data of Qingzhou City, ShandongProvince, based on a systematic analysis of the spec... To build a rapid and accurate method for greenhouse vegetable landinformation extraction using an index model derived from TM digital data of Qingzhou City, ShandongProvince, based on a systematic analysis of the spectral characteristics of different land use typesin the study area, a subset of the image was first made to eliminate the mountainous region notassociated with vegetable distribution, and then water body pixels were masked. With this the V_Iindex model for greenhouse vegetable land extraction was developed. The index model indicatedgreenhouse vegetable land for Qingzhou in April 2002 was concentrated in the southeast and aroundrural residential areas. Field data used for an accuracy evaluation showed that greenhouse hectaresdetermined with remote sensing were 95.9% accurate, and accuracy for the spatial distribution ofgreenhouse vegetable land cross checked with a random sample was 96.3%. Therefore, this approachprovided an effective method for greenhouse vegetable land information extraction and has potentialsignificance for management of greenhouse vegetable production in the study area, as well as NorthChina. 展开更多
关键词 greenhouse vegetable land information extraction qingzhou city TM image
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Determination of 3H and 14C in Organic Sample after Separation through Combustion Method 被引量:2
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作者 Simona Popoaca Cristina Bucur Vasile Simionov 《Journal of Energy and Power Engineering》 2014年第10期1687-1694,共8页
The Environmental program of the Cernavoda NPP (nuclear power plant) is based on the analysis of environmental samples: airborne, TLDs (thermoluminescence dosimeters), water, deposition, soil, grass, sediment, fi... The Environmental program of the Cernavoda NPP (nuclear power plant) is based on the analysis of environmental samples: airborne, TLDs (thermoluminescence dosimeters), water, deposition, soil, grass, sediment, fish, milk, meat, eggs, grains, fruits and vegetables, using determination of 3H and 14C, gross alpha/beta and gamma spectrometry measurement techniques. This Program is a legal constraint for nuclear utilities and it is approved and supervised by the regulatory body. Besides, the actual legal requirements, Cernavoda NPP participates in a CANDU (Canadian Deuterium Uranium) Owners Group Project (COG HS & E-304) in order to implement the new standard CAN-CSA 288.1-08 for derived emission limits using results of measurements for OBT (organically bound tritium) concentrations in plant and animal products. The method for determination of 3H and 14C in organic samples after separation through non-catalytic combustion by flame oxidation is performed in Sample Oxidizer 307 equipment. Average values for total tritium activity concentration in fish samples of 21 ± 2 Bq/kg fresh weight were determined. Results for 14C have an average value of 327 ± 26 Bq/kg-C in fish from Danube-River and 315 ± 25 Bq/kg-C in fish from lakes. The average values for 14C activity concentration in vegetables samples from Cernavoda and Seimeni areas are about 338 ± 27 Bq/kg-C. 展开更多
关键词 3H 14C ENVIRONMENT organic samples.
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A New Approach for the Measurement of Digestible Carbohydrates in Different Food Samples with HPLC-RI
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作者 S. Devindra T. Longvah 《Journal of Agricultural Science and Technology(B)》 2011年第8期1216-1223,共8页
This paper gives an impetus in quantifying digestible carbohydrates, which are important components of cereals, legumes and vegetables. The HPLC method was applied for the first time in India to estimate the digestibl... This paper gives an impetus in quantifying digestible carbohydrates, which are important components of cereals, legumes and vegetables. The HPLC method was applied for the first time in India to estimate the digestible carbohydrates such as sugars and starches in different branded rice, legumes and vegetable samples which were procured from local market of twin cities of Hyderabad and Secunderabad in Andhra Pradesh State, India. In the present study, we estimated carbohydrates in vitro, mimicking the in vivo condition by incorporating enzymatic digestion. Among the rice varieties the analyzed total soluble sugars were in the range of 5.69% to 9.62%, vegetables 0.0% to 3.72% and legumes 0.04% to 0.98%. Soluble starches in rice samples ranged from 12.51% to 17.64%, in vegetables from 1.73% to 7.28% and in legumes from 23.76% to 38.71%. Insoluble starches in rice samples were observed to be bracketed in between 52.53% to 60.43%, where as in vegetables from 0.58% to 8.83% and in legumes from 16.13% to 29.22%. Concluding our observation, the total amount of starches and total sugars in rice fell in between 74.32% to 80.75%, in vegetables from 1.74% to 16.11%, and in legumes from 39.93% to 68.91%. 展开更多
关键词 STARCHES a-amylase PROTEASE AMYLOGLUCOSIDASE HPLC-RI method digestible carbohydrates.
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Determination of Pesticides Residues in Some Fruits and Vegetables Imported to Iraq
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作者 Ismael Ibrahim Alyaseri Mukhtar Abdul Sattar Ali Abdul Karim Jawad Ali Nadir Kamil Bahi 《Journal of Agricultural Science and Technology(A)》 2012年第1期65-70,共6页
A study was carried out in the laboratories of the National Center for Pesticides Control/State Board for Plant Protection / Ministry of Agriculture in 2010-2011. The aim was to determine the residues of some pesticid... A study was carried out in the laboratories of the National Center for Pesticides Control/State Board for Plant Protection / Ministry of Agriculture in 2010-2011. The aim was to determine the residues of some pesticides in fruits and vegetables imported to Iraq from neighboring countries (Jordan, Syria, Turkey and Iran). Two types of fruits (apples and oranges) and two types of vegetables (tomatoes and cucumber) were selected for the purpose of this study. These fruits and vegetables are the most agricultural products imported for human consumption in Iraq. Samples were taken from different border points and from local markets. Extraction, clean up and analysis were then processed. The results indicated the presence of small amounts of residues of certain pesticides such as Deltamethrin and Abamectin and Thiamethoxam in some samples. However, these amounts were less than the limit allowed internationally. No indication was observed for the presence of other pesticides residues such as Bifenthrin Trticonazol and Imidacloprid ... etc. in the samples analyzed. Therefore, there is a need to continuity of inspection on pesticides residues in agricultural products imported to Iraq in order to prevent the entry of contaminating materials and secure human safety. 展开更多
关键词 Pesticides residues VEGETABLES FRUITS Iraq
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美国调香师对若干食用香料的评价(256)
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《国内外香化信息》 2012年第4期11-12,共2页
(2505)2-甲氧基-3-(甲基丙基)吡嗪 来源——SAFC;FEMA#3433,CAS#24168.70—5;天然来源——甜椒、芦笋、欧防风、莴苣、南瓜、格蓬油;香气特征——@0.1%;霉香,壤香,蔬菜样气息和青香;尝味特征——@0.1ppm:霉味,青香... (2505)2-甲氧基-3-(甲基丙基)吡嗪 来源——SAFC;FEMA#3433,CAS#24168.70—5;天然来源——甜椒、芦笋、欧防风、莴苣、南瓜、格蓬油;香气特征——@0.1%;霉香,壤香,蔬菜样气息和青香;尝味特征——@0.1ppm:霉味,青香味和蔬菜样香味;尝味特征——@0.2ppm:陈蔬菜样味道,青香味,甜椒样的和土壤香味; 展开更多
关键词 美国调香师 食用香料 评价 香气特征 蔬菜样 天然来源 香味 甜椒
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感念街天
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作者 陈德寿 《边疆文学》 2000年第12期44-44,共1页
芒市的街天,是一幅亮丽的风景画。她的亮丽,不是随处可见的瓜果蔬菜样样有,也不是鸡鱼鸭肉沿街摆。而是在这熙攘的街天,能让人从中读出许多的韵味,许多的欣喜。我们这一代人,从久远的老街走来,带着老街苦涩滋味的记忆信步于今日的街天,... 芒市的街天,是一幅亮丽的风景画。她的亮丽,不是随处可见的瓜果蔬菜样样有,也不是鸡鱼鸭肉沿街摆。而是在这熙攘的街天,能让人从中读出许多的韵味,许多的欣喜。我们这一代人,从久远的老街走来,带着老街苦涩滋味的记忆信步于今日的街天,感觉是一张经年的黑白照与今日彩照的对比。打开存封的记忆,依稀如昨天。最初的记忆是牵着母亲的衣角赶芒市街,有炎炎的烈日之时,亦有暴雨瓢泼之日。似乎要走很远的路,脚走痛了,而稚幼的心且很甜很兴奋。跟母亲上街。 展开更多
关键词 记忆 母亲 蔬菜样 风景画 农贸市场 沿街 猪肉 暴雨 感觉 鸭肉
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美国调香师对若干食用香料的评价(287)
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《国内外香化信息》 2014年第11期10-11,共2页
(2754)欧盟天然玫瑰醚Rose Oxide,EU Natural来源——Axxence Aromatic;FEMA#3236,CAS#16409-43-1;天然存在——柑桔油、香叶叶子、荔枝、玫瑰;香气特征——@100%:涩的,青香,叶香,壤香,花香和药草香;尝味特征——@1ppm:青香味,花香... (2754)欧盟天然玫瑰醚Rose Oxide,EU Natural来源——Axxence Aromatic;FEMA#3236,CAS#16409-43-1;天然存在——柑桔油、香叶叶子、荔枝、玫瑰;香气特征——@100%:涩的,青香,叶香,壤香,花香和药草香;尝味特征——@1ppm:青香味,花香味,荔枝样和蔬菜样;尝味特征——@2ppm:青香味,药草味,花香味,蜂蜜样,果味和蔬菜样;建议应用——在低用量水平下,这种有力的化合物可以为水果食品香精,如梨、苹果、红毛丹、荔枝、猕猴桃和白葡萄,以及蔬菜食品香精,如青椒、黄瓜、芥末、水田芹、萝卜等赋予新鲜的青香香调。其他应用领域还包括薄荷和花香食品香精。Axxence Aromatic;www.axxence. 展开更多
关键词 美国调香师 食用香料 评价 香气特征 食品香精 蔬菜样 ROSE 玫瑰醚
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美国调香师对若干食用香料的评价(270)
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《国内外香化信息》 2013年第6期10-11,共2页
(2633)格蓬净油F1435 来源——Biolandes;CFR21172.510,CAS#93165—40.3;天然;香气特征——@1%:青香,蔬菜样香气,新鲜的,轻微的木香和青的胡椒样,并带有一种熏香香韵;尝味特征——@1ppm:青香味,新鲜的蔬菜样味道,轻... (2633)格蓬净油F1435 来源——Biolandes;CFR21172.510,CAS#93165—40.3;天然;香气特征——@1%:青香,蔬菜样香气,新鲜的,轻微的木香和青的胡椒样,并带有一种熏香香韵;尝味特征——@1ppm:青香味,新鲜的蔬菜样味道,轻微的木香味和壤香味;尝味特征——@3ppm:青香味,壤香味,蔬菜样味道,轻微的木香味,蜡香味和叶香味;建议应用——这种强烈的植物提取物可以为蔬菜香精(特别是胡椒、黄瓜、青番茄和生菜香精)提供一种新鲜的青香和土壤香调。用量水平低于1ppm时,可以为水果香精,如西瓜、苹果和梨,以及热带水果如芒果增添新鲜感和天然感。 展开更多
关键词 美国调香师 食用香料 香气特征 评价 热带水果 植物提取物 蔬菜样 香味
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