Numerous innovative heat recovery-to-power technologies have been resourcefully and technologically exploited to bridge the growing gap between energy needs and its sustainable and affordable supply.Among them,the pro...Numerous innovative heat recovery-to-power technologies have been resourcefully and technologically exploited to bridge the growing gap between energy needs and its sustainable and affordable supply.Among them,the proposed trilateral-cycle(TLC) power system exhibits high thermodynamic efficiency during heat recovery-to-power from low-to-medium temperature heat sources.The TLCs are proposed and analysed using n-pentane as working fluid for waste heat recovery-to-power generation from low-grade heat source to evaluate the thermodynamic efficiency of the cycles.Four different single stage TLC configurations with distinct working principles are modelled thermodynamically using engineering equation solver.Based on the thermodynamic framework,thermodynamic performance simulation and efficiency analysis of the cycles as well as the exergy efficiencies of the heating and condensing processes are carried out and compared in their efficiency.The results show that the simple TLC,recuperated TLC,reheat TLC and regenerative TLC operating at subcritical conditions with cycle high temperature of 473 K can attain thermal efficiencies of 21.97%,23.91%,22.07% and 22.9%,respectively.The recuperated TLC attains the highest thermodynamic efficiency at the cycle high temperature because of its lowest exergy destruction rates in the heat exchanger and condenser.The efficiency analysis carried out would assist in guiding thermodynamic process development and thermal integration of the proposed cycles.展开更多
A method for fabricating arrays of microcapsules covalently immobilized onto chemically patterned substrates was developed.The core-shell microparticles with poly(allylamine hydrochloride)(PAH) as the outermost layer ...A method for fabricating arrays of microcapsules covalently immobilized onto chemically patterned substrates was developed.The core-shell microparticles with poly(allylamine hydrochloride)(PAH) as the outermost layer were obtained by layer-by-layer (LbL) assembly,which were further treated with glutaraldehyde to endow the particles with abundant aldehyde groups on their surfaces.The particles were then covalently coupled to the chemically patterned regions with amino groups created by microcontact printing (μCP).After dissolution of the core particles,arrays of the hollow microcapsules with unchanged structures were obtained.These arrays could stand rigorous environmental conditions of higher ionic strength,and lower and higher pH values.Thus,the technique could be possibly applied to exploiting chips of microcontainers or microreactors in sensing technology.展开更多
Sr2Bi4Ti5O18(SBTi) single layered and Sr2Bi4Ti5O18 /Pb(Zr0.53Ti0.47)O3(SBTi/PZT) bilayered thin films have been prepared on Pt/TiO2/SiO2/Si substrates by pulsed-laser deposition(PLD).The related structural characteriz...Sr2Bi4Ti5O18(SBTi) single layered and Sr2Bi4Ti5O18 /Pb(Zr0.53Ti0.47)O3(SBTi/PZT) bilayered thin films have been prepared on Pt/TiO2/SiO2/Si substrates by pulsed-laser deposition(PLD).The related structural characterizations and electrical properties have been comparatively investigated.X-ray diffraction reveals that both films have crystallized into perovskite phases and scanning electron microscopy shows the sharp interfaces.Both films show well-saturated ferroelectric hysteresis loops,however,compared with the single layered SBTi films,the SBTi/PZT bilayered films have significantly increased remnant polarization(Pr) and decreased coercive field(Ec),with the applied field of 260 kV/cm.The measured Pr and Ec of SBTi and SBTi/PZT films were 7.9 C/cm 2,88.1 kV/cm and 13.0 C/cm 2,51.2 kV/cm,respectively.In addition,both films showed good fatigue-free characteristics,the switchable polarization decreased by 9% and 11% of the initial values after 2.2 10 9 switching cycles for the SBTi single layered films and the SBTi/PZT bilayered films,respectively.Our results may provide some guidelines for further optimization of multilayered ferroelectric thin films.展开更多
基金The University of Ilorin,Nigeria financially supported this research through scholarship grant from Tertiary Education Trust Fund
文摘Numerous innovative heat recovery-to-power technologies have been resourcefully and technologically exploited to bridge the growing gap between energy needs and its sustainable and affordable supply.Among them,the proposed trilateral-cycle(TLC) power system exhibits high thermodynamic efficiency during heat recovery-to-power from low-to-medium temperature heat sources.The TLCs are proposed and analysed using n-pentane as working fluid for waste heat recovery-to-power generation from low-grade heat source to evaluate the thermodynamic efficiency of the cycles.Four different single stage TLC configurations with distinct working principles are modelled thermodynamically using engineering equation solver.Based on the thermodynamic framework,thermodynamic performance simulation and efficiency analysis of the cycles as well as the exergy efficiencies of the heating and condensing processes are carried out and compared in their efficiency.The results show that the simple TLC,recuperated TLC,reheat TLC and regenerative TLC operating at subcritical conditions with cycle high temperature of 473 K can attain thermal efficiencies of 21.97%,23.91%,22.07% and 22.9%,respectively.The recuperated TLC attains the highest thermodynamic efficiency at the cycle high temperature because of its lowest exergy destruction rates in the heat exchanger and condenser.The efficiency analysis carried out would assist in guiding thermodynamic process development and thermal integration of the proposed cycles.
基金Project supported by the National Natural Science Foundation of China(Nos.20434030 and 20774084)the National Basic Research Program(973)of China(No. 2005CB623902)the National Science Fund for Distinguished Young Scholars of China(No.50425311)
文摘A method for fabricating arrays of microcapsules covalently immobilized onto chemically patterned substrates was developed.The core-shell microparticles with poly(allylamine hydrochloride)(PAH) as the outermost layer were obtained by layer-by-layer (LbL) assembly,which were further treated with glutaraldehyde to endow the particles with abundant aldehyde groups on their surfaces.The particles were then covalently coupled to the chemically patterned regions with amino groups created by microcontact printing (μCP).After dissolution of the core particles,arrays of the hollow microcapsules with unchanged structures were obtained.These arrays could stand rigorous environmental conditions of higher ionic strength,and lower and higher pH values.Thus,the technique could be possibly applied to exploiting chips of microcontainers or microreactors in sensing technology.
基金supported by the National Natural Science Foundation(Grant Nos. 50805076 and 51275237)the National Natural Science Key Corporation Foundations (Grant No. 61161120323)Science Research Foundation at NUAA (Grant No. NS2012014)
文摘Sr2Bi4Ti5O18(SBTi) single layered and Sr2Bi4Ti5O18 /Pb(Zr0.53Ti0.47)O3(SBTi/PZT) bilayered thin films have been prepared on Pt/TiO2/SiO2/Si substrates by pulsed-laser deposition(PLD).The related structural characterizations and electrical properties have been comparatively investigated.X-ray diffraction reveals that both films have crystallized into perovskite phases and scanning electron microscopy shows the sharp interfaces.Both films show well-saturated ferroelectric hysteresis loops,however,compared with the single layered SBTi films,the SBTi/PZT bilayered films have significantly increased remnant polarization(Pr) and decreased coercive field(Ec),with the applied field of 260 kV/cm.The measured Pr and Ec of SBTi and SBTi/PZT films were 7.9 C/cm 2,88.1 kV/cm and 13.0 C/cm 2,51.2 kV/cm,respectively.In addition,both films showed good fatigue-free characteristics,the switchable polarization decreased by 9% and 11% of the initial values after 2.2 10 9 switching cycles for the SBTi single layered films and the SBTi/PZT bilayered films,respectively.Our results may provide some guidelines for further optimization of multilayered ferroelectric thin films.
