Considering magneto-electro-elastic thin plate, the von Karman plate theory of large deflection and the geometric nonlinearity, the mathematical model of nonlinear undamped forced vibration is established. Making use ...Considering magneto-electro-elastic thin plate, the von Karman plate theory of large deflection and the geometric nonlinearity, the mathematical model of nonlinear undamped forced vibration is established. Making use of the improved Lindstedt-Poincare (L-P) method, the undamped forced vibration problem is solved, and the amplitude-frequency response equation of thin plate is obtained. Furthermore, the amplitude frequency response curves of system under different condi- tions are obtained by numerical simulation. The results show that the thickness of the plate, mechanical excitation, parame- ter e, pure piezoelectric material of BaTiO3, pure piezomagnetic material of CoFe2 04, different magneto-electro-elastic ma- terials of BaTiO3/CoFe2 04 and Terfenol-D/PZT will have an impact on the system frequency response. The main effects in- volve principal resonance interval, spring stiffness characteristic and amplitude jumping phenomena.展开更多
The integration of electronic components and the popularity of flexible devices have come up with higher expectations for the heat dissipation capability and comprehensive mechanical performance of thermal management ...The integration of electronic components and the popularity of flexible devices have come up with higher expectations for the heat dissipation capability and comprehensive mechanical performance of thermal management materials.In this work,after the modification of polyimide(PI)fibers through oxidation and amination,the obtained PDA@OPI fibers(polydopamine(PDA)-modified pre-oxidized PI fibers)with abundant amino groups were mixed into graphene oxide(GO)to form uniform GO-PDA@OPI composites.Followed by evaporation,carbonization,graphitization and mechanical compaction,the G-gPDA@OPI films with a stable three-dimensional(3D)long-range interconnected covalent structure were built.In particular,due to the rich covalent bonds between GO layers and PDI@OPI fibers,the enhanced synergistic graphitization promotes an ordered graphitized structure with less interlayer distance between adjacent graphene sheets in composite film.As a result,the optimized G-gPDA@OPI film displays an improved tensile strength of 78.5 MPa,tensile strain of 19.4%and thermal conductivity of 1028 W/(m·K).Simultaneously,it also shows superior flexibility and high resilience.This work provides an easily-controlled and relatively low-cost route for fabricating multifunctional graphene heat dissipation films.展开更多
Surface modification of Diamond-like carbon (DLC) films was carried out in order to estimate the reliability of the ultra thin DLC films. The wear resistance, conductivity and mechatronic reliability of the films were...Surface modification of Diamond-like carbon (DLC) films was carried out in order to estimate the reliability of the ultra thin DLC films. The wear resistance, conductivity and mechatronic reliability of the films were studied by contact atomic force microscope (AFM), electric force microscope (EFM) and conductive AFM. The failure mechanism of pits formed and the reason for conductivity changed of DLC films were examined.展开更多
The adsorption isotherms of the polysulfone hollow fiber chelating membrane modified with thionrea as chelating groups for Hg^2+ were determined. The effects of mobile phase conditions and the operating parameters on...The adsorption isotherms of the polysulfone hollow fiber chelating membrane modified with thionrea as chelating groups for Hg^2+ were determined. The effects of mobile phase conditions and the operating parameters on removal performance of the chelating membrane for Hg^2+ were also investigated. The recovery of Hg^2+ decreased at low pH and the optimum range of pH was from 6 to 7. The feed concentration effected on recovery of Hg^2+ at the specified loading amount of Hg^2+. The Hg^2+ could be removed from different concentration feed solution by chelating membrane. The increase of feed flow rate led to slight decrease of recovery of Hg^2+ at the specified loading amount of Hg^2+. The chelating membrane could be operated at height feed flow rate and a large-scale removal of H^2+ could be realized. With the increase of load amount, Hg^2+ recovery decreased, but the saturation degree of chelating membrane increased. According to required recovery of H^2+ and the saturation degree of chelating membrane, the optimum loading amount of Hg^2+ should be selected in the actual removal of H^2+.展开更多
Rolling Thin Film Oven Test (RTFOT) is the AASHTO T240 standard method to simulate asphalt plant mix aging. But it has proven inadequate in aging polymer-modified asphalts (PMA). NCHRP 9-10 offered a modified RTF...Rolling Thin Film Oven Test (RTFOT) is the AASHTO T240 standard method to simulate asphalt plant mix aging. But it has proven inadequate in aging polymer-modified asphalts (PMA). NCHRP 9-10 offered a modified RTFOT (MRTFOT) by adding a steel rod in each bottle. Since construction temperature of PMA mixture is 10 ℃ -20 ℃ higher than that of conventional asphalt mixtures in the field, elevating RTFOT temperature for PMA is necessary for adequate aging and proper simulation. Six PMAs with various PG grades and sources were aged with RTFO at elevated temperatures. Some were also treated with MRTFOT for comparison. SHRP performance grade and phase angle were used as indicators to analyze the effects of RTFOT under different conditions. The results show that elevating the temperature is more effective than using rods. And PMA RTFOT temperature could be determined by equiviscous principle. From limited data, O. 25 Pa ~ s is tentatively proposed as critical viscosity for PMA, but still more work is necessary to validate this. Given the fact that equiviscous principle is seldom used in field practice, a simple approach was proposed: 173 ℃ is used for RTFOT of PG70 PMAs (grading herein from un-aged asphalts) , while 178 ℃ is for PMAs of PG76 or PG82 and 20 ℃ higher than standard 163 ℃ is necessary for PG 88 or stiffer PMAs.展开更多
Polydimethylsiloxane (PDMS), tetraethoxysilane (TEOS), ethyl alcohol (EtOH) and deionized water were main raw materials to prepare silicone-modified hybrid thin films using sol-gel method. The effect of the cont...Polydimethylsiloxane (PDMS), tetraethoxysilane (TEOS), ethyl alcohol (EtOH) and deionized water were main raw materials to prepare silicone-modified hybrid thin films using sol-gel method. The effect of the contents of H2O and PDMS on thin films was studied. When the volume ratio of H20 to TEOS is 0.5, the optimum quality of thin films is obtained. And the gelation time is affected slightly by H20 content. Uniform thin films are obtained when the volume ratio of PDMS to TEOS is 0.2. Yet, the sol would be inactive in 6 d. Various properties of thin films were studied, including hardness, adhesive quality, hydrophobic property, corrosion protection property, and abrasion resistance. Test results show that the pencil hardness is generally 3-6 H, and adhesive quality achieves the highest standard of 0. When the sintering temperature is below 400℃, the contact angle is about 95° and hydrophobic films are obtained. The abrasion resistance of thin films is better than that of aluminum alloy when the sintering temperature is higher than 300℃. And the excellent corrosion protective effect is obtained by single-layer coating when the sintering temperature is higher than 400℃.展开更多
A simple and rapid colorimetric method for the and Whatman filter paper chromatography is described. determination of some amino acids on thin layer chromatography (TLC) The studied compounds are cysteine, proline, ...A simple and rapid colorimetric method for the and Whatman filter paper chromatography is described. determination of some amino acids on thin layer chromatography (TLC) The studied compounds are cysteine, proline, methionine, tryptophan glutmine, glycine, thyrosine, threonine, leucine and lysine. The method is based on the formation of color from the reaction of stannous chloride (SnCI2) and ninhydrin reagents. The procedure has been successfully applied to the assay of the standard amino acid preparation after TLC separation, and the results of the studied compounds were clear and favorable, comparing to the official methods. However, the improved TLC is much more efficient for the detection of amino acid. The main advantage of this method is that the detection of amino acids can be preformed visually.展开更多
The n-type semiconducting titanium oxide thin films are well-known as electron transporting interlayer in photovoltaic cells. The favorable characteristics of interlayers in photovoltaics are high optical transmittan...The n-type semiconducting titanium oxide thin films are well-known as electron transporting interlayer in photovoltaic cells. The favorable characteristics of interlayers in photovoltaics are high optical transmittance (T%), wide band gap energy (Eg) and high electrical conductivity (σ). Modifying titanium oxide films with metal nanoparticles would increase electrical conductivity but reduce optical band gap energy. We developed the sol-gel derived titanium suboxide (TiOx) films modified with silver (Ag) or gold (Au) or copper (Cu) nanoparticles (NPs). This study explores a tradeoff between narrowing optical band gap and enhancing electrical conductivity of nanostructured TiOx films by controlling the Au- or Ag- or Cu-NPs loading concentrations (mol%) in titania. The Au- and Cu-NPs loading concentration of 4 mol% should meet a tradeoff which yields the higher T%, wider Eg and higher compared to those of pure TiOx films. In addition, since the pure Cu is not thermodynamically stable in ambience as compared to Au and Ag, the stability of as-obtained colloidal CuNPs is also examined. A careful examination of the time evolution of surface plasmon resonance (SPR) bands of CuNPs indicates that their stability is only up to 4 h.展开更多
An experiment on retail film packaging system was conducted to compare the atmospheric composition within sealed packs containing rambutan fruits. This research was done in order to study the effect of packaging films...An experiment on retail film packaging system was conducted to compare the atmospheric composition within sealed packs containing rambutan fruits. This research was done in order to study the effect of packaging films with different permeability on the some of physicochemical properties of rambutan during storage at 10℃. The films used were 0.090 mm low density polyethylene (LDPE), 0.040 mm polyprophylene and 0.057 mm LDPE compared unwrapped fruits. Fruits were evaluated every 5 days for changes in moisture content, total sugars, vitamin C, hardness and color. Unwrapped rambutan had severe browning after 10 days. Sealed packages especially the LDPE had delayed the development of the browning for 20 days of storage and had the lowest weight loss.展开更多
The article investigated the influence of modification process parameters on dispersity of MWNTs DI (in deionized) water and PVA/MWNT composite's electrical conductivity. Experimental results obtained by SEM (scan...The article investigated the influence of modification process parameters on dispersity of MWNTs DI (in deionized) water and PVA/MWNT composite's electrical conductivity. Experimental results obtained by SEM (scanning electron microscope), TEM (transmission electron microscope), transform Fourier infrared spectroscopy, pH meter confirmed the most effective conditions in modifying the MWNT surface at the 1:3 mixture of nitric and sulfuric acid at 60 ℃. The extinction coefficient value of functionalized MWNTs at 500 nm wavelength was determined to be 41.24 cm^2·mg^-1, while their dispersibility in DI water was about 12.85 mg/mL and stable in more than 3 weeks via UV-vis spectroscopy. The other important result is the decrease of volume resistivity from 7.98 × 10^6 MΩ·m ofPVA (polyvinyl alcohol) to 4.15 × 10^4 MΩ·m of PVA/1 wt% modified MWNT thin film.展开更多
A uniform and dense TiO2 film was grown on the surface of porous NiTi shape memory alloys(SMAs) successfully by RF magnetron sputtering.The morphology and composition of the surface film were analyzed by using scannin...A uniform and dense TiO2 film was grown on the surface of porous NiTi shape memory alloys(SMAs) successfully by RF magnetron sputtering.The morphology and composition of the surface film were analyzed by using scanning electron microscopy and X-ray photoelectron spectroscopy.The corrosion resistance measurement proved that the surface modified porous NiTi SMAs exhibit better corrosion resistance and over 25% reduction of Ni ion release in the blood of the rabbits in comparing with the samples without surface modification.Moreover,the biocompatibility,as demonstrated by cell adherence and implant surgery,revealed that the cell adherence and bone tissue inducing capability are respectively enhanced over 1.1-1.2 and 9-10 times by sputtering a uniform TiO2 film on the surfaces of porous NiTi SMAs.展开更多
A series of Cr/SmCo/Cr films with high Sm concentration(37.7at%) were prepared by magnetron sputtering.Effects of SmCo thickness,annealing temperature,and annealing time on magnetic properties and crystal structure we...A series of Cr/SmCo/Cr films with high Sm concentration(37.7at%) were prepared by magnetron sputtering.Effects of SmCo thickness,annealing temperature,and annealing time on magnetic properties and crystal structure were carefully studied.Results show that crystallization degree and phase transition in the films can be controlled by the SmCo thickness and optimized by properly increasing the annealing temperature and extending the annealing time.Finally,a SmCo film with high magnetic properties and low MEI was constructed.展开更多
基金National Natural Science Foundation of China(No.11202190)Scientific Research Staring Foundation for the Returned Overseas Chinese Scholars,Ministry of Education,ChinaResearch Project Supported by Shanxi Scholarship Council of China(No.2013-085)
文摘Considering magneto-electro-elastic thin plate, the von Karman plate theory of large deflection and the geometric nonlinearity, the mathematical model of nonlinear undamped forced vibration is established. Making use of the improved Lindstedt-Poincare (L-P) method, the undamped forced vibration problem is solved, and the amplitude-frequency response equation of thin plate is obtained. Furthermore, the amplitude frequency response curves of system under different condi- tions are obtained by numerical simulation. The results show that the thickness of the plate, mechanical excitation, parame- ter e, pure piezoelectric material of BaTiO3, pure piezomagnetic material of CoFe2 04, different magneto-electro-elastic ma- terials of BaTiO3/CoFe2 04 and Terfenol-D/PZT will have an impact on the system frequency response. The main effects in- volve principal resonance interval, spring stiffness characteristic and amplitude jumping phenomena.
基金Projects(51971089, 51872087) supported by the National Natural Science Foundation of ChinaProject(2020JJ5021)supported by the Natural Science Foundation of Hunan Province,ChinaProject(kq1804010) supported by the Major Science and Technology Program of Changsha,China。
文摘The integration of electronic components and the popularity of flexible devices have come up with higher expectations for the heat dissipation capability and comprehensive mechanical performance of thermal management materials.In this work,after the modification of polyimide(PI)fibers through oxidation and amination,the obtained PDA@OPI fibers(polydopamine(PDA)-modified pre-oxidized PI fibers)with abundant amino groups were mixed into graphene oxide(GO)to form uniform GO-PDA@OPI composites.Followed by evaporation,carbonization,graphitization and mechanical compaction,the G-gPDA@OPI films with a stable three-dimensional(3D)long-range interconnected covalent structure were built.In particular,due to the rich covalent bonds between GO layers and PDI@OPI fibers,the enhanced synergistic graphitization promotes an ordered graphitized structure with less interlayer distance between adjacent graphene sheets in composite film.As a result,the optimized G-gPDA@OPI film displays an improved tensile strength of 78.5 MPa,tensile strain of 19.4%and thermal conductivity of 1028 W/(m·K).Simultaneously,it also shows superior flexibility and high resilience.This work provides an easily-controlled and relatively low-cost route for fabricating multifunctional graphene heat dissipation films.
文摘Surface modification of Diamond-like carbon (DLC) films was carried out in order to estimate the reliability of the ultra thin DLC films. The wear resistance, conductivity and mechatronic reliability of the films were studied by contact atomic force microscope (AFM), electric force microscope (EFM) and conductive AFM. The failure mechanism of pits formed and the reason for conductivity changed of DLC films were examined.
基金the Natural Science Foundation of Tianjin (No05YFJ MJC04200)
文摘The adsorption isotherms of the polysulfone hollow fiber chelating membrane modified with thionrea as chelating groups for Hg^2+ were determined. The effects of mobile phase conditions and the operating parameters on removal performance of the chelating membrane for Hg^2+ were also investigated. The recovery of Hg^2+ decreased at low pH and the optimum range of pH was from 6 to 7. The feed concentration effected on recovery of Hg^2+ at the specified loading amount of Hg^2+. The Hg^2+ could be removed from different concentration feed solution by chelating membrane. The increase of feed flow rate led to slight decrease of recovery of Hg^2+ at the specified loading amount of Hg^2+. The chelating membrane could be operated at height feed flow rate and a large-scale removal of H^2+ could be realized. With the increase of load amount, Hg^2+ recovery decreased, but the saturation degree of chelating membrane increased. According to required recovery of H^2+ and the saturation degree of chelating membrane, the optimum loading amount of Hg^2+ should be selected in the actual removal of H^2+.
文摘Rolling Thin Film Oven Test (RTFOT) is the AASHTO T240 standard method to simulate asphalt plant mix aging. But it has proven inadequate in aging polymer-modified asphalts (PMA). NCHRP 9-10 offered a modified RTFOT (MRTFOT) by adding a steel rod in each bottle. Since construction temperature of PMA mixture is 10 ℃ -20 ℃ higher than that of conventional asphalt mixtures in the field, elevating RTFOT temperature for PMA is necessary for adequate aging and proper simulation. Six PMAs with various PG grades and sources were aged with RTFO at elevated temperatures. Some were also treated with MRTFOT for comparison. SHRP performance grade and phase angle were used as indicators to analyze the effects of RTFOT under different conditions. The results show that elevating the temperature is more effective than using rods. And PMA RTFOT temperature could be determined by equiviscous principle. From limited data, O. 25 Pa ~ s is tentatively proposed as critical viscosity for PMA, but still more work is necessary to validate this. Given the fact that equiviscous principle is seldom used in field practice, a simple approach was proposed: 173 ℃ is used for RTFOT of PG70 PMAs (grading herein from un-aged asphalts) , while 178 ℃ is for PMAs of PG76 or PG82 and 20 ℃ higher than standard 163 ℃ is necessary for PG 88 or stiffer PMAs.
基金supported partly by the School of Mechanical,Electronic and Control Engineering,Beijing Jiaotong university,China
文摘Polydimethylsiloxane (PDMS), tetraethoxysilane (TEOS), ethyl alcohol (EtOH) and deionized water were main raw materials to prepare silicone-modified hybrid thin films using sol-gel method. The effect of the contents of H2O and PDMS on thin films was studied. When the volume ratio of H20 to TEOS is 0.5, the optimum quality of thin films is obtained. And the gelation time is affected slightly by H20 content. Uniform thin films are obtained when the volume ratio of PDMS to TEOS is 0.2. Yet, the sol would be inactive in 6 d. Various properties of thin films were studied, including hardness, adhesive quality, hydrophobic property, corrosion protection property, and abrasion resistance. Test results show that the pencil hardness is generally 3-6 H, and adhesive quality achieves the highest standard of 0. When the sintering temperature is below 400℃, the contact angle is about 95° and hydrophobic films are obtained. The abrasion resistance of thin films is better than that of aluminum alloy when the sintering temperature is higher than 300℃. And the excellent corrosion protective effect is obtained by single-layer coating when the sintering temperature is higher than 400℃.
文摘A simple and rapid colorimetric method for the and Whatman filter paper chromatography is described. determination of some amino acids on thin layer chromatography (TLC) The studied compounds are cysteine, proline, methionine, tryptophan glutmine, glycine, thyrosine, threonine, leucine and lysine. The method is based on the formation of color from the reaction of stannous chloride (SnCI2) and ninhydrin reagents. The procedure has been successfully applied to the assay of the standard amino acid preparation after TLC separation, and the results of the studied compounds were clear and favorable, comparing to the official methods. However, the improved TLC is much more efficient for the detection of amino acid. The main advantage of this method is that the detection of amino acids can be preformed visually.
文摘The n-type semiconducting titanium oxide thin films are well-known as electron transporting interlayer in photovoltaic cells. The favorable characteristics of interlayers in photovoltaics are high optical transmittance (T%), wide band gap energy (Eg) and high electrical conductivity (σ). Modifying titanium oxide films with metal nanoparticles would increase electrical conductivity but reduce optical band gap energy. We developed the sol-gel derived titanium suboxide (TiOx) films modified with silver (Ag) or gold (Au) or copper (Cu) nanoparticles (NPs). This study explores a tradeoff between narrowing optical band gap and enhancing electrical conductivity of nanostructured TiOx films by controlling the Au- or Ag- or Cu-NPs loading concentrations (mol%) in titania. The Au- and Cu-NPs loading concentration of 4 mol% should meet a tradeoff which yields the higher T%, wider Eg and higher compared to those of pure TiOx films. In addition, since the pure Cu is not thermodynamically stable in ambience as compared to Au and Ag, the stability of as-obtained colloidal CuNPs is also examined. A careful examination of the time evolution of surface plasmon resonance (SPR) bands of CuNPs indicates that their stability is only up to 4 h.
文摘An experiment on retail film packaging system was conducted to compare the atmospheric composition within sealed packs containing rambutan fruits. This research was done in order to study the effect of packaging films with different permeability on the some of physicochemical properties of rambutan during storage at 10℃. The films used were 0.090 mm low density polyethylene (LDPE), 0.040 mm polyprophylene and 0.057 mm LDPE compared unwrapped fruits. Fruits were evaluated every 5 days for changes in moisture content, total sugars, vitamin C, hardness and color. Unwrapped rambutan had severe browning after 10 days. Sealed packages especially the LDPE had delayed the development of the browning for 20 days of storage and had the lowest weight loss.
文摘The article investigated the influence of modification process parameters on dispersity of MWNTs DI (in deionized) water and PVA/MWNT composite's electrical conductivity. Experimental results obtained by SEM (scanning electron microscope), TEM (transmission electron microscope), transform Fourier infrared spectroscopy, pH meter confirmed the most effective conditions in modifying the MWNT surface at the 1:3 mixture of nitric and sulfuric acid at 60 ℃. The extinction coefficient value of functionalized MWNTs at 500 nm wavelength was determined to be 41.24 cm^2·mg^-1, while their dispersibility in DI water was about 12.85 mg/mL and stable in more than 3 weeks via UV-vis spectroscopy. The other important result is the decrease of volume resistivity from 7.98 × 10^6 MΩ·m ofPVA (polyvinyl alcohol) to 4.15 × 10^4 MΩ·m of PVA/1 wt% modified MWNT thin film.
基金supported by the National Natural Science Foundation of China (Grant No. 50701019)the Fundamental Research Funds for the Central Universities (Grant No. 2009ZM0258)the Guangdong Provincial Science and Technology Project (Grant No. 2010B031100004)
文摘A uniform and dense TiO2 film was grown on the surface of porous NiTi shape memory alloys(SMAs) successfully by RF magnetron sputtering.The morphology and composition of the surface film were analyzed by using scanning electron microscopy and X-ray photoelectron spectroscopy.The corrosion resistance measurement proved that the surface modified porous NiTi SMAs exhibit better corrosion resistance and over 25% reduction of Ni ion release in the blood of the rabbits in comparing with the samples without surface modification.Moreover,the biocompatibility,as demonstrated by cell adherence and implant surgery,revealed that the cell adherence and bone tissue inducing capability are respectively enhanced over 1.1-1.2 and 9-10 times by sputtering a uniform TiO2 film on the surfaces of porous NiTi SMAs.
基金supported by the National Natural Science Foundation of China(Grant Nos.50901007 and 11174020)the Postdoctoral Science Foundation of China(Grant No.201003049)+2 种基金the Foundation of Key Laboratory for Advanced Materials Processing Technology,Ministry of Education,China(Grant No.2010001)the Fundamental Research Funds for the Central Universitiesthe New Teacher Foundation of Ministry of Education(Grant No.200800081030)
文摘A series of Cr/SmCo/Cr films with high Sm concentration(37.7at%) were prepared by magnetron sputtering.Effects of SmCo thickness,annealing temperature,and annealing time on magnetic properties and crystal structure were carefully studied.Results show that crystallization degree and phase transition in the films can be controlled by the SmCo thickness and optimized by properly increasing the annealing temperature and extending the annealing time.Finally,a SmCo film with high magnetic properties and low MEI was constructed.