Patterned porous silicon （PS） films were synthesised by using bydrogen ion implantation technique and typical electrochemical anodic etching method.The surface morphology and characteristics of the PS films were cha...Patterned porous silicon （PS） films were synthesised by using bydrogen ion implantation technique and typical electrochemical anodic etching method.The surface morphology and characteristics of the PS films were characterized by scanning electron microscopy （SEM）,X-ray diffraction（XRD）,and atomic force microscopy （AFM）.The efficient electron field emission with low turn-on field of about 3.5V/μm was obtained at current density of 0.1μA/cm^2.The electron field emission current density from the patterned PS films reached 1mA/cm^2 under and applied field of about 12.5V/μm.The experimental results show that the patterned PS films are of certain practical significance and are valuable for flat panel displays.展开更多
Semiconductor-type TiO2 oxygen sensing thin films were synthesized using tetrabutyl titanate （Ti （OBu）4） as precursor and diethanolamine （DEA） as complexing agent by the sol-get process. The porous and oxygen se...Semiconductor-type TiO2 oxygen sensing thin films were synthesized using tetrabutyl titanate （Ti （OBu）4） as precursor and diethanolamine （DEA） as complexing agent by the sol-get process. The porous and oxygen sensing TiO2 films were obtained by the addition of polyethylene glycol （PEG）. The micrographs of scanning electron microscope （SEM） show that the pores of the sample about 400-600 nm in size with PEG（2 000 g/mol） are larger than those about 300 nm in size with PEG（ 1 000 g/mol）, while the density of pores is lower. The results also indicate that increasing the content of PEG properly is beneficial to the formation of porous structure. With the increasing content of PEG from 0 g to 2.5 g, the oxygen sensitivity increases from 330 to more than 1 000 at 800 ℃, from 170 to more than 1 000 at 900℃, and the response time to O2 and H2 are about 1.5 s and less than 1s, respectively.展开更多
Both of planar and mesoporous architectures prevail for perovskite solar cells(PSCs).However,it is still an open question how the architecture affects the performance of PSCs.The inconsistent results in the references...Both of planar and mesoporous architectures prevail for perovskite solar cells(PSCs).However,it is still an open question how the architecture affects the performance of PSCs.The inconsistent results in the references often create confusion.In particular,the specific roles of mesoporous frameworks are yet to be well elaborated and require further clarification.In this study,we carefully compared the properties of perovskite films and the device performances for both architectures to unravel the roles of mesoporous TiO2 framworks in CH3NH3PbI3 PSCs.The detailed characterizations of structural,microscopic,optical and electrical properties revealed that the presence of mesoporous TiO2 framework contributed to enlarged perovskite crystal sizes,enhanced light harvesting,efficient electron extration and suppressed charge recombination.As a result,compared with the planar device,the mesoporous device yielded an improved power conversion efficiency of 18.18%,coupled with a reduced hystersis.This study reveals the benefits of mesoporous TiO2 framework in PSCs and provides the guidance for the design and optimization of architectures for high-performance devices.展开更多
基金National Natural Science Foundation of China (60476004) Foundation of Graduate Students of East ChinaNormal University(ECNU2005) Foundation of State Key Laboratory of Advanced Technology for MaterialsSynthesis and Processing( Wuhan University of Tech
文摘Patterned porous silicon （PS） films were synthesised by using bydrogen ion implantation technique and typical electrochemical anodic etching method.The surface morphology and characteristics of the PS films were characterized by scanning electron microscopy （SEM）,X-ray diffraction（XRD）,and atomic force microscopy （AFM）.The efficient electron field emission with low turn-on field of about 3.5V/μm was obtained at current density of 0.1μA/cm^2.The electron field emission current density from the patterned PS films reached 1mA/cm^2 under and applied field of about 12.5V/μm.The experimental results show that the patterned PS films are of certain practical significance and are valuable for flat panel displays.
基金National Natural Science Foundation of China (No 59995520)
文摘Semiconductor-type TiO2 oxygen sensing thin films were synthesized using tetrabutyl titanate （Ti （OBu）4） as precursor and diethanolamine （DEA） as complexing agent by the sol-get process. The porous and oxygen sensing TiO2 films were obtained by the addition of polyethylene glycol （PEG）. The micrographs of scanning electron microscope （SEM） show that the pores of the sample about 400-600 nm in size with PEG（2 000 g/mol） are larger than those about 300 nm in size with PEG（ 1 000 g/mol）, while the density of pores is lower. The results also indicate that increasing the content of PEG properly is beneficial to the formation of porous structure. With the increasing content of PEG from 0 g to 2.5 g, the oxygen sensitivity increases from 330 to more than 1 000 at 800 ℃, from 170 to more than 1 000 at 900℃, and the response time to O2 and H2 are about 1.5 s and less than 1s, respectively.
基金financially supported by the National Natural Science Foundation of China(51602088)the Open Fund of the Key Laboratory of Photovoltaic and Energy Conservation Materials,Chinese Academy of Sciences(PECL2019KF007)and China Postdoctoral Science Foundation(2017T100313)。
文摘Both of planar and mesoporous architectures prevail for perovskite solar cells(PSCs).However,it is still an open question how the architecture affects the performance of PSCs.The inconsistent results in the references often create confusion.In particular,the specific roles of mesoporous frameworks are yet to be well elaborated and require further clarification.In this study,we carefully compared the properties of perovskite films and the device performances for both architectures to unravel the roles of mesoporous TiO2 framworks in CH3NH3PbI3 PSCs.The detailed characterizations of structural,microscopic,optical and electrical properties revealed that the presence of mesoporous TiO2 framework contributed to enlarged perovskite crystal sizes,enhanced light harvesting,efficient electron extration and suppressed charge recombination.As a result,compared with the planar device,the mesoporous device yielded an improved power conversion efficiency of 18.18%,coupled with a reduced hystersis.This study reveals the benefits of mesoporous TiO2 framework in PSCs and provides the guidance for the design and optimization of architectures for high-performance devices.
