Saffron, obtained from the flower stigmas of Crocus sativus L., is one of the most expensive food spices. The introduction of saffron in alpine areas could help to broaden and diversify the activities of mountain mult...Saffron, obtained from the flower stigmas of Crocus sativus L., is one of the most expensive food spices. The introduction of saffron in alpine areas could help to broaden and diversify the activities of mountain multifunctional farms, with a positive impact on economy and land management. According to ISO 3632(2010/2011), saffron can be classified into three categories of quality(I, II, III) depending on the concentration of the three main metabolites responsible for its characteristic colour, flavor and aroma: Crocin, Picrocrocin and Safranal. This study represents the first investigation of the quality of saffron produced in the Italian Alps evaluated with spectrophotometry, HPLC, solid-phase microextraction(SPME), and gas chromatographic analysis combined with mass spectrometry(GC/MS). The experiments used Crocus sativus stigmas produced in 2012-2013 in different areas of the Central Italian Alps were located at an altitude between 720 and 1200 m a.s.l.. Results obtained were compared to commercial saffron. The analyses confirmed that all samples can be classified in the first quality category according to the ISO classification. This high quality is also confirmed by HPLC analysis. Moreover, the SPME-GC/MS analysis identified some differences in the aromatic profile of saffron samples, in particular regarding safranal concentration. A preliminary assessment of the economic viability of high quality saffron production for local markets was also performed. Our study provides valid information regarding the quality and economic sustainability of saffron production in the alpine area confirming this crop as a good candidate for a new source of income for multifunctional farms in mountain areas.展开更多
In weak acidic medium the alkaline cationic Safranine T interacts with acidic biological rnacromolecule heparin intensively causing the change of the molecular conformation, the maximum absorption wavelength and the a...In weak acidic medium the alkaline cationic Safranine T interacts with acidic biological rnacromolecule heparin intensively causing the change of the molecular conformation, the maximum absorption wavelength and the absorption value. The optimum experimental condition was given and a new method to determine the heparin was established. The linear range was 0.05-2.0 mg/L and the correlation coefficient was 0.9974. The method has been applied to analyze the samples and the results are satisfactory. Furthermore, the interaction mechanism was indicated.展开更多
A quick and sensitive method was developed for the determination of 19 metal elements in Saffron,a traditional Chinese medicinal herb,collected from Tibet Autonomous Region and Henan Province of China using inductivel...A quick and sensitive method was developed for the determination of 19 metal elements in Saffron,a traditional Chinese medicinal herb,collected from Tibet Autonomous Region and Henan Province of China using inductively coupled plasma atomic emission spectrometry（ICP-AES）or inductively coupled plasma mass spectrometry（ICP-MS）.The determined 19 metals in Saffron include Ca,Fe,Mg,P,Sr,Al,Mn,Zn,V,Cr,Se,Co,Ni,Mo,and heavy metals As,Cu,Cd,Hg and Pb.For all the analyzed elements,the correlative coefficients of the calibration curves were no less than 0.9938.This proposed method was accurate,and the relative standard deviations of the measurements were lower than 5.25%.It can be used for the quality control of metal elements in Saffron.展开更多
The Pliocene fluvial/lacustrine sediments of the Sanying Formation lie along the Red River fault and its northwest extension;their majority outcrops appear around Eryuan.The Sanying Formation is characterized by multi...The Pliocene fluvial/lacustrine sediments of the Sanying Formation lie along the Red River fault and its northwest extension;their majority outcrops appear around Eryuan.The Sanying Formation is characterized by multiple intercalated coal layers and its unconformities contact with the underlying Triassic limestone and the overlying Quaternary coarse sediments.Cosmogenic nuclide burial dating confirms the Pliocene age of the Sanying Formation.The burial ages of the overlying Quaternary sediments provide the lower age limit of the Sanying Formation:2 Ma.Detrital zircon U-Pb age distribution suggests provenance of the Sanying Formation traced to the Songpan-Ganzi flysch belt.From the spatial distribution as well as sedimentary and fault ages,we found a strong connection of the Sanying Formation with the Red River and the Jianchuan faults.We therefore propose that activation of the Red River and the Jianchuan faults during the Late Miocene resulted in subsidence of basins in the extensional areas around Eryuan and in the middle to south segments of the Red River fault.The basins were filled with water carried by the Jinsha River and overflow-lakes formed within the basins where the Sanying Formation was deposited.Most of the lakes were dried and sedimentation of the Sanying Formation ceased due to the uplift of the Yunling Mountains,which forced rerouting of the Jinsha River at the beginning of Quaternary.展开更多
基金partly supported by "Accordo di Programma, affermazione in Edolo del Centro di Eccellenza Università della Montagna" MIURUniversità degli Studi di Milano, prot. no. 386 1293-05/08/2011 and by Fondazione della Comunità Bresciana- Onlus
文摘Saffron, obtained from the flower stigmas of Crocus sativus L., is one of the most expensive food spices. The introduction of saffron in alpine areas could help to broaden and diversify the activities of mountain multifunctional farms, with a positive impact on economy and land management. According to ISO 3632(2010/2011), saffron can be classified into three categories of quality(I, II, III) depending on the concentration of the three main metabolites responsible for its characteristic colour, flavor and aroma: Crocin, Picrocrocin and Safranal. This study represents the first investigation of the quality of saffron produced in the Italian Alps evaluated with spectrophotometry, HPLC, solid-phase microextraction(SPME), and gas chromatographic analysis combined with mass spectrometry(GC/MS). The experiments used Crocus sativus stigmas produced in 2012-2013 in different areas of the Central Italian Alps were located at an altitude between 720 and 1200 m a.s.l.. Results obtained were compared to commercial saffron. The analyses confirmed that all samples can be classified in the first quality category according to the ISO classification. This high quality is also confirmed by HPLC analysis. Moreover, the SPME-GC/MS analysis identified some differences in the aromatic profile of saffron samples, in particular regarding safranal concentration. A preliminary assessment of the economic viability of high quality saffron production for local markets was also performed. Our study provides valid information regarding the quality and economic sustainability of saffron production in the alpine area confirming this crop as a good candidate for a new source of income for multifunctional farms in mountain areas.
文摘In weak acidic medium the alkaline cationic Safranine T interacts with acidic biological rnacromolecule heparin intensively causing the change of the molecular conformation, the maximum absorption wavelength and the absorption value. The optimum experimental condition was given and a new method to determine the heparin was established. The linear range was 0.05-2.0 mg/L and the correlation coefficient was 0.9974. The method has been applied to analyze the samples and the results are satisfactory. Furthermore, the interaction mechanism was indicated.
文摘A quick and sensitive method was developed for the determination of 19 metal elements in Saffron,a traditional Chinese medicinal herb,collected from Tibet Autonomous Region and Henan Province of China using inductively coupled plasma atomic emission spectrometry（ICP-AES）or inductively coupled plasma mass spectrometry（ICP-MS）.The determined 19 metals in Saffron include Ca,Fe,Mg,P,Sr,Al,Mn,Zn,V,Cr,Se,Co,Ni,Mo,and heavy metals As,Cu,Cd,Hg and Pb.For all the analyzed elements,the correlative coefficients of the calibration curves were no less than 0.9938.This proposed method was accurate,and the relative standard deviations of the measurements were lower than 5.25%.It can be used for the quality control of metal elements in Saffron.
基金supported by the"Strategic Priority Research Program"of the Chinese Academy of Sciences(Grant No.XDB03020300)National Natural Science Foundation of China(Grant Nos.41173067&41021063)
文摘The Pliocene fluvial/lacustrine sediments of the Sanying Formation lie along the Red River fault and its northwest extension;their majority outcrops appear around Eryuan.The Sanying Formation is characterized by multiple intercalated coal layers and its unconformities contact with the underlying Triassic limestone and the overlying Quaternary coarse sediments.Cosmogenic nuclide burial dating confirms the Pliocene age of the Sanying Formation.The burial ages of the overlying Quaternary sediments provide the lower age limit of the Sanying Formation:2 Ma.Detrital zircon U-Pb age distribution suggests provenance of the Sanying Formation traced to the Songpan-Ganzi flysch belt.From the spatial distribution as well as sedimentary and fault ages,we found a strong connection of the Sanying Formation with the Red River and the Jianchuan faults.We therefore propose that activation of the Red River and the Jianchuan faults during the Late Miocene resulted in subsidence of basins in the extensional areas around Eryuan and in the middle to south segments of the Red River fault.The basins were filled with water carried by the Jinsha River and overflow-lakes formed within the basins where the Sanying Formation was deposited.Most of the lakes were dried and sedimentation of the Sanying Formation ceased due to the uplift of the Yunling Mountains,which forced rerouting of the Jinsha River at the beginning of Quaternary.
