Heterogeneous catalysts with ultra-small clusters and atomically dispersed(USCAD)active sites have gained increasing attention in recent years.However,developing USCAD catalysts with high-density metal sites anchored ...Heterogeneous catalysts with ultra-small clusters and atomically dispersed(USCAD)active sites have gained increasing attention in recent years.However,developing USCAD catalysts with high-density metal sites anchored in porous nanomaterials is still challenging.Here,through the template-free S-assisted pyrolysis of low-cost Fe-salts with melamine(MA),porous alveolate Fe/g-C3N4 catalysts with high-density(Fe loading up to 17.7 wt%)and increased USCAD Fe sites were synthesized.The presence of a certain amount of S species in the Fe-salts/MA system plays an important role in the formation of USCAD S-Fe-salt/CN catalysts;the S species act as a"sacrificial carrier"to increase the dispersion of Fe species through Fe-S coordination and generate porous alveolate structure by escaping in the form of SO2 during pyrolysis.The S-Fe-salt/CN catalysts exhibit greatly promoted activity and reusability for degrading various organic pollutants in advanced oxidation processes compared to the corresponding Fe-salt/CN catalysts,due to the promoted accessibility of USCAD Fe sites by the porous alveolate structure.This S-assisted method exhibits good feasibility in a large variety of S species(thiourea,S powder,and NH4SCN)and Fe salts,providing a new avenue for the low-cost and large-scale synthesis of high-density USCAD metal/g-C3N4 catalysts.展开更多
Since more and more mobile applications are based on the proliferation of social information, the study of Mobile Social Networks （MSNs） combines social sciences and wireless communications. Operating wireless netwo...Since more and more mobile applications are based on the proliferation of social information, the study of Mobile Social Networks （MSNs） combines social sciences and wireless communications. Operating wireless networks more efficiently by exploiting social relationships between MSN users is an appealing but challenging option for network operators. An MSN-aided content dissemination technique is presented as a potential extension of conventional cellular wireless networks in order to satisfy growing data traffic. By allowing the MSN users to create a self-organized ad hoc network for spontaneously disseminating contents, the network operator may be able to reduce the operational costs and simultaneously achieve an improved network performance. In this paper, we first summarize the basic features of the MSN architecture, followed by a survey of the factors which may affect MSN-aided content dissemination. Using a case study, we demonstrate that one can save resources of the Base Station （BS） while substantially lowering content dissemination delay. Finally, other potential applications of MSN-aided content dissemination are introduced, and a range of lustre challenges are summarized.展开更多
文摘Heterogeneous catalysts with ultra-small clusters and atomically dispersed(USCAD)active sites have gained increasing attention in recent years.However,developing USCAD catalysts with high-density metal sites anchored in porous nanomaterials is still challenging.Here,through the template-free S-assisted pyrolysis of low-cost Fe-salts with melamine(MA),porous alveolate Fe/g-C3N4 catalysts with high-density(Fe loading up to 17.7 wt%)and increased USCAD Fe sites were synthesized.The presence of a certain amount of S species in the Fe-salts/MA system plays an important role in the formation of USCAD S-Fe-salt/CN catalysts;the S species act as a"sacrificial carrier"to increase the dispersion of Fe species through Fe-S coordination and generate porous alveolate structure by escaping in the form of SO2 during pyrolysis.The S-Fe-salt/CN catalysts exhibit greatly promoted activity and reusability for degrading various organic pollutants in advanced oxidation processes compared to the corresponding Fe-salt/CN catalysts,due to the promoted accessibility of USCAD Fe sites by the porous alveolate structure.This S-assisted method exhibits good feasibility in a large variety of S species(thiourea,S powder,and NH4SCN)and Fe salts,providing a new avenue for the low-cost and large-scale synthesis of high-density USCAD metal/g-C3N4 catalysts.
基金support of the RC-UK’s India-UK Advanced Technology Centre (IU-ATC),that of the EU’s Concerto project, that of the China Scholarship Council (CSC) as well as of the European Research Council’s Advanced Grant
文摘Since more and more mobile applications are based on the proliferation of social information, the study of Mobile Social Networks （MSNs） combines social sciences and wireless communications. Operating wireless networks more efficiently by exploiting social relationships between MSN users is an appealing but challenging option for network operators. An MSN-aided content dissemination technique is presented as a potential extension of conventional cellular wireless networks in order to satisfy growing data traffic. By allowing the MSN users to create a self-organized ad hoc network for spontaneously disseminating contents, the network operator may be able to reduce the operational costs and simultaneously achieve an improved network performance. In this paper, we first summarize the basic features of the MSN architecture, followed by a survey of the factors which may affect MSN-aided content dissemination. Using a case study, we demonstrate that one can save resources of the Base Station （BS） while substantially lowering content dissemination delay. Finally, other potential applications of MSN-aided content dissemination are introduced, and a range of lustre challenges are summarized.
