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降凝剂对原油蜡相变的影响 被引量:13
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作者 宋昭峥 柯明 +1 位作者 蒋庆哲 赵密福 《石油化工高等学校学报》 EI CAS 2005年第2期40-43,共4页
探讨了降凝剂对原油中蜡相变过程的影响,得出了固态蜡为正交晶型的结论。在蜡相变过程中,胶质使蜡的固-液相变能从5 .6 3J·g-1降低到2 .94J·g-1,同时斜方晶型-正交晶型的转变能从1.5 7J·g-1升高到6 .6 1J·g-1;在蜡... 探讨了降凝剂对原油中蜡相变过程的影响,得出了固态蜡为正交晶型的结论。在蜡相变过程中,胶质使蜡的固-液相变能从5 .6 3J·g-1降低到2 .94J·g-1,同时斜方晶型-正交晶型的转变能从1.5 7J·g-1升高到6 .6 1J·g-1;在蜡相变过程中,降凝剂使蜡的固-液相变能从5 .6 3J·g-1降低到0 .4 7J·g-1,同时斜方晶型-正交晶型的转变能从1.5 7J·g-1升高到8.0 2J·g-1;因此,胶质和降凝剂增大蜡晶处于液态的趋势,达到了降低原油凝点的目的;降凝剂是否具有降凝作用,在于降凝剂分子结构与蜡的分子结构是否匹配,另外,原油的组分性质对降凝效果的影响也很大。降凝剂是否有效还与蜡的分子结构有关,如果蜡的相变过程不存在斜方晶型→正交晶型转变过渡态,降凝剂不会对这种蜡产生作用。 展开更多
关键词 降凝剂 蜡相变 正交晶型 斜方晶型
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25^(#)相变蜡-十四醇相变共晶材料的制备及性质研究 被引量:5
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作者 杨建森 张圆圆 +1 位作者 尹宁 唐少容 《功能材料》 EI CAS CSCD 北大核心 2021年第5期5111-5116,共6页
为了解决单一相变材料热工性质的不足,以25#相变蜡-十四醇相变共晶材料(PCEM)为芯材,三聚氰胺改性脲醛树脂(MUF)和三聚氰胺改性酚醛树脂(MPF)为壁材,通过原位聚合法制备了相变微胶囊,探讨了壁材种类、乳化剂用量及乳化转速对微胶囊的影... 为了解决单一相变材料热工性质的不足,以25#相变蜡-十四醇相变共晶材料(PCEM)为芯材,三聚氰胺改性脲醛树脂(MUF)和三聚氰胺改性酚醛树脂(MPF)为壁材,通过原位聚合法制备了相变微胶囊,探讨了壁材种类、乳化剂用量及乳化转速对微胶囊的影响,并采用SEM、DSC、FT-IR、TG对微胶囊的微观结构、热学性质及稳定性进行测试分析。结果表明,以MUF为壁材,所制备的微胶囊近似球形,粒径分布均匀,其相变温度和相变潜热分别为22.43℃和74.00 J/g,包覆率高达74.88%。芯材与壁材之间仅为简单的物理嵌合,且50次冷热循环后微胶囊的储热性能几乎未发生变化。当温度高于190℃,微胶囊才会出现明显的失重现象,具有良好的储热性能和热稳定性。因此,PCEM在建筑节能领域具有良好的应用前景。 展开更多
关键词 25^(#)-十四醇共晶材料 微胶囊 温度 潜热 包覆率
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单盘式浮顶油罐内含蜡原油温降规律数值计算研究 被引量:4
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作者 王敏 李敬法 +1 位作者 张欣雨 宇波 《石油科学通报》 2017年第2期267-278,共12页
建立了考虑含蜡原油非牛顿性和析蜡相变过程的单盘式浮顶油罐内含蜡原油温降物理数学模型,并发展了一体化耦合求解方法。模型中,采用幂律方程描述罐内含蜡原油的非牛顿特性;采用湍流大涡模拟方法计算罐内含蜡原油的湍流流动过程;采用焓... 建立了考虑含蜡原油非牛顿性和析蜡相变过程的单盘式浮顶油罐内含蜡原油温降物理数学模型,并发展了一体化耦合求解方法。模型中,采用幂律方程描述罐内含蜡原油的非牛顿特性;采用湍流大涡模拟方法计算罐内含蜡原油的湍流流动过程;采用焓多孔介质理论计算罐内含蜡原油的析蜡相变过程,并跟踪罐内含蜡原油的相变界面。利用文献中的结果对本文模型进行验证。基于验证的程序,对实际单盘式浮顶油罐内含蜡原油温降过程进行计算,研究罐内含蜡原油温降过程的演化规律,并对罐顶、罐底凝油层的增长以及罐顶、罐底和罐壁处传热量的变化规律进行研究。研究结果可为单盘式浮顶油罐的设计和生产方案的制定提供一定的指导。 展开更多
关键词 单盘式浮顶油罐 温降规律 非牛顿性 蜡相变 大涡模拟
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Preparation and hygrothermal performance of composite phase change material wallboard with humidity control based on expanded perlite/diatomite/paraffin 被引量:14
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作者 YANG Hua LIU Yun +2 位作者 KONG Xiang-fei CHEN Wan-he YAO Cheng-qiang 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第10期2387-2398,共12页
Phase change material(PCM)can reduce the indoor temperature fluctuation and humidity control material can adjust relative humidity used in buildings.In this study,a kind of composite phase change material particles(CP... Phase change material(PCM)can reduce the indoor temperature fluctuation and humidity control material can adjust relative humidity used in buildings.In this study,a kind of composite phase change material particles(CPCMPs)were prepared by vacuum impregnation method with expanded perlite(EP)as supporting material and paraffin as phase change material.Thus,a PCM plate was fabricated by mould pressing method with CPCMPs and then composite phase change humidity control wallboard(CPCHCW)was prepared by spraying the diatom mud on the surface of PCM plate.The composition,thermophysical properties and microstructure were characterized using X-ray diffraction instrument(XRD),differential scanning calorimeter(DSC)and scanning electron microscope(SEM).Additionally,the hygrothermal performance of CPCHCW was characterized by temperature and humidity collaborative test.The results can be summarized as follows:(1)CPCMPs have suitable phase change parameters with melting/freezing point of 18.23°C/29.42°C and higher latent heat of 54.66 J/g/55.63 J/g;(2)the diatom mud can control the humidity of confined space with a certain volume;(3)the combination of diatom mud and PCM plate in CPCHCW can effectively adjust the indoor temperature and humidity.The above conclusions indicate the potential of CPCHCW in the application of building energy efficiency. 展开更多
关键词 thermal storage humidity control phase change material PARAFFIN expanded perlite diatom mud
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Synthesis and thermal characterization of the C-S-H/paraffin composite phase change material utilizing a discontinuous two-step nucleation method
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作者 Shen Xuyan Feng Pan Zhang Qi 《Journal of Southeast University(English Edition)》 EI CAS 2024年第4期327-335,共9页
The novel calcium-silicate-hydrate(C-S-H)/paraffin composite phase change materials were synthesized using a discontinuous two-step nucleation method.Initially,the C-S-H precursor is separated and dried,followed by im... The novel calcium-silicate-hydrate(C-S-H)/paraffin composite phase change materials were synthesized using a discontinuous two-step nucleation method.Initially,the C-S-H precursor is separated and dried,followed by immersion in an aqueous environment to transform it into C-S-H.This two-step nucleation approach results in C-S-H with a specific surface area of 497.2 m^(2)/g,achieved by preventing C-S-H foil overlapping and refining its pore structure.When impregnated with paraffin,the novel C-S-H/paraffin composite exhibits superior thermal properties,such as a higher potential heat value of 148.3 J/g and an encapsulation efficiency of 81.6%,outperforming conventional C-S-H.Moreover,the composite material demonstrates excellent cyclic performance,indicating its potential for building thermal storage compared to other paraffin-based composites.Compared with the conventional method,this simple technology,which only adds conversion and centrifugation steps,does not negatively impact preparation costs,the environment,and resource consumption.This study provides valuable theoretical insights for designing thermal storage concrete materials and advancing building heat management. 展开更多
关键词 two-step nucleation C-S-H paraffin phase change materials composite building thermal management
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Numerical study on solid–liquid phase change in paraffin as phase change material for battery thermal management 被引量:3
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作者 Qiannan Zhang Yutao Huo Zhonghao Rao 《Science Bulletin》 SCIE EI CAS CSCD 2016年第5期391-400,共10页
With the large latent heat and low cost, the paraffin has been widely used in battery thermal management(BTM) system to improve the efficiency and cycling life of power battery. The numerical model of paraffin melting... With the large latent heat and low cost, the paraffin has been widely used in battery thermal management(BTM) system to improve the efficiency and cycling life of power battery. The numerical model of paraffin melting in a cavity has been established, and the effects on the solid–liquid phase change process have been investigated for the purpose of enhancing the heat transfer performance of paraffin-based BTM system. The results showed that the location of the heating wall had great effects on the melting process. The paraffin in the cavity melted most quickly when the heating wall located at the bottom. Furthermore, the effects of thermal conductivity and the velocity of the slip wall have been considered. The gradient of liquid fraction increased with the increase in thermal conductivity, and the melting process could be accelerated or delayed by the slip wall with different velocity. 展开更多
关键词 Phase change material Battery thermal management Solid–liquid phase change Heat flux Thermal conductivity
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