The adsorption behavior of thiophene and benzene on NiY zeolite has been investigated by the frequency response(FR) method.The FR spectra of thiophene and benzene on NiY zeolite were recorded at 302-335 K in a pressur...The adsorption behavior of thiophene and benzene on NiY zeolite has been investigated by the frequency response(FR) method.The FR spectra of thiophene and benzene on NiY zeolite were recorded at 302-335 K in a pressure range of 26.6-266 Pa.The results showed that adsorption was found to be the rate-controlling process for the thiophene/NiY zeolite system,and there were two different adsorption processes.Two kinds of adsorption models have been proposed,namely:the S-M interaction(low frequency adsorption) and the π-complexation(high frequency adsorption).High frequency adsorption obeyed the Langmuir model.By combining the FR method and Langmuir model,the adsorption site of high frequency adsorption process at 302 K and 335 K was 3.172 mmol/g and 2.974 mmol/g,respectively,and on the combined adsorption isotherms,the adsorption site of the low frequency adsorption process at 302 K and 335 K was 0.308 mmol/gand 0.436 mmol/g,respectively.The low frequency adsorption process(S-M interaction) was the main adsorption process.The diffusion process was the rate-controlling process for the benzene-NiY zeolite system.展开更多
基金the National Natural Science Foundation of China(NSFC.Contract No.20546003 and No.20776064)
文摘The adsorption behavior of thiophene and benzene on NiY zeolite has been investigated by the frequency response(FR) method.The FR spectra of thiophene and benzene on NiY zeolite were recorded at 302-335 K in a pressure range of 26.6-266 Pa.The results showed that adsorption was found to be the rate-controlling process for the thiophene/NiY zeolite system,and there were two different adsorption processes.Two kinds of adsorption models have been proposed,namely:the S-M interaction(low frequency adsorption) and the π-complexation(high frequency adsorption).High frequency adsorption obeyed the Langmuir model.By combining the FR method and Langmuir model,the adsorption site of high frequency adsorption process at 302 K and 335 K was 3.172 mmol/g and 2.974 mmol/g,respectively,and on the combined adsorption isotherms,the adsorption site of the low frequency adsorption process at 302 K and 335 K was 0.308 mmol/gand 0.436 mmol/g,respectively.The low frequency adsorption process(S-M interaction) was the main adsorption process.The diffusion process was the rate-controlling process for the benzene-NiY zeolite system.
