The non-random two liquids (NRTL) equation together with the Pitzer/Curl Virial equation of state are used to investigate the simultaneous representation of excess enthalpies (h^E) and vapour-liquid equilibria (...The non-random two liquids (NRTL) equation together with the Pitzer/Curl Virial equation of state are used to investigate the simultaneous representation of excess enthalpies (h^E) and vapour-liquid equilibria (VLE) and the VLE prediction from h^E data. The calculation strategy for properly determining NRTL parameters and the effect of their temperature dependence on the simultaneous correlation of h^E and VLE data and the VLE extrapolation are analysed in detail.展开更多
Mg ion-exchanged samples were prepared with acid-washed Shengli lignite.The chemical composition of the ash of the raw sample was determined by X-ray fluorescence.The equilibrium adsorption water contents of samples w...Mg ion-exchanged samples were prepared with acid-washed Shengli lignite.The chemical composition of the ash of the raw sample was determined by X-ray fluorescence.The equilibrium adsorption water contents of samples were determined in a range of relative humidity.The ion-exchange process was characterized by FT-IR,ash content,and p H value.A possible mechanism is proposed for equilibrium adsorption water of ion-exchanged samples at different humidities.The extent of ion-exchange reaction between Mg2+and lignite is controlled by the concentration of Mg2+in Mg SO4solution.The effect of Mg2+on equilibrium adsorption water content varies with relative humidity and content of Mg2+.The factor that controls equilibrium adsorption water content at low relative humidity is water interactions with sorption sites,which are Mg2+–carboxyl group complex.At middle relative humidity capillary force between Mg2+–water clusters Mg+(H2O)nand capillary is more important.At high relative humidity,free water–free water interactions are more significant.展开更多
Based on an attribution analysis of the global mean temperature biases in the Flexible Global Ocean- AtmOsphere-Land System model, spectral version 2 (FGOALS-s2) through a coupled atmosphere-surface ch- mate feedb...Based on an attribution analysis of the global mean temperature biases in the Flexible Global Ocean- AtmOsphere-Land System model, spectral version 2 (FGOALS-s2) through a coupled atmosphere-surface ch- mate feedback-response analysis method (CFRAM), the model's global surface-atmosphere energy balance in boreal winter and summer is examined. Within the en- ergy-balance-based CFRAM system, the model temperature biases are attributed to energy perturbations resulting from model biases in individual radiative and non-radia- tive processes in the atmosphere and at the surface. The results show that, although the global mean surface tem- perature (Ts) bias is only 0.38 K in January and 1.70 K in July, and the atmospheric temperature (Ta) biases from the troposphere to the stratosphere are only around +3 K at most, the temperature biases due to model biases in rep- resenting the individual radiative and non-radiative proc- esses are considerably large (over -4-10 K at most). Spe- cifically, the global cold radiative Ts bias, mainly due to the overestimated surface albedo, is compensated for by the global warm non-radiative Ts bias that is mainly due to the overestimated downward surface heat fluxes. The model biases in non-radiative processes in the lower tro- posphere (up to 5-15 K) are relatively much larger than in upper levels, which are mainly responsible for the warm Ta biases there. In contrast, the global mean cold ira biases in the mid-to-upper troposphere are mainly dominated by radiative processes. The warm/cold Ta biases in the lower/upper stratosphere are dominated by non-radiative processes, while the warm ira biases in the mid-strato- sphere can be attributed to the radiative ozone feedback process.展开更多
The thermal conditions like the temperature distribution and the heat fluxes during metal cutting have a major influence on the machinability, the tool lifetime, the metallurgical structure and thus the functionality ...The thermal conditions like the temperature distribution and the heat fluxes during metal cutting have a major influence on the machinability, the tool lifetime, the metallurgical structure and thus the functionality of the work piece. This in particular applies for manufacturing processes like milling, drilling and turning for high-value turbomachinery components like impellers, combustion engines and compressors of the aerospace and automotive industry as well as energy generation, which play a major role in modern societies. However, numerous analytical and experimental efforts have been conducted in order to understand the thermal conditions in metal cutting, yet many questions still prevail. Most models are based on a stationary point of view and do not include time dependent effects like in intensity and distribution varying heat sources, varying engagement conditions and progressive tool wear. In order to cover such transient physics an analytical approach based on Green's functions for the solution of the partial differential equations of unsteady heat conduction in solids is used to model entire transient temperature fields. The validation of the model is carried out in orthogonal cutting experiments not only punctually but also for entire temperature fields. For these experiments an integrated measurement of prevailing cutting force and temperature fields in the tool and the chip by means of high-speed thermography were applied. The thermal images were analyzed with regard to thermodynamic energy balancing in order to derive the heat partition between tool, chips and workpiece. The thus calculated heat flow into the tool was subsequently used in order to analytically model the transient volumetric temperature fields in the tool. The described methodology enables the modeling of the transient thermal state in the cutting zone and particular in the tool, which is directly linked to phenomena like tool wear and workpiece surface modifications.展开更多
基金Supported by Deutsche Forschungsgemeinschaft(DFG) (LE 886/4-1)
文摘The non-random two liquids (NRTL) equation together with the Pitzer/Curl Virial equation of state are used to investigate the simultaneous representation of excess enthalpies (h^E) and vapour-liquid equilibria (VLE) and the VLE prediction from h^E data. The calculation strategy for properly determining NRTL parameters and the effect of their temperature dependence on the simultaneous correlation of h^E and VLE data and the VLE extrapolation are analysed in detail.
基金Supported by the National Basic Research Program of China(2012CB214900)the National Natural Science Foundation of China(51274197)+1 种基金the 111 Project(B12030)the Fundamental Research Funds for the Central Universities(2014XT05)
文摘Mg ion-exchanged samples were prepared with acid-washed Shengli lignite.The chemical composition of the ash of the raw sample was determined by X-ray fluorescence.The equilibrium adsorption water contents of samples were determined in a range of relative humidity.The ion-exchange process was characterized by FT-IR,ash content,and p H value.A possible mechanism is proposed for equilibrium adsorption water of ion-exchanged samples at different humidities.The extent of ion-exchange reaction between Mg2+and lignite is controlled by the concentration of Mg2+in Mg SO4solution.The effect of Mg2+on equilibrium adsorption water content varies with relative humidity and content of Mg2+.The factor that controls equilibrium adsorption water content at low relative humidity is water interactions with sorption sites,which are Mg2+–carboxyl group complex.At middle relative humidity capillary force between Mg2+–water clusters Mg+(H2O)nand capillary is more important.At high relative humidity,free water–free water interactions are more significant.
基金jointly supported by the Special Fund for Public Welfare Industry(Meteorology)(Grant No.GYHY201406001)Science Foundation of the Chinese Academy of Sciences(Grant No.XDA11010402)the National Natural Science Foundation of China(Grant No.91437105)
文摘Based on an attribution analysis of the global mean temperature biases in the Flexible Global Ocean- AtmOsphere-Land System model, spectral version 2 (FGOALS-s2) through a coupled atmosphere-surface ch- mate feedback-response analysis method (CFRAM), the model's global surface-atmosphere energy balance in boreal winter and summer is examined. Within the en- ergy-balance-based CFRAM system, the model temperature biases are attributed to energy perturbations resulting from model biases in individual radiative and non-radia- tive processes in the atmosphere and at the surface. The results show that, although the global mean surface tem- perature (Ts) bias is only 0.38 K in January and 1.70 K in July, and the atmospheric temperature (Ta) biases from the troposphere to the stratosphere are only around +3 K at most, the temperature biases due to model biases in rep- resenting the individual radiative and non-radiative proc- esses are considerably large (over -4-10 K at most). Spe- cifically, the global cold radiative Ts bias, mainly due to the overestimated surface albedo, is compensated for by the global warm non-radiative Ts bias that is mainly due to the overestimated downward surface heat fluxes. The model biases in non-radiative processes in the lower tro- posphere (up to 5-15 K) are relatively much larger than in upper levels, which are mainly responsible for the warm Ta biases there. In contrast, the global mean cold ira biases in the mid-to-upper troposphere are mainly dominated by radiative processes. The warm/cold Ta biases in the lower/upper stratosphere are dominated by non-radiative processes, while the warm ira biases in the mid-strato- sphere can be attributed to the radiative ozone feedback process.
文摘The thermal conditions like the temperature distribution and the heat fluxes during metal cutting have a major influence on the machinability, the tool lifetime, the metallurgical structure and thus the functionality of the work piece. This in particular applies for manufacturing processes like milling, drilling and turning for high-value turbomachinery components like impellers, combustion engines and compressors of the aerospace and automotive industry as well as energy generation, which play a major role in modern societies. However, numerous analytical and experimental efforts have been conducted in order to understand the thermal conditions in metal cutting, yet many questions still prevail. Most models are based on a stationary point of view and do not include time dependent effects like in intensity and distribution varying heat sources, varying engagement conditions and progressive tool wear. In order to cover such transient physics an analytical approach based on Green's functions for the solution of the partial differential equations of unsteady heat conduction in solids is used to model entire transient temperature fields. The validation of the model is carried out in orthogonal cutting experiments not only punctually but also for entire temperature fields. For these experiments an integrated measurement of prevailing cutting force and temperature fields in the tool and the chip by means of high-speed thermography were applied. The thermal images were analyzed with regard to thermodynamic energy balancing in order to derive the heat partition between tool, chips and workpiece. The thus calculated heat flow into the tool was subsequently used in order to analytically model the transient volumetric temperature fields in the tool. The described methodology enables the modeling of the transient thermal state in the cutting zone and particular in the tool, which is directly linked to phenomena like tool wear and workpiece surface modifications.