An interfacial equation of state based on perturbation theory for surfactant-oil-water system has been developed. By combining the interfacial equation of state with Boudh-Hir and Mansoori's model, a molecular the...An interfacial equation of state based on perturbation theory for surfactant-oil-water system has been developed. By combining the interfacial equation of state with Boudh-Hir and Mansoori's model, a molecular ther-modynamic model has been proposed. The interfacial tension of surfactant-oil-water systems can be calculated from the surface tensions of pure oil and water by this model. The interfacial tension data for sodium dodecyl sulphate-heptane-water system, polyoxyethylene n-octylphenol-heptane-water system and hexadecyl trimethyl ammonium bromide-heptane-water system have been correlated. By using the adjustable parameters obtained, the interfacial tensions of these systems at other temperatures have been predicted. Both the correlated and the predicted values are satisfactory.展开更多
The main objective of this work was to develop a kinetic model to describe the variation of the surface tension in an air-water interface due to the adsorption of proteins from different origins and to identify quanti...The main objective of this work was to develop a kinetic model to describe the variation of the surface tension in an air-water interface due to the adsorption of proteins from different origins and to identify quantitatively the relevant parameters, it was considered that the processes of adsorption, unfolding and reordering of the protein molecule in the interface occur simultaneously. The model used in the present work to calculate the surface tension postulates the existence of two simultaneous processes, adsorption and protein rearrangement represented with an equation of first order with two exponential components. The relevant parameter of the equation are ka and kr-the rate constants of the two first order kinetic phases that correspond to both conformational states of the protein, adsorption and rearrangement during the process of variation of the surface tension, and the amplitude parameters Aa and Ar. The results suggest that the kinetic model for the variation of the surface tension of protein solutions proposed in this work, with two simultaneous first order processes, is more appropriate than previous models to describe such variation.展开更多
A molecular dynamics simulation model is established based on the well-known Lennard-Jones 12-6 potential function to determine the surface tension of a Lennard-Jones liquid-vapor interface. The simulation is carried ...A molecular dynamics simulation model is established based on the well-known Lennard-Jones 12-6 potential function to determine the surface tension of a Lennard-Jones liquid-vapor interface. The simulation is carried out with argon as the working fluid of a given molecular number at different temperature and different truncated radius. It is found that the surface tension of a Lennard-Jones fluid is likely to be bigger for a bigger truncated radius, and tends to be constant after the truncated radius increased to a certain value. It is also found that the surface tension becomes smaller as the temperature increases.展开更多
The production and properties of the biosurfactant synthesized by Bacillus subtilis CCTCC AB93108 were studied. The maximum concentration of the surfactant is 1.64 g/L when the bacteria grow in a medium supplemented w...The production and properties of the biosurfactant synthesized by Bacillus subtilis CCTCC AB93108 were studied. The maximum concentration of the surfactant is 1.64 g/L when the bacteria grow in a medium supplemented with glucose as carbon sources. The isolated biosurfactant is a complex of protein and polysaccharide without lipids. It reduces the surface tension of distilled water to 45.9 mN/m, and its critical micelle concentration (CMC) is 2.96 g/L. It can stabilize emulsions of several aromatic and aliphatic hydrocarbons, such as benzene, xylene, n-pentane, n-nonane, gasoline and diesel oil. It presents high emulsification activity and stability in a wide range of temperature (4-100 ℃) and a long period of duration.展开更多
A new model based on the theoretical work of Boudh-Hir and Mansoori was developed for prediction of surface tension of pure fluids. The new model has the advantage of not requiring densities in the calculation, and th...A new model based on the theoretical work of Boudh-Hir and Mansoori was developed for prediction of surface tension of pure fluids. The new model has the advantage of not requiring densities in the calculation, and the input parameters are critical temperature and connectivity indices. A total of 209 compounds covering a wide variety of substances were used to develop the model, and the overall correlative AAD is 4.21%. To test its predictive ability, the model is further used to predict the surface tension of 25 more compounds that were not included in the model development. The overall predictive AAD is 4.07%, which illustrates that the model is reliable. The model proposed is simple and easy to apply, with good predictive accuracy.展开更多
2-Hexyl-1-decanol was used as the main material to prepare a block-polyether sulfonate extended surfactant(IC_(16)P_(6)E_(6)S).The solubility and surface active properties of IC_(16)P_(6)E_(6)S were evaluated,and then...2-Hexyl-1-decanol was used as the main material to prepare a block-polyether sulfonate extended surfactant(IC_(16)P_(6)E_(6)S).The solubility and surface active properties of IC_(16)P_(6)E_(6)S were evaluated,and then the IC_(16)P_(6)E_(6)S was mixed with a cationic surfactant hexadecyl trimethyl ammonium bromide(CTAB)and a zwitterionic betaine surfactant(HAB),respectively.The effects of mixing ratios of IC_(16)P_(6)E_(6)S∶HAB and IC_(16)P_(6)E_(6)S∶CTAB on the hydrodynamic diameter and interfacial properties were discussed.The emulsification,adsorption and laboratory core displacement experiments of the binary system were tested.The results showed that the critical micelle concentration(cmc)of IC_(16)P_(6)E_(6)S in distilled water was 0.1 mmol/L and the surface tension at cmc(γcmc)was 28.53 mN/m.IC_(16)P_(6)E_(6)S showed strong synergistic effects with HAB and CTAB,and the mixed systems could effectively reduce the interfacial tension compared with single surfactants.The mixed systems with n(IC_(16)P_(6)E_(6)S)∶n(HAB)of 1∶1 and n(IC_(16)P_(6)E_(6)S)∶n(CTAB)of 1∶3 could maintain ultra-low interfacial tension(in the order of magnitude of 10^(-3)mN/m)in the salinity range of 1%-7%NaCl and low interfacial tension(in the order of magnitude of 10^(-2)mN/m)in the salinity range of 3%-7%NaCl,respectively.With the increase of salinity,the emulsion formed by the mixed surfactant system underwent the phase transition process from WinsorⅠto WinsorⅢand then to WinsorⅡ.The emulsion of mixed IC_(16)P_(6)E_(6)S/HAB system had more middle-phase emulsion volume than that of the mixed IC_(16)P_(6)E_(6)S/CTAB system,and the former emulsion system was more stable.The mixed IC_(16)P_(6)E_(6)S/HAB system also had good solubilization effect,and the amount of oil solubilization was up to 43 mL/g.Meanwhile,it had good adsorption resistance.Compared with water flooding,the depressurization rate could reach 25.00%and the recovery could be enhanced by 11.75%,indicating that the IC_(16)P_(6)E_(6)S/HAB system was more conducive to the depressurization and injection enhancement for low-permeability reservoirs.展开更多
An equation of state (EOS) applicable for the interfacial properties of CO2-methanol and CO2-ethanol mixtures was established by combining the cross-association EOS and the density gradient theory (DGT). The correlate...An equation of state (EOS) applicable for the interfacial properties of CO2-methanol and CO2-ethanol mixtures was established by combining the cross-association EOS and the density gradient theory (DGT). The correlated surface tensions of CO2-ethanol mixtures agreed well with the experimental data. The results illustrated the temperature and pressure dependence of the cross-association between CO2 and alcohol hydroxyls in the whole vapor-liquid surface,and the influence of the cross-association on the calculation of the surface tensions of binary mixtures.展开更多
Gas diffusion layer(GDL) plays a great important role in proton exchange membrane fuel cell(PEMFC).Water transport mechanism in GDL is still not clear.In the present study,an ex-situ transparent setup is built to visu...Gas diffusion layer(GDL) plays a great important role in proton exchange membrane fuel cell(PEMFC).Water transport mechanism in GDL is still not clear.In the present study,an ex-situ transparent setup is built to visualize the transport phenomena and to measure the threshold pressure of water in GDL at different temperatures.It is found that the relationship between the breakthrough pressure and the temperature is nearly linear(i.e.the pressure decreases linearly with the increase of temperature).To avoid the problems faced by the continuum models,the pore network model is developed to simulate the liquid water transport through the carbon paper.A uniform pressure boundary condition is used in simulation and the results are similar to the ones obtained in the experiment.The reason is that the contact angle and surface tension coefficient of water in GDLs change accordingly with the change of temperature.展开更多
We derive the Misner-Sharp-like masses Dilaton-Axion black hole by using the modified first of the Reissner-Nordstr6m black hole and the Einstein-Maxwell- law of thermodynamics. Their surface tensions are investigated...We derive the Misner-Sharp-like masses Dilaton-Axion black hole by using the modified first of the Reissner-Nordstr6m black hole and the Einstein-Maxwell- law of thermodynamics. Their surface tensions are investigated. For the Reissner-NordstrSm black hole, the outer horizon radius is treated as a variable and the effective temperature is introduced. For the Einstein-Maxwe11-Dilaton-Axion black hole, the outer horizon radius, the angular momentum unit mass and the parameter b are seen as three independent variables, and the mass, the horizon area and the angular momentum are functions of them.展开更多
基金Supported by the National Nature Science Foundation of China(No.29736170)
文摘An interfacial equation of state based on perturbation theory for surfactant-oil-water system has been developed. By combining the interfacial equation of state with Boudh-Hir and Mansoori's model, a molecular ther-modynamic model has been proposed. The interfacial tension of surfactant-oil-water systems can be calculated from the surface tensions of pure oil and water by this model. The interfacial tension data for sodium dodecyl sulphate-heptane-water system, polyoxyethylene n-octylphenol-heptane-water system and hexadecyl trimethyl ammonium bromide-heptane-water system have been correlated. By using the adjustable parameters obtained, the interfacial tensions of these systems at other temperatures have been predicted. Both the correlated and the predicted values are satisfactory.
文摘The main objective of this work was to develop a kinetic model to describe the variation of the surface tension in an air-water interface due to the adsorption of proteins from different origins and to identify quantitatively the relevant parameters, it was considered that the processes of adsorption, unfolding and reordering of the protein molecule in the interface occur simultaneously. The model used in the present work to calculate the surface tension postulates the existence of two simultaneous processes, adsorption and protein rearrangement represented with an equation of first order with two exponential components. The relevant parameter of the equation are ka and kr-the rate constants of the two first order kinetic phases that correspond to both conformational states of the protein, adsorption and rearrangement during the process of variation of the surface tension, and the amplitude parameters Aa and Ar. The results suggest that the kinetic model for the variation of the surface tension of protein solutions proposed in this work, with two simultaneous first order processes, is more appropriate than previous models to describe such variation.
基金Funded by the National Natural Science Foundation of China (No.50076048)
文摘A molecular dynamics simulation model is established based on the well-known Lennard-Jones 12-6 potential function to determine the surface tension of a Lennard-Jones liquid-vapor interface. The simulation is carried out with argon as the working fluid of a given molecular number at different temperature and different truncated radius. It is found that the surface tension of a Lennard-Jones fluid is likely to be bigger for a bigger truncated radius, and tends to be constant after the truncated radius increased to a certain value. It is also found that the surface tension becomes smaller as the temperature increases.
基金Project(IRT0719) supported by the Program for Changjiang Scholars and Innovative Research Team in University of China Project (2004AA649370) supported by the National High-Tech Research and Development Program of China+1 种基金 Projects(50425927, 50225926) supported by the Natural Foundation for Distinguished Young Scholars Project(2007F3102) supported by Technology Foundation for Creative Young Scholars of Fujian Province, China
文摘The production and properties of the biosurfactant synthesized by Bacillus subtilis CCTCC AB93108 were studied. The maximum concentration of the surfactant is 1.64 g/L when the bacteria grow in a medium supplemented with glucose as carbon sources. The isolated biosurfactant is a complex of protein and polysaccharide without lipids. It reduces the surface tension of distilled water to 45.9 mN/m, and its critical micelle concentration (CMC) is 2.96 g/L. It can stabilize emulsions of several aromatic and aliphatic hydrocarbons, such as benzene, xylene, n-pentane, n-nonane, gasoline and diesel oil. It presents high emulsification activity and stability in a wide range of temperature (4-100 ℃) and a long period of duration.
基金Supported by the National Natural Science Foundation of China (No. 20106001) the Teaching and Research Award Program for Outstanding Young Teachers in Higher Education Institutions of China, the Trans-century Training Programme Foundation for the Talen
文摘A new model based on the theoretical work of Boudh-Hir and Mansoori was developed for prediction of surface tension of pure fluids. The new model has the advantage of not requiring densities in the calculation, and the input parameters are critical temperature and connectivity indices. A total of 209 compounds covering a wide variety of substances were used to develop the model, and the overall correlative AAD is 4.21%. To test its predictive ability, the model is further used to predict the surface tension of 25 more compounds that were not included in the model development. The overall predictive AAD is 4.07%, which illustrates that the model is reliable. The model proposed is simple and easy to apply, with good predictive accuracy.
文摘2-Hexyl-1-decanol was used as the main material to prepare a block-polyether sulfonate extended surfactant(IC_(16)P_(6)E_(6)S).The solubility and surface active properties of IC_(16)P_(6)E_(6)S were evaluated,and then the IC_(16)P_(6)E_(6)S was mixed with a cationic surfactant hexadecyl trimethyl ammonium bromide(CTAB)and a zwitterionic betaine surfactant(HAB),respectively.The effects of mixing ratios of IC_(16)P_(6)E_(6)S∶HAB and IC_(16)P_(6)E_(6)S∶CTAB on the hydrodynamic diameter and interfacial properties were discussed.The emulsification,adsorption and laboratory core displacement experiments of the binary system were tested.The results showed that the critical micelle concentration(cmc)of IC_(16)P_(6)E_(6)S in distilled water was 0.1 mmol/L and the surface tension at cmc(γcmc)was 28.53 mN/m.IC_(16)P_(6)E_(6)S showed strong synergistic effects with HAB and CTAB,and the mixed systems could effectively reduce the interfacial tension compared with single surfactants.The mixed systems with n(IC_(16)P_(6)E_(6)S)∶n(HAB)of 1∶1 and n(IC_(16)P_(6)E_(6)S)∶n(CTAB)of 1∶3 could maintain ultra-low interfacial tension(in the order of magnitude of 10^(-3)mN/m)in the salinity range of 1%-7%NaCl and low interfacial tension(in the order of magnitude of 10^(-2)mN/m)in the salinity range of 3%-7%NaCl,respectively.With the increase of salinity,the emulsion formed by the mixed surfactant system underwent the phase transition process from WinsorⅠto WinsorⅢand then to WinsorⅡ.The emulsion of mixed IC_(16)P_(6)E_(6)S/HAB system had more middle-phase emulsion volume than that of the mixed IC_(16)P_(6)E_(6)S/CTAB system,and the former emulsion system was more stable.The mixed IC_(16)P_(6)E_(6)S/HAB system also had good solubilization effect,and the amount of oil solubilization was up to 43 mL/g.Meanwhile,it had good adsorption resistance.Compared with water flooding,the depressurization rate could reach 25.00%and the recovery could be enhanced by 11.75%,indicating that the IC_(16)P_(6)E_(6)S/HAB system was more conducive to the depressurization and injection enhancement for low-permeability reservoirs.
基金supported by the National Natural Science Foundation of China (21076070)the Fundamental Research Funds for the Central Universities (09MG13)
文摘An equation of state (EOS) applicable for the interfacial properties of CO2-methanol and CO2-ethanol mixtures was established by combining the cross-association EOS and the density gradient theory (DGT). The correlated surface tensions of CO2-ethanol mixtures agreed well with the experimental data. The results illustrated the temperature and pressure dependence of the cross-association between CO2 and alcohol hydroxyls in the whole vapor-liquid surface,and the influence of the cross-association on the calculation of the surface tensions of binary mixtures.
基金supported by the National Natural Science Foundation of China (No.50976011)Fundamental Research Funds for the Central Universities of China (No. 2009JBM090)
文摘Gas diffusion layer(GDL) plays a great important role in proton exchange membrane fuel cell(PEMFC).Water transport mechanism in GDL is still not clear.In the present study,an ex-situ transparent setup is built to visualize the transport phenomena and to measure the threshold pressure of water in GDL at different temperatures.It is found that the relationship between the breakthrough pressure and the temperature is nearly linear(i.e.the pressure decreases linearly with the increase of temperature).To avoid the problems faced by the continuum models,the pore network model is developed to simulate the liquid water transport through the carbon paper.A uniform pressure boundary condition is used in simulation and the results are similar to the ones obtained in the experiment.The reason is that the contact angle and surface tension coefficient of water in GDLs change accordingly with the change of temperature.
基金Supported by the National Natural Science Foundation of China under Grant No.11405016Basic Research Project of Science and Technology Committee of Chongqing under Grant No.cstc2016jcyja0364
文摘We derive the Misner-Sharp-like masses Dilaton-Axion black hole by using the modified first of the Reissner-Nordstr6m black hole and the Einstein-Maxwell- law of thermodynamics. Their surface tensions are investigated. For the Reissner-NordstrSm black hole, the outer horizon radius is treated as a variable and the effective temperature is introduced. For the Einstein-Maxwe11-Dilaton-Axion black hole, the outer horizon radius, the angular momentum unit mass and the parameter b are seen as three independent variables, and the mass, the horizon area and the angular momentum are functions of them.
