Al2O3 ceramic powder was applied to modify the large pores defects on the surface of the porous metal Ti support,in situ oxidation method was a convenient method to prepare defect free ceramic/Ti composite membranes o...Al2O3 ceramic powder was applied to modify the large pores defects on the surface of the porous metal Ti support,in situ oxidation method was a convenient method to prepare defect free ceramic/Ti composite membranes on this basis.In situ oxidation conditions experimental results show that the best condition for preparing the TiO2-Al2O3/Ti composite membrane is under 800°C for 2 h,and the microstructure and pore sizes of the TiO2-Al2O3/Ti composite membranes are affected obviously.The thickness and composition of the TiO2/Ti composite membranes are determined by SEM and XRD completely.The pore size distribution of the composite membrane is measured by bubble pressure method,the most probable aperture is about 3.12μm,while the average pore size of defect free TiO2-Al2O3/Ti is about 3.23μm.After ultrasonic treatment,the slight weight change of membranes reveals no observable change,which indicates that TiO2-Al2O3/Ti composite membranes maintain a good stability.展开更多
Fertile topsoil was added onto the surface of barren slope land in Three Gorges Reservoir region of China in an anthropogenic process known as the foreign soil reconstruction project. The main goal of this paper was t...Fertile topsoil was added onto the surface of barren slope land in Three Gorges Reservoir region of China in an anthropogenic process known as the foreign soil reconstruction project. The main goal of this paper was to reveal the influence of anthropogenic activities on pedogenic processes and soil classifications. Chemical weathering indices and comparative analysis were applied to discuss changes in geochemical compositions and weathering features of purplish soils(Cambisols) before and after the project. Results showed that:(1) The foreign soil reconstruction project slightly altered the major element composition of topsoil and improved the soil structure. Although the distributions of major elements in the original topsoil, original subsoil, foreign topsoil and newly constructed topsoil were all similar to that in upper continental crust, newly constructed topsoil was the most similar soil.(2) The chemical index of alteration was more sensitive than the weathering index of Parker at indicating chemical weathering status of purplish soil. The chemical weathering status of newly constructed topsoil was higher than that of the original topsoil and lower than that of foreign topsoil.(3) Anthropogenic activities may provide a promising new thought for the anthropogenic soil classification system. The scope and subgroups of Anthrosols should be extended and strengthened. Or there may be a need to combine Anthrosols and Technosols orders to create a new soil order. The results may be used for optimizing soil mellowing engineering activities and enriching the soil classification system.展开更多
基金Projects(212006065,21666018)supported by the National Natural Science Foundation of China
文摘Al2O3 ceramic powder was applied to modify the large pores defects on the surface of the porous metal Ti support,in situ oxidation method was a convenient method to prepare defect free ceramic/Ti composite membranes on this basis.In situ oxidation conditions experimental results show that the best condition for preparing the TiO2-Al2O3/Ti composite membrane is under 800°C for 2 h,and the microstructure and pore sizes of the TiO2-Al2O3/Ti composite membranes are affected obviously.The thickness and composition of the TiO2/Ti composite membranes are determined by SEM and XRD completely.The pore size distribution of the composite membrane is measured by bubble pressure method,the most probable aperture is about 3.12μm,while the average pore size of defect free TiO2-Al2O3/Ti is about 3.23μm.After ultrasonic treatment,the slight weight change of membranes reveals no observable change,which indicates that TiO2-Al2O3/Ti composite membranes maintain a good stability.
基金the National Key Technology Research and Development Program of the Ministry of Science and Technology of China (Grant No. 2012BAD05B06)
文摘Fertile topsoil was added onto the surface of barren slope land in Three Gorges Reservoir region of China in an anthropogenic process known as the foreign soil reconstruction project. The main goal of this paper was to reveal the influence of anthropogenic activities on pedogenic processes and soil classifications. Chemical weathering indices and comparative analysis were applied to discuss changes in geochemical compositions and weathering features of purplish soils(Cambisols) before and after the project. Results showed that:(1) The foreign soil reconstruction project slightly altered the major element composition of topsoil and improved the soil structure. Although the distributions of major elements in the original topsoil, original subsoil, foreign topsoil and newly constructed topsoil were all similar to that in upper continental crust, newly constructed topsoil was the most similar soil.(2) The chemical index of alteration was more sensitive than the weathering index of Parker at indicating chemical weathering status of purplish soil. The chemical weathering status of newly constructed topsoil was higher than that of the original topsoil and lower than that of foreign topsoil.(3) Anthropogenic activities may provide a promising new thought for the anthropogenic soil classification system. The scope and subgroups of Anthrosols should be extended and strengthened. Or there may be a need to combine Anthrosols and Technosols orders to create a new soil order. The results may be used for optimizing soil mellowing engineering activities and enriching the soil classification system.
