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电化学原位红外光谱的方法和研究进展 被引量:2
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作者 姜艳霞 李广 +3 位作者 叶进裕 李君涛 周志有 孙世刚 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2021年第2期191-207,共17页
研究电化学体系多相界面的精细结构和电化学过程对于发展电化学基础理论、认识电催化反应机理和界面过程,以及指导高效电催化剂的可控构筑具有重要意义.传统电化学方法不具备分子识别能力,局限于对复杂电化学体系的宏观和唯像研究.电化... 研究电化学体系多相界面的精细结构和电化学过程对于发展电化学基础理论、认识电催化反应机理和界面过程,以及指导高效电催化剂的可控构筑具有重要意义.传统电化学方法不具备分子识别能力,局限于对复杂电化学体系的宏观和唯像研究.电化学原位红外光谱将电化学调制和红外光谱方法相结合,利用红外光谱的指纹特征和表面选律实现对电化学反应过程中反应物种的成键方式和浓度变化的特异性识别,获取电极表界面的物理结构和化学变化特征,以及对参与电化学反应的各种物质的实时、定性和定量检测,为研究电化学反应过程和机理,建立电极材料的结构与性能的构效关系,提供分子水平的信息.本文以本课题组的工作为主,从理论和实验两个方面综述外反射电化学原位红外光谱的基础与研究进展.首先介绍电化学原位红外光谱的原理、方法及其新技术,重点综述电化学原位红外光谱在燃料电池、锂离子电池等能量转化与储存领域中的研究进展,最后展望电化学原位红外光谱方法的应用和发展方向. 展开更多
关键词 电化学原位红外光谱 方法 应用 表界面过程 电催化剂 反应机理
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Characterization of carbon fibers recovered through mechanochemical-enhanced recycling of waste carbon fiber reinforced plastics 被引量:2
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作者 NZIOKA Antony Mutua ALUNDA Bernard Ouma +4 位作者 YAN Cao-zheng SIM Ye-Jin KIM Myung-Gyun YOON Bok-Young KIM Young-Ju 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第10期2688-2703,共16页
In this study,we present the characterization of the carbon fibers recovered from the mechanochemical-enhanced recycling of carbon fiber reinforced fibers.The objectives of the study were to investigate the effect of ... In this study,we present the characterization of the carbon fibers recovered from the mechanochemical-enhanced recycling of carbon fiber reinforced fibers.The objectives of the study were to investigate the effect of our modified recycling method on the interfacial properties of recovered fibers.The reinforced plastics were recycled;the recycling efficiency was determined and the recovered fibers were sized using 1 wt%and 3 wt%concentration of(3-aminopropyl)triethoxysilane.We characterized the morphologies utilizing the electron spectroscopy for chemical analysis(ESCA),atomic force microscopy(AFM),FTIR-attenuated total reflection(ATR)spectroscopy and scanning electron microscopy(SEM).Although the surface of the fibers had no cracks,there was evidence of contaminations which affected the interfacial properties and the quality of the fibers.Results showed that the trends in the recovered and virgin fibers were similar with an increase in sizing concentration.The results highlighted the perspectives of increasing the quality of recovered fibers after the recycling process. 展开更多
关键词 recycled carbon fibers fiber reinforced plastics mechanochemical process interfacial property surface morphology
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Large excavations and their effect on displacement of land boundaries 被引量:1
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作者 Jan Nemcik Naj Aziz 《International Journal of Mining Science and Technology》 SCIE EI 2012年第5期633-637,共5页
A study to estimate land surface movement caused by large surface excavations in sedimentary strata is presented.In stratified or jointed strata the stress relief driven movement adjacent to large excavations can be s... A study to estimate land surface movement caused by large surface excavations in sedimentary strata is presented.In stratified or jointed strata the stress relief driven movement adjacent to large excavations can be significantly larger than expected.High lateral stresses measured in Australia and other places around the world indicate that the ratio of horizontal to vertical stress has been particularly high at shallow depths.The in situ strata is in compression and during excavation,stress is relieved towards the opening causing strata movement.Large excavations such as,open cut mines or highway cuttings,can initiate an extensive horizontal slide of surface layers towards the excavation.These ground movements can be damaging to surface structures such as water storage dams and large buildings.Based on stress measurements at shallow depths in Australian coal mines the study presented here calculates and models the extent of potential ground movement along the bedding surface adjacent to large excavations and provides a new prediction tool of land movement at the excavation boundary that can benefit the geotechnical practitioners in the mining industry. 展开更多
关键词 Stress measurements High lateral stress Lateral stress relief Lateral displacement of bedded strata Stability of large excavations
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