土工袋挡墙作为一种新型加筋土挡墙,已被广泛应用于水利、交通、建筑等各类工程的支挡结构。针对其工作环境多变的特点,运用岩土工程有限元分析软件GTS(Geotechnical and Tunnel analysis System)研究了土工袋挡墙在不同工况下的变形特...土工袋挡墙作为一种新型加筋土挡墙,已被广泛应用于水利、交通、建筑等各类工程的支挡结构。针对其工作环境多变的特点,运用岩土工程有限元分析软件GTS(Geotechnical and Tunnel analysis System)研究了土工袋挡墙在不同工况下的变形特性。研究结果表明挡墙坡度、高宽比以及填土表面荷载强度对于土工袋挡墙变形特性具有重要影响:坡度决定了土工袋挡墙的变形形态和变形转折点的位置范围,随着坡度变小,墙顶水平位移迅速减小;高宽比越小,墙面变形量越小,且挡墙坡度越大,减小高宽比对限制墙面弯曲变形的效果越好;填土表面荷载强度越大,墙面弯曲变形越大,墙面变形转折点位置随着填土表面荷载的增大在一定变化范围内逐渐上移。由结果可知,坡度决定挡墙变形形态,而高宽比及填土荷载影响主要墙面变形量。展开更多
Ce(SO4)2?H2O2 solution was adopted to prepare a chemical conversion coating on AZ91D magnesium alloy.Additives of Ni(NO3)2 and sodium dodecyl benzene sulfonate were applied to improving the coating formation.SEM,...Ce(SO4)2?H2O2 solution was adopted to prepare a chemical conversion coating on AZ91D magnesium alloy.Additives of Ni(NO3)2 and sodium dodecyl benzene sulfonate were applied to improving the coating formation.SEM,EDS,XRD and GIXD were adopted to study the coating morphology,structure and composition,and the potential change curve in the treating solution was recorded to study the coating growth.Sodium dodecyl benzene sulfonate makes a remarkable improvement in the coating compactness,and shortens the time in the second stage of the coating formation from 5 min to 2 min.Compared to Ni(NO3)2,sodium dodecyl benzene sulfonate makes the more remarkable effect on the corrosion resistance improvement,since it can decrease the current density of corrosion from 7.41×10-5 A/cm2 to 2.20×10-5 A/cm2.The additives of Ni(NO3)2 and sodium dodecyl benzene sulfonate can enhance the Ce content from 18.92% to 22.32% and 25.08% in the coating,respectively.The XRD and GIXD results indicated that all the conversion coating formed in different solutions exhibit amorphous structure.展开更多
A thermodynamic model was developed for determining the surface tension of RE2O3-MgO-SiO2(RE=La, Nd, Sm, Gd and Y) melts considering the ionic radii of the components and Butler's equation. The temperature and com...A thermodynamic model was developed for determining the surface tension of RE2O3-MgO-SiO2(RE=La, Nd, Sm, Gd and Y) melts considering the ionic radii of the components and Butler's equation. The temperature and composition dependence of the surface tensions in molten RE2O3-MgO-SiO2 slag systems was reproduced by the present model using surface tensions and molar volumes of pure oxides, as well as the anionic and cationic radii of the melt components. The iso-surface tension lines of La2O3-MgO-SiO2 slag melt at 1873 K were calculated and the effects of slag composition on the surface tension were also investigated. The surface tensions of La2O3, Gd2O3, Nd2O3 and Y2O3 at 1873 K were evaluated as 686, 677, 664 and 541 m N/m, respectively. The surface tension of pure rare earth oxide melts linearly decreases with increasing cationic field strength, except for Y2O3 oxide, while Y2O3 has a much weaker surface tension. The evaluated results of the surface tension show good agreements with literature data, and the mean deviation of the present model is found to be 1.05% at 1873 K.展开更多
A soil batch experiment was conducted to investigate both separate and compound effects of three types of surfactants: anionic dodecylbenzene sulfonic acid sodiumsalt (DBSS), cationic cetyltrimethylammonium bromide (C...A soil batch experiment was conducted to investigate both separate and compound effects of three types of surfactants: anionic dodecylbenzene sulfonic acid sodiumsalt (DBSS), cationic cetyltrimethylammonium bromide (CTAB), and non-ionic nonyl phenol polyethyleneoxy ether (TX-100), as well as ethylenediaminetetraacetic acid (EDTA) on cadmium solubility, sorption kinetics, and sorption-desorption behavior in purple soil. The results indicated that both individual application of the three types of surfactants and surfactants combined with EDTA could stimulate Cd extraction from the soil with a general effectiveness ranking of EDTA/TX-100 > EDTA/DBSS > EDTA/CTAB > EDTA > TX-100 > DBSS > CTAB. Further study showed that the compound application of surfactants and EDTA had stronger (P < 0.05) effects on Cd solubility than those added individually. The application of surfactants and EDTA to purple soil (P < 0.05) decreased the proportion of Cd sorbed, while their effectiveness ranking was similar to that of enhanced solubilization. The sorption kinetics of Cd in purple soil was best described by the double-constant equation, while the Freundlich equation gave an excellent fit to the sorption isotherm curves. Therefore, surfactant-enhanced remediation of Cd contaminated soil is feasible and further research should be conducted.展开更多
Global nitrogen (N) budgets for intensive agricultural systems were compiled for a 0.5 by 0.5 degree resolution. These budgets include N inputs (N fertilizer, animal manure, biological N fixation and atmospheric N dep...Global nitrogen (N) budgets for intensive agricultural systems were compiled for a 0.5 by 0.5 degree resolution. These budgets include N inputs (N fertilizer, animal manure, biological N fixation and atmospheric N deposition) and outputs (N removal from the field in harvested crops and grass and grass consumption by grazing animals, ammonia volatilization,denitrification and leaching). Data for the historical years 1970 and 1995 and a projection for 2030 were used to study changes in the recovery of N and the different loss terms for intensive agricultural systems. The results indicate that the overall system N recovery and fertilizer use efficiency slowly increased in the industrialized countries between 1970 and 1995, the values for developing countries have decreased in the same period. For the coming three decades our results indicate a rapid increase in both the industrialized and developing countries. High values of > 80% for fertilizer use efficiency may be related to surface N balance deficits, implying a depletion of soil N and loss of soil fertility. The projected intensification in most developing countries will cause a gradual shift from deficits to surpluses in the coming decades.The projected fast growth of crop and livestock production, and intensification and associated increase in fertilizer inputs will cause a major increase in the surface N balance surplus in the coming three decades. This implies increasing losses of N compounds to air (ammonia, nitrous oxide and nitric oxide), and groundwater and surface water (nitrate).展开更多
Adsorption isotherms of metsulfuron and bensulfuron on a hexadecyltrimethylammonium (HDTMA) bromide-modified paddy soil under different ionic strengths, with divalent cation Cu^2+, or having different pH were studi...Adsorption isotherms of metsulfuron and bensulfuron on a hexadecyltrimethylammonium (HDTMA) bromide-modified paddy soil under different ionic strengths, with divalent cation Cu^2+, or having different pH were studied to describe their adsorptive behavior, and to try to explain the adsorption process of a sulfonylurea compound with a carbamoylsulfamoyl group in the modified soil environment. All the adsorption isotherms fitted the Freundlich equation well, and the HDTMA treatment of paddy soil dramatically enhanced adsorption capacity of metsulfuron or bensulfuron. Also, an increase of ionic strength and the addition of divalent heavy metal cation Cu^2+ on the HDTMA-modified paddy soil increased the adsorption of metsulfuron or bensulfuron. Additionally, for metsulfuron and bensulfuron in the aqueous phase, adsorption capacity of the HDTMA-modified paddy soft gradually increased with decreasing pH.展开更多
Surface chemical properties of soil colloids are the important factor affecting soil fertility and genesis. To provide scientific basis for soil genetic classification, promotion of soil fertility and reasonable ferti...Surface chemical properties of soil colloids are the important factor affecting soil fertility and genesis. To provide scientific basis for soil genetic classification, promotion of soil fertility and reasonable fertilization, the specific surface area and electric charge of soil colloids in relation to clay minerals and organic matter are further discussed on the basis of the results obtained from the studies on surface chemical properties of soil colloids in five main soils of China. Results from the studies show that the effect of clay minerals and organic matter on the surface chemical properties of soil colloids is very complicated because the siloxane surface, hydrated oxide surface and organic matter surface do not exist separately, but they are always mixed together and influenced each other. The understanding of the relationship among clay minerals, organic matter and surface chemical properties of soil colloids depends upon further study of the relevant disciplines of soil science, especially the study on the mechanisms of organo-mineral complexes.展开更多
The phenomenon of preferential solution flow during dump leaching of low-grade ores was studied.The formative mechanism of preferential solution flow was investigated through analyzing the relationship between permeab...The phenomenon of preferential solution flow during dump leaching of low-grade ores was studied.The formative mechanism of preferential solution flow was investigated through analyzing the relationship between permeability and ore diameter,and the relationship between surface tension and ore diameter.The preferential solution flow happened within the fine ore area when the dump was unsaturated.And it could happen within the coarse ore area when the dump became saturated.The results of experiment show that the outflow of coarse ore area increases sharply with higher applied rate.The outflow of fine ore area is greater than that of coarse ore area when the applied rate is below 3.2 L/min,and the preferential solution flow happens in fine ore area.But the preferential solution flow happens in coarse ore area when the applied rate is higher than 3.2 L/min.The result of the experiment is consistent with the mechanism analyzing.展开更多
Remote sensing and geographic information systems (GIS) technologies were used to detect land use/cover changes (LUCC) and to assess their impacts on land surface temperature (LST) in the Zhujiang Delta. Multi-tempora...Remote sensing and geographic information systems (GIS) technologies were used to detect land use/cover changes (LUCC) and to assess their impacts on land surface temperature (LST) in the Zhujiang Delta. Multi-temporal Landsat TM and Landsat ETM+ data were employed to identify patterns of LUCC as well as to quantify urban expansion and the associated decrease of vegetation cover. The thermal infrared bands of the data were used to retrieve LST. The results revealed a strong and uneven urban growth,which caused LST to raise 4.56℃in the newly urbanized part of the study area. Overall, remote sensing and GIS technologies were effective approaches for monitoring and analyzing urban growth patterns and evaluating their impacts on LST.展开更多
Adsorption of potassium and sodium ions by four typical variable charge soils of South China was studied. The results indicated that the variable charge soils saturated with H and Al showed a much higher preference fo...Adsorption of potassium and sodium ions by four typical variable charge soils of South China was studied. The results indicated that the variable charge soils saturated with H and Al showed a much higher preference for potassium ions relative to sodium ions, and this tendency could not be changed by such factors as the pH, the concentration of the cations, the dielectric constant of solvent, the accompanying anions and the iron oxide content etc., suggesting that this difference in affinity is caused by the difference in the nature of the two cations. It was observed that a negative adsorption of sodium ions by latosol and lateritic red soil in a mixed system containing equal amount of potassium and sodium ions at low pH, which is caused by a competitive adsorption of potassium and sodium ions and repulsion of positive charge on the surfaces of soil particles for cations. The adsorption of potassium and sodium ions increased with the decreases in the dielectric constant of solvent and the iron oxide content. Sulfate affected the adsorption of potassium and sodium ions through changing the surface properties of the soils.展开更多
We investigated the patterns of phosphorus transport from purple-soil cropland of 5° and 10° slopes with bare and vegetated surfaces,respectively.Each type of land was tested under a simulated moderate rainf...We investigated the patterns of phosphorus transport from purple-soil cropland of 5° and 10° slopes with bare and vegetated surfaces,respectively.Each type of land was tested under a simulated moderate rainfall of 0.33 mm/min,a downfall of 0.90 mm/min,and a rainstorm of 1.86 mm/min.Runoff dynamics and changes in the export amount of phosphorus are influenced by the rainfall intensity,the slope and surface conditions of cropland.The vegetation diverts rain water from the surface into soil and helps the formation of a subsurface runoff,but has little influence on runoff process at the same sloping degree.Vegetated soil has a smaller phosphorous loss,particularly much less in the particulate form.A heavier rainfall flushes away more phosphorous.Rainwater percolating soil carries more dissolved phosphorous than particulate phosphorous.Understanding the patterns of phosphorous transport under various conditions from purple soil in the middle of Sichuan basin is helpful for developing countermeasures against non-point-source pollution resulting in the eutrophication of water bodies in this region that could,if not controlled properly,deteriorate the water quality of the Three Gorges Reservoir.展开更多
Surface morphology of soil cracks is one of the important factors influencing the water evaporation rate in cracked soil in Yuanmou Dry-hot Valley Region,Southwest China. Quantitative study of the complicated surface ...Surface morphology of soil cracks is one of the important factors influencing the water evaporation rate in cracked soil in Yuanmou Dry-hot Valley Region,Southwest China. Quantitative study of the complicated surface morphology of soil cracks is a prerequisite for further studies of soil-cracking mechanisms. The present paper establishes a quantitative indicator system by application of concepts and methods originating from Fractal Geometry and Network Analysis. These indicators can effectively express the complicated features of soil-crack network structure. Furthermore,a series of values related to soil-crack morphology was obtained by image processing on field photos of soil-crack quads,and gradation criteria for the degree of development of soil cracks were determined. Finally,the changes in values of the morphological indicators under different degrees of development were analyzed in detail. Our results indicate that (1) the degree of development of soil cracks can be divided into five grades,i.e.,feeble development,slight development,medium development,intensive development and extremely intensive development; (2) the values of the indicators change predictably with increasing degree of development of soil cracks. The area density (Dc) increases,and both the area-weighted mean ratio of crack area to perimeter (AWMARP),which reflects the intensity of cracking,and the index r,which is related to the connectivity of a soil crack,grow uniformly (albeit with different forms). AWMRAP increases at a geometric rate while r shows logarithm-mic growth,indicating a gradual increase in theconnectivity of a soil crack. Nevertheless,the area-weighted mean of soil-crack fractal dimension (AWMFRAC) shows a decreasing trend,indicating a gradual decline in the complexity of cracks as area density increases.展开更多
Two cells consisting of a chloride-selective electrode and a nitrate-selective electrode or of a chloride-selective electrode and a perchlorate-selective electrode were directly put in the soil suspension to determine...Two cells consisting of a chloride-selective electrode and a nitrate-selective electrode or of a chloride-selective electrode and a perchlorate-selective electrode were directly put in the soil suspension to determine the concentration ratios Cl-/ NO3- or Cl-/ ClO4- for studying the adsorption of the three anions by variable charge soils. It was found that all the concentration ratios CCl- / CNO3- and CCl- / CClO4- in suspension were smaller than unity when soil samples were in equilibrium with mixed KCl and KNO3 or KCl and KClO4 solutions of equal concentration. The order of the amount of chloride, nitrate and perchlorate adsorbed by variable charge soils was Cl-> NO3-> ClO4- when the soils adsorbed these anions from the solution containing equal concentrations of Cl-, NO3- and ClO4-. Such factors as the pH of the suspension, the iron oxide content of the soil etc. could affect the amounts and the ratios of anions adsorbed. The adsorption was chiefly caused by coulombic attraction, but a covalent force between the anion and the metal atom on the surface of soil particles may also be involved, at least for Cl- ions, even for NO3- ions.展开更多
文摘土工袋挡墙作为一种新型加筋土挡墙,已被广泛应用于水利、交通、建筑等各类工程的支挡结构。针对其工作环境多变的特点,运用岩土工程有限元分析软件GTS(Geotechnical and Tunnel analysis System)研究了土工袋挡墙在不同工况下的变形特性。研究结果表明挡墙坡度、高宽比以及填土表面荷载强度对于土工袋挡墙变形特性具有重要影响:坡度决定了土工袋挡墙的变形形态和变形转折点的位置范围,随着坡度变小,墙顶水平位移迅速减小;高宽比越小,墙面变形量越小,且挡墙坡度越大,减小高宽比对限制墙面弯曲变形的效果越好;填土表面荷载强度越大,墙面弯曲变形越大,墙面变形转折点位置随着填土表面荷载的增大在一定变化范围内逐渐上移。由结果可知,坡度决定挡墙变形形态,而高宽比及填土荷载影响主要墙面变形量。
基金Project (20070420772) supported by Postdoctoral Science Foundation of ChinaProject (7010404) supported by the Natural Science Foundation of Guangdong Province,China
文摘Ce(SO4)2?H2O2 solution was adopted to prepare a chemical conversion coating on AZ91D magnesium alloy.Additives of Ni(NO3)2 and sodium dodecyl benzene sulfonate were applied to improving the coating formation.SEM,EDS,XRD and GIXD were adopted to study the coating morphology,structure and composition,and the potential change curve in the treating solution was recorded to study the coating growth.Sodium dodecyl benzene sulfonate makes a remarkable improvement in the coating compactness,and shortens the time in the second stage of the coating formation from 5 min to 2 min.Compared to Ni(NO3)2,sodium dodecyl benzene sulfonate makes the more remarkable effect on the corrosion resistance improvement,since it can decrease the current density of corrosion from 7.41×10-5 A/cm2 to 2.20×10-5 A/cm2.The additives of Ni(NO3)2 and sodium dodecyl benzene sulfonate can enhance the Ce content from 18.92% to 22.32% and 25.08% in the coating,respectively.The XRD and GIXD results indicated that all the conversion coating formed in different solutions exhibit amorphous structure.
基金Project(51374020)supported by the National Natural Science Foundation of China
文摘A thermodynamic model was developed for determining the surface tension of RE2O3-MgO-SiO2(RE=La, Nd, Sm, Gd and Y) melts considering the ionic radii of the components and Butler's equation. The temperature and composition dependence of the surface tensions in molten RE2O3-MgO-SiO2 slag systems was reproduced by the present model using surface tensions and molar volumes of pure oxides, as well as the anionic and cationic radii of the melt components. The iso-surface tension lines of La2O3-MgO-SiO2 slag melt at 1873 K were calculated and the effects of slag composition on the surface tension were also investigated. The surface tensions of La2O3, Gd2O3, Nd2O3 and Y2O3 at 1873 K were evaluated as 686, 677, 664 and 541 m N/m, respectively. The surface tension of pure rare earth oxide melts linearly decreases with increasing cationic field strength, except for Y2O3 oxide, while Y2O3 has a much weaker surface tension. The evaluated results of the surface tension show good agreements with literature data, and the mean deviation of the present model is found to be 1.05% at 1873 K.
基金Project supported by the Foundation for University Key Teachers through the Education Committee of Chongqing,China (No. 110758).
文摘A soil batch experiment was conducted to investigate both separate and compound effects of three types of surfactants: anionic dodecylbenzene sulfonic acid sodiumsalt (DBSS), cationic cetyltrimethylammonium bromide (CTAB), and non-ionic nonyl phenol polyethyleneoxy ether (TX-100), as well as ethylenediaminetetraacetic acid (EDTA) on cadmium solubility, sorption kinetics, and sorption-desorption behavior in purple soil. The results indicated that both individual application of the three types of surfactants and surfactants combined with EDTA could stimulate Cd extraction from the soil with a general effectiveness ranking of EDTA/TX-100 > EDTA/DBSS > EDTA/CTAB > EDTA > TX-100 > DBSS > CTAB. Further study showed that the compound application of surfactants and EDTA had stronger (P < 0.05) effects on Cd solubility than those added individually. The application of surfactants and EDTA to purple soil (P < 0.05) decreased the proportion of Cd sorbed, while their effectiveness ranking was similar to that of enhanced solubilization. The sorption kinetics of Cd in purple soil was best described by the double-constant equation, while the Freundlich equation gave an excellent fit to the sorption isotherm curves. Therefore, surfactant-enhanced remediation of Cd contaminated soil is feasible and further research should be conducted.
基金Project supported by the Netherlands Environmental Assessment Agency, National Institute for Public Health and the Environment (No. S/550005/01/DD) the Canadian International Development Agency, Canada and the Chinese Academy of Sciences, China (No.KZCX2-413)
文摘Global nitrogen (N) budgets for intensive agricultural systems were compiled for a 0.5 by 0.5 degree resolution. These budgets include N inputs (N fertilizer, animal manure, biological N fixation and atmospheric N deposition) and outputs (N removal from the field in harvested crops and grass and grass consumption by grazing animals, ammonia volatilization,denitrification and leaching). Data for the historical years 1970 and 1995 and a projection for 2030 were used to study changes in the recovery of N and the different loss terms for intensive agricultural systems. The results indicate that the overall system N recovery and fertilizer use efficiency slowly increased in the industrialized countries between 1970 and 1995, the values for developing countries have decreased in the same period. For the coming three decades our results indicate a rapid increase in both the industrialized and developing countries. High values of > 80% for fertilizer use efficiency may be related to surface N balance deficits, implying a depletion of soil N and loss of soil fertility. The projected intensification in most developing countries will cause a gradual shift from deficits to surpluses in the coming decades.The projected fast growth of crop and livestock production, and intensification and associated increase in fertilizer inputs will cause a major increase in the surface N balance surplus in the coming three decades. This implies increasing losses of N compounds to air (ammonia, nitrous oxide and nitric oxide), and groundwater and surface water (nitrate).
基金Project supported by the National Key Basic Research Support Foundation of China (No. 2002CB410804) the National Natural Science Foundation of China (No. 39970146).
文摘Adsorption isotherms of metsulfuron and bensulfuron on a hexadecyltrimethylammonium (HDTMA) bromide-modified paddy soil under different ionic strengths, with divalent cation Cu^2+, or having different pH were studied to describe their adsorptive behavior, and to try to explain the adsorption process of a sulfonylurea compound with a carbamoylsulfamoyl group in the modified soil environment. All the adsorption isotherms fitted the Freundlich equation well, and the HDTMA treatment of paddy soil dramatically enhanced adsorption capacity of metsulfuron or bensulfuron. Also, an increase of ionic strength and the addition of divalent heavy metal cation Cu^2+ on the HDTMA-modified paddy soil increased the adsorption of metsulfuron or bensulfuron. Additionally, for metsulfuron and bensulfuron in the aqueous phase, adsorption capacity of the HDTMA-modified paddy soft gradually increased with decreasing pH.
文摘Surface chemical properties of soil colloids are the important factor affecting soil fertility and genesis. To provide scientific basis for soil genetic classification, promotion of soil fertility and reasonable fertilization, the specific surface area and electric charge of soil colloids in relation to clay minerals and organic matter are further discussed on the basis of the results obtained from the studies on surface chemical properties of soil colloids in five main soils of China. Results from the studies show that the effect of clay minerals and organic matter on the surface chemical properties of soil colloids is very complicated because the siloxane surface, hydrated oxide surface and organic matter surface do not exist separately, but they are always mixed together and influenced each other. The understanding of the relationship among clay minerals, organic matter and surface chemical properties of soil colloids depends upon further study of the relevant disciplines of soil science, especially the study on the mechanisms of organo-mineral complexes.
基金Project(50325415)supported by the National Science Fund for Distinguished Young ScholarsProject (50621603) supported by China Science Fund for Distinguished Group+1 种基金Project (2004CB619200) supported by National Key Fundamental Research and Development Program of ChinaProject (50574099) supported by National Natural Science Foundation of China
文摘The phenomenon of preferential solution flow during dump leaching of low-grade ores was studied.The formative mechanism of preferential solution flow was investigated through analyzing the relationship between permeability and ore diameter,and the relationship between surface tension and ore diameter.The preferential solution flow happened within the fine ore area when the dump was unsaturated.And it could happen within the coarse ore area when the dump became saturated.The results of experiment show that the outflow of coarse ore area increases sharply with higher applied rate.The outflow of fine ore area is greater than that of coarse ore area when the applied rate is below 3.2 L/min,and the preferential solution flow happens in fine ore area.But the preferential solution flow happens in coarse ore area when the applied rate is higher than 3.2 L/min.The result of the experiment is consistent with the mechanism analyzing.
基金Project supported by the Science and Technology Project Foundation of Guangzhou (No. 2005Z3-D0551)the Science and Technology Project Foundation of Guangzhou Education Bureau (No. 62026)
文摘Remote sensing and geographic information systems (GIS) technologies were used to detect land use/cover changes (LUCC) and to assess their impacts on land surface temperature (LST) in the Zhujiang Delta. Multi-temporal Landsat TM and Landsat ETM+ data were employed to identify patterns of LUCC as well as to quantify urban expansion and the associated decrease of vegetation cover. The thermal infrared bands of the data were used to retrieve LST. The results revealed a strong and uneven urban growth,which caused LST to raise 4.56℃in the newly urbanized part of the study area. Overall, remote sensing and GIS technologies were effective approaches for monitoring and analyzing urban growth patterns and evaluating their impacts on LST.
文摘Adsorption of potassium and sodium ions by four typical variable charge soils of South China was studied. The results indicated that the variable charge soils saturated with H and Al showed a much higher preference for potassium ions relative to sodium ions, and this tendency could not be changed by such factors as the pH, the concentration of the cations, the dielectric constant of solvent, the accompanying anions and the iron oxide content etc., suggesting that this difference in affinity is caused by the difference in the nature of the two cations. It was observed that a negative adsorption of sodium ions by latosol and lateritic red soil in a mixed system containing equal amount of potassium and sodium ions at low pH, which is caused by a competitive adsorption of potassium and sodium ions and repulsion of positive charge on the surfaces of soil particles for cations. The adsorption of potassium and sodium ions increased with the decreases in the dielectric constant of solvent and the iron oxide content. Sulfate affected the adsorption of potassium and sodium ions through changing the surface properties of the soils.
基金the Natural Science Foundation of China (No. 40571093)the National Field Station Fund
文摘We investigated the patterns of phosphorus transport from purple-soil cropland of 5° and 10° slopes with bare and vegetated surfaces,respectively.Each type of land was tested under a simulated moderate rainfall of 0.33 mm/min,a downfall of 0.90 mm/min,and a rainstorm of 1.86 mm/min.Runoff dynamics and changes in the export amount of phosphorus are influenced by the rainfall intensity,the slope and surface conditions of cropland.The vegetation diverts rain water from the surface into soil and helps the formation of a subsurface runoff,but has little influence on runoff process at the same sloping degree.Vegetated soil has a smaller phosphorous loss,particularly much less in the particulate form.A heavier rainfall flushes away more phosphorous.Rainwater percolating soil carries more dissolved phosphorous than particulate phosphorous.Understanding the patterns of phosphorous transport under various conditions from purple soil in the middle of Sichuan basin is helpful for developing countermeasures against non-point-source pollution resulting in the eutrophication of water bodies in this region that could,if not controlled properly,deteriorate the water quality of the Three Gorges Reservoir.
基金supported by the National Key Technologies Research and Development Program in the Eleventh Five-Year Plan of China (Grant No.2008BAD98B02, 2006BAC01A11)the Western Light Program of Talents Cultivating of CAS (2008)+1 种基金the National Natural Sciences Foundation of China (Grant No. 30470297)the Foundation of Key Laboratory of Mountain Hazards and Surface Process, CAS
文摘Surface morphology of soil cracks is one of the important factors influencing the water evaporation rate in cracked soil in Yuanmou Dry-hot Valley Region,Southwest China. Quantitative study of the complicated surface morphology of soil cracks is a prerequisite for further studies of soil-cracking mechanisms. The present paper establishes a quantitative indicator system by application of concepts and methods originating from Fractal Geometry and Network Analysis. These indicators can effectively express the complicated features of soil-crack network structure. Furthermore,a series of values related to soil-crack morphology was obtained by image processing on field photos of soil-crack quads,and gradation criteria for the degree of development of soil cracks were determined. Finally,the changes in values of the morphological indicators under different degrees of development were analyzed in detail. Our results indicate that (1) the degree of development of soil cracks can be divided into five grades,i.e.,feeble development,slight development,medium development,intensive development and extremely intensive development; (2) the values of the indicators change predictably with increasing degree of development of soil cracks. The area density (Dc) increases,and both the area-weighted mean ratio of crack area to perimeter (AWMARP),which reflects the intensity of cracking,and the index r,which is related to the connectivity of a soil crack,grow uniformly (albeit with different forms). AWMRAP increases at a geometric rate while r shows logarithm-mic growth,indicating a gradual increase in theconnectivity of a soil crack. Nevertheless,the area-weighted mean of soil-crack fractal dimension (AWMFRAC) shows a decreasing trend,indicating a gradual decline in the complexity of cracks as area density increases.
文摘Two cells consisting of a chloride-selective electrode and a nitrate-selective electrode or of a chloride-selective electrode and a perchlorate-selective electrode were directly put in the soil suspension to determine the concentration ratios Cl-/ NO3- or Cl-/ ClO4- for studying the adsorption of the three anions by variable charge soils. It was found that all the concentration ratios CCl- / CNO3- and CCl- / CClO4- in suspension were smaller than unity when soil samples were in equilibrium with mixed KCl and KNO3 or KCl and KClO4 solutions of equal concentration. The order of the amount of chloride, nitrate and perchlorate adsorbed by variable charge soils was Cl-> NO3-> ClO4- when the soils adsorbed these anions from the solution containing equal concentrations of Cl-, NO3- and ClO4-. Such factors as the pH of the suspension, the iron oxide content of the soil etc. could affect the amounts and the ratios of anions adsorbed. The adsorption was chiefly caused by coulombic attraction, but a covalent force between the anion and the metal atom on the surface of soil particles may also be involved, at least for Cl- ions, even for NO3- ions.