A broadband infrared surface sum frequency generation vibrational spectroscopy （SFG-VS） and an in situ UV excitation setup devoted to studying surface photocatalysis have been constructed. With a home-made compact h...A broadband infrared surface sum frequency generation vibrational spectroscopy （SFG-VS） and an in situ UV excitation setup devoted to studying surface photocatalysis have been constructed. With a home-made compact high vacuum cell, organic contaminants on TiO2 thin film surface prepared by RF magnetron sputtering were in situ removed under 266 nm irradiation in 10 kPa 02 atmosphere. We obtained the methanol spectrum in the CH3 stretching vibration region on TiO2 surface with changing the methanol pressure at room temperature. Features of both molecular and dissociative methanol, methoxy, adsorbed on this surface were resolved. The CH3 symmetric stretching vibration frequency and Fermi resonance of molecular methanol is red-shifted by about 6-8 cm-1 from low to high coverage. Moreover, the recombination of dissociative methanol and H on Surfaces in vacuum was also observed. Our results suggest two equilibria exist： between molecular methanol in the gas phase and that on surfaces, and between molecular methanol and dissociative methanol on surfaces.展开更多
Removal of foreign bodies from seed mixtures, or their calibration for use as planting material, as well as fraction classification of granular materials requires screening surfaces with vibratory motion. This paper p...Removal of foreign bodies from seed mixtures, or their calibration for use as planting material, as well as fraction classification of granular materials requires screening surfaces with vibratory motion. This paper presents some aspects on the working process of a sieve, made of perforated sheet and having an outer conical surface with oscillatory circular motion （alternative） on the horizontal. Results are presented for some experimental researches on the movement of material on the sieve, for various kinematical parameters of the sieve （amplitude and oscillation frequency）. A conical sieve, suspended at the upper and lower in three points, was tested for screening of rapeseeds in order to estimate the influence of oscillation frequency on the screening process. Curves were drawn for separation intensity on the sieve generating line, and by regression analysis with normal distribution law were determined the equation coefficients and the correlation with experimental data. Movement of material on the sieve and its working process, in general, was appreciated by means of the peak position of distribution curve depending on the oscillation frequency of the sieve, considering that the normal distribution law correlates very well the data obtained by experiments.展开更多
基金This work was supported by the National Ba- sic Research Program of China （No.2013CB834600） and the National Natural Science Foundation of China （No.II27002/B030403, No.II290162/A040106, and No.21322310/B030402）.
文摘A broadband infrared surface sum frequency generation vibrational spectroscopy （SFG-VS） and an in situ UV excitation setup devoted to studying surface photocatalysis have been constructed. With a home-made compact high vacuum cell, organic contaminants on TiO2 thin film surface prepared by RF magnetron sputtering were in situ removed under 266 nm irradiation in 10 kPa 02 atmosphere. We obtained the methanol spectrum in the CH3 stretching vibration region on TiO2 surface with changing the methanol pressure at room temperature. Features of both molecular and dissociative methanol, methoxy, adsorbed on this surface were resolved. The CH3 symmetric stretching vibration frequency and Fermi resonance of molecular methanol is red-shifted by about 6-8 cm-1 from low to high coverage. Moreover, the recombination of dissociative methanol and H on Surfaces in vacuum was also observed. Our results suggest two equilibria exist： between molecular methanol in the gas phase and that on surfaces, and between molecular methanol and dissociative methanol on surfaces.
文摘Removal of foreign bodies from seed mixtures, or their calibration for use as planting material, as well as fraction classification of granular materials requires screening surfaces with vibratory motion. This paper presents some aspects on the working process of a sieve, made of perforated sheet and having an outer conical surface with oscillatory circular motion （alternative） on the horizontal. Results are presented for some experimental researches on the movement of material on the sieve, for various kinematical parameters of the sieve （amplitude and oscillation frequency）. A conical sieve, suspended at the upper and lower in three points, was tested for screening of rapeseeds in order to estimate the influence of oscillation frequency on the screening process. Curves were drawn for separation intensity on the sieve generating line, and by regression analysis with normal distribution law were determined the equation coefficients and the correlation with experimental data. Movement of material on the sieve and its working process, in general, was appreciated by means of the peak position of distribution curve depending on the oscillation frequency of the sieve, considering that the normal distribution law correlates very well the data obtained by experiments.
