A matrix of 96 Al2O3 ceramics was implanted with Ni ion of different dosages and energies using a MEVVA implanter. Then metallic structures of copper were made on the implanted ceramics, by using selective electroless...A matrix of 96 Al2O3 ceramics was implanted with Ni ion of different dosages and energies using a MEVVA implanter. Then metallic structures of copper were made on the implanted ceramics, by using selective electroless copper plating. In addition, the characteristics and microstructure of the implanted layer were studied by using the SEM, RBS and XPS. The results show that： 1） the implanted Ni exits as Ni^2, Ni^2＋, and Ni^3＋ in the surface of Al2O3 and metal Ni particles precipitate on ceramics during implantation; 2） the concentration of Ni submits to the Gauss distribution along the direction of implantation on the surface of Al2O3 and high Ni concentration on the surface can be obtained if the Ni is implanted with low energy and a high dosage and 3） Ni ion implantation can activate the surface of Al2O3 and induce electroless copper plating on the ceramics.展开更多
Organic electroluminescent device,also known as organic light-emitting diode (OLED),is a kind of solid state light emitting device by carrier injection which can directly transform electrical energy into luminous ener...Organic electroluminescent device,also known as organic light-emitting diode (OLED),is a kind of solid state light emitting device by carrier injection which can directly transform electrical energy into luminous energy.Due to its low operating voltage,low energy consumption,high brightness,flexibility in the choice of materials and easy realization of full color display,OLED is the potential material both in the display and illumination fields.However,there is much scope to improve the efficiency,lifetime,and reduce the cost in mass production before OLEDs can replace traditional technology in some application fields.In this work,we report the oxygen plasma immersion ion implantation (PIII) to improve the surface oxygen ratio of ITO films for further increase of surface work function above the common treatment of O2 inductively coupled plasma (ICP).The ratio of oxygen content at the surface layer was improved to be much higher than by O2 ICP treatment.A further surface work function relative increase of 0.4e V above OICP sample and 0.4 eV above the as-prepared sample can be estimated by the peak relative shift in the X-ray photoelectron spectroscopy (XPS) diagram.Moreover,the XPS characterization was carried out at least 50 h after the PIII implantation to indicate that the surface modifying effects are stable.The variations of transparency and conductivity of the PIII treated ITO samples can be neglected.展开更多
基金Project BK200403 supported by the Natural Science Foundation of Jiangsu Province Project 2005A046 supported by Youth Foundation of CUMT
文摘A matrix of 96 Al2O3 ceramics was implanted with Ni ion of different dosages and energies using a MEVVA implanter. Then metallic structures of copper were made on the implanted ceramics, by using selective electroless copper plating. In addition, the characteristics and microstructure of the implanted layer were studied by using the SEM, RBS and XPS. The results show that： 1） the implanted Ni exits as Ni^2, Ni^2＋, and Ni^3＋ in the surface of Al2O3 and metal Ni particles precipitate on ceramics during implantation; 2） the concentration of Ni submits to the Gauss distribution along the direction of implantation on the surface of Al2O3 and high Ni concentration on the surface can be obtained if the Ni is implanted with low energy and a high dosage and 3） Ni ion implantation can activate the surface of Al2O3 and induce electroless copper plating on the ceramics.
基金supported by the National Natural Science Foundation of China (Grant Nos. 11005021 and 51177017)
文摘Organic electroluminescent device,also known as organic light-emitting diode (OLED),is a kind of solid state light emitting device by carrier injection which can directly transform electrical energy into luminous energy.Due to its low operating voltage,low energy consumption,high brightness,flexibility in the choice of materials and easy realization of full color display,OLED is the potential material both in the display and illumination fields.However,there is much scope to improve the efficiency,lifetime,and reduce the cost in mass production before OLEDs can replace traditional technology in some application fields.In this work,we report the oxygen plasma immersion ion implantation (PIII) to improve the surface oxygen ratio of ITO films for further increase of surface work function above the common treatment of O2 inductively coupled plasma (ICP).The ratio of oxygen content at the surface layer was improved to be much higher than by O2 ICP treatment.A further surface work function relative increase of 0.4e V above OICP sample and 0.4 eV above the as-prepared sample can be estimated by the peak relative shift in the X-ray photoelectron spectroscopy (XPS) diagram.Moreover,the XPS characterization was carried out at least 50 h after the PIII implantation to indicate that the surface modifying effects are stable.The variations of transparency and conductivity of the PIII treated ITO samples can be neglected.
