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电化学渗氮对不锈钢表面结构的影响
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作者 陈真勇 魏欣欣 +2 位作者 徐妍婷 张波 马秀良 《材料研究学报》 EI CAS CSCD 北大核心 2024年第3期161-167,共7页
使用原子力显微技术和透射电子显微技术等手段,研究了电化学渗氮的304L不锈钢多尺度下表面结构的演变。结果表明,在电化学渗氮电位下304L不锈钢表面发生了钝化膜的局部阴极还原、金属基体的微区阳极溶解以及溶解的金属阳离子再沉积,从... 使用原子力显微技术和透射电子显微技术等手段,研究了电化学渗氮的304L不锈钢多尺度下表面结构的演变。结果表明,在电化学渗氮电位下304L不锈钢表面发生了钝化膜的局部阴极还原、金属基体的微区阳极溶解以及溶解的金属阳离子再沉积,从而形成了起伏幅度为几十纳米的微观粗糙表面。在扫描透射成像模式下进行的超级能谱分析结果表明,表面沉积物的主要组成是Fe的氧化物,进一步佐证了在渗氮过程中发生了Fe的微区阳极溶解和Fe阳离子的再沉积过程。 展开更多
关键词 材料表面与界面 表面结构演变 电化学渗氮 透射电子显微技术 原子力显微技术 304L不锈钢
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Evolution of surface microstructure of Cu-50Cr alloy treated by high current pulsed electron beam 被引量:7
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作者 CHAI LinJiang ZHOU ZhiMing +3 位作者 XIAO ZhiPei TU Jian WANG YaPing HUANG WeiJiu 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2015年第3期462-469,共8页
A Cu-50Cr alloy was treated by the high current pulsed electron beam(HCPEB)at 20 and 30 ke V with pulse numbers ranging from 1 to 100.Surface morphologies and microstructures of specimens before and after the treatmen... A Cu-50Cr alloy was treated by the high current pulsed electron beam(HCPEB)at 20 and 30 ke V with pulse numbers ranging from 1 to 100.Surface morphologies and microstructures of specimens before and after the treatments were investigated by employing scanning electron microscopy and X-ray diffraction.Results show that the HCPEB technique is able to induce remarkable surface modifications for the Cu-50Cr alloy.Cracks in Cr phases appear even after one-pulse treatment and their density always increases with the pulse number.Formation reason for these cracks is attributed to quasi-static thermal stresses accumulated along the specimen surface.Craters with typical morphologies are formed due to the dynamic thermal field induced by the HCPEB and they are found to prefer the sites near cracks or boundaries between neighboring Cr phases.Another microstructural characteristic produced by the HCPEB is the fine Cr spheroids,which are determined to be due to occurrence of liquid phase separation in the Cu-50Cr alloy.Finally,a general microstructural evolution profile that incorporates various HCPEB-induced surface features is tentatively outlined. 展开更多
关键词 Cu-Cr alloy MICROSTRUCTURE surface modification electron beam
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