Pores,microcracks and density of plasma sprayed Cr2O3 coatings before and after high-intensity pulsed ion beam(HIPIB) irradiation were investigated using the ultrasonic reflection coefficient spectroscopy(URCS).The UR...Pores,microcracks and density of plasma sprayed Cr2O3 coatings before and after high-intensity pulsed ion beam(HIPIB) irradiation were investigated using the ultrasonic reflection coefficient spectroscopy(URCS).The URCS was analyzed based on an acoustic transmission model for the multi-layered structure.The longitudinal velocity in the coatings was calculated from the experimental URCS,and the attenuation coefficient expression was deduced by comparing the experimental and numerical fitting amplitude spectral lines.The longitudinal velocity of as-sprayed Cr2O3 coating is 2 002 m/s,and increases to 2 099 and 2 148 m/s after being irradiated by HIPIB with 1 and 5 shots.Correspondingly,the factor A changes from 0.046 to 0.026 and 0.020 and n from 1.702 to 1.658 and 1.649 in the attenuation coefficient expression of α=Af n.It is observed that the surface morphology of Cr2O3 coatings changes from rough and porous to smooth and uniform with the increase of shot number,which accords with the ultrasonic analyses reasonably.The URCS seems to provide a convenient and nondestructive method to characterize surface modification of the plasma sprayed coatings.展开更多
The absorption process of radiative heat in its transmission medium and the effect of ultra-attenuation on the radiative characteristics are analyzed in detail. A method of ultra-attenuation to enhance the radiative c...The absorption process of radiative heat in its transmission medium and the effect of ultra-attenuation on the radiative characteristics are analyzed in detail. A method of ultra-attenuation to enhance the radiative characteristics of the medium is proposed. It is proved that decreasing the particle size of coatings can increase the transmission depth of radiative heat and get higher emissivity and absorptivity both theoretically and practically. Ultra-attenuation and nanocrystallization will bring a brilliant prospect to the development of radiative coatings.展开更多
Sodium hypochlorite and ozone are the principal active substances and usually employed in ballast water management systems. In the present study, the authors focus on the effect of these active substances to the maaix...Sodium hypochlorite and ozone are the principal active substances and usually employed in ballast water management systems. In the present study, the authors focus on the effect of these active substances to the maaix polymer of coating. In order to obtain such information, the authors investigated the penetration of active substances to the polymer from cross section of specimens introduced by SAICAS （surface and interracial cutting analysis system）, followed by FT-IR-ATR （Fourier transform infrared and attenuated total reflectance） spectroscopy analysis from Z direction of cross section. The corrosion test of coating panels by these active substances （control as artificial seawater） has been conducted for 120 days. The results show that the depth profile of each active substance is around few dozens of micrometers from coating surface. The criteria of corrosion test cannot be determined by these results due to lacking in actual corrosion data immersed for 15 years under active substances. However, the authors evaluated the effect on ballast tank coating systems by active substances using analytical methods of SAICAS and FT-IR-ATR spectroscopy.展开更多
基金Project(KM200710015010) supported by the Scientific Research Program of Beijing Municipal Education Commission,China
文摘Pores,microcracks and density of plasma sprayed Cr2O3 coatings before and after high-intensity pulsed ion beam(HIPIB) irradiation were investigated using the ultrasonic reflection coefficient spectroscopy(URCS).The URCS was analyzed based on an acoustic transmission model for the multi-layered structure.The longitudinal velocity in the coatings was calculated from the experimental URCS,and the attenuation coefficient expression was deduced by comparing the experimental and numerical fitting amplitude spectral lines.The longitudinal velocity of as-sprayed Cr2O3 coating is 2 002 m/s,and increases to 2 099 and 2 148 m/s after being irradiated by HIPIB with 1 and 5 shots.Correspondingly,the factor A changes from 0.046 to 0.026 and 0.020 and n from 1.702 to 1.658 and 1.649 in the attenuation coefficient expression of α=Af n.It is observed that the surface morphology of Cr2O3 coatings changes from rough and porous to smooth and uniform with the increase of shot number,which accords with the ultrasonic analyses reasonably.The URCS seems to provide a convenient and nondestructive method to characterize surface modification of the plasma sprayed coatings.
文摘The absorption process of radiative heat in its transmission medium and the effect of ultra-attenuation on the radiative characteristics are analyzed in detail. A method of ultra-attenuation to enhance the radiative characteristics of the medium is proposed. It is proved that decreasing the particle size of coatings can increase the transmission depth of radiative heat and get higher emissivity and absorptivity both theoretically and practically. Ultra-attenuation and nanocrystallization will bring a brilliant prospect to the development of radiative coatings.
文摘Sodium hypochlorite and ozone are the principal active substances and usually employed in ballast water management systems. In the present study, the authors focus on the effect of these active substances to the maaix polymer of coating. In order to obtain such information, the authors investigated the penetration of active substances to the polymer from cross section of specimens introduced by SAICAS （surface and interracial cutting analysis system）, followed by FT-IR-ATR （Fourier transform infrared and attenuated total reflectance） spectroscopy analysis from Z direction of cross section. The corrosion test of coating panels by these active substances （control as artificial seawater） has been conducted for 120 days. The results show that the depth profile of each active substance is around few dozens of micrometers from coating surface. The criteria of corrosion test cannot be determined by these results due to lacking in actual corrosion data immersed for 15 years under active substances. However, the authors evaluated the effect on ballast tank coating systems by active substances using analytical methods of SAICAS and FT-IR-ATR spectroscopy.
