土壤氡气和分量化探技术在西岩地区铀矿勘查中联合应用研究

西岩地区位于修水-宁国碳硅泥岩型铀成矿带中段,为更好预测研究区深部铀成矿潜力,探索土壤氡气和分量化探技术在碳硅泥岩型铀矿勘查工作中的联合应用效果,研究采用土壤氡气和分量化探联合测量的工作方法,通过圈定氡浓度异常,铀分量异常,同时对分量元素进行相关性分析、R型聚类分析等,提取与铀成矿相关信息,结合伽马能谱测量结果预测深部铀成矿潜力,并进行钻探揭露验证。结果显示,氡浓度异常与铀分量异常复合区深部存在工业铀矿化,经分量化探元素R型聚类、异常特征分析,揭示U-Mo-Se-V-Ag-P分量异常组合可以作为研究区铀矿勘查的地球化学标志。表明土壤氡气和分量化探联合测量对于碳硅泥岩型铀矿深部预测具有有效性和可行性,为今后碳硅泥岩型铀矿勘查提供新的方法组合。

The Comparison of Contents of Malondialdehyde and Proline in the Area of Karst Area in Northweastern Guangxi Province

[Objective] To select excellent pioneer species of better ecological and economical comprehensive benefits from the common rock hill plants in Karst area in northwestern Guangxi Province.[Method] Determine the contents of malondialdehyde and proline in leaves of 65 strains of plants by thiobarbituric acid method and sultosalicylic acid method,analyze the relevance of the contents of malondialdehyde and proline by mathematics statistics and analyze the 65 kinds of rock hill plants by clustering [Result] The contents of malondialdehyde and proline are 0.005 2-0.038 1 μmol/g.There are comparably significant differences in the contents of malondialdehyde in different plants;The determination of proline contents in plant＇s leaves are 4.347-374.956 μg/ml.There are also significant differences in proline of different leaves of rock hill plants.The contents of malondialdehyde and proline can be used as a reference point in selecting pioneer plants in Karst area.But when we select the pioneer plants,not only the biological characters of the species themselves should be taken into consideration,but also the differences of Karst area environment,ecological and biological benefits and the reasonable distribution of species.[Conclusion] Pistacia chinensis,Zenia insignis,Acacia confusa,Itoa orientalis and Sophora japonica can be used as the first choices of excellent pioneer plants in Karst area in northwestern area which comparably consists with the real situation of afforestation of rock hills and recovery of plants in Guangxi.

Mantle plume activity and melting conditions： Evidence from olivines in picritic-komatiitic rocks from the Emeishan Large Igneous Province, southwestern China

Olivine phenocryst compositions and whole-rock chemical compositions are used to identify primitive picrite basalts from the early part of flood basalt successions in the western part of the Emeishan large igneous province （ELIP）, southwestern China. The Fo contents of olivine phenocrysts of komatiites with MgO-21.79 wt% range from 85.2% to 91.4%. The composition of unerupted parental melts is calculated from the compositions of the most Fo-rich olivine phenocrysts. These melts had -22 wt% MgO, and originated in mantle with a potential temperature of -1600℃ and at about 4.2 GPa pressure, supporting the conclusion that the generation of ELIP can be attributed to melting of a plume head beginning at -138 km depth.

Effect analysis of borehole microseismic monitoring technology on shale gas fracturing in western Hubei

Hydraulic fracturing technology is an important means of shale gas development,and microseismic monitoring is the key technology of fracturing effect evaluation.In this study,hydraulic fracturing and microseismic monitoring were simultaneously conducted in the Eyangye 2HF well(hereinafter referred to as EYY2HF well).The target stratum of this well is the second member of the Doushantuo Formation of the Sinian System,which is the oldest stratum of horizontal shale gas wells in the world.A total of 4341 microseismic fracturing events were identified,and 23 fracturing stages of the well were defined.The fluctuation of the number of events showed a repeating“high-low”pattern,and the average energy of these events showed minimal differences.These findings indicate that the water pressure required for the reconstruction of the EYY2HF well is appropriate.The main body of the fracture network extended from northwest to southeast,consistent with the interpretation of regional geological and seismic data.The stimulated rock volumes showed a linear increase with the increase of the fracturing stage.Some technological measures,such as quick lift displacement,quick lift sand ratio,and pump stop for secondary sand addition,were adopted during fracturing to increase the complexity of the fracture network.Microseismic fracture monitoring of the well achieved expected eff ects and guided real-time fracturing operations and fracturing eff ect evaluation.

Rehabilitation and Sustainable Use Pattern of Rocky-desertified Land in Southwest China’s Poverty-stricken Karst Mountainous Areas——A Case Study in Benggu Township, Xichou County, Yunnan, China

The rocky desert in a karst area directly causes the lack of soil, water and forest, hence leading to the poverty there. In 1990, the villagers from the Muzhe Village in Benggu Township, Xichou County, Yunnan declared a war against rocky desert in an attempt to ask the fields for more yields. They invented a distinctive land rehabilitation and sustainable use pattern called “transforming heavenand earth” that had been practiced in Southwest China’s karst areas. The key mechanism of the pattern was to develop terraced fields with well conserved soil, water and fertility by exploding rocks in the fields, building stone walls, gathering more soil, and improving soil quality and productivity for the fields in combination with building of irrigation facilities and roads, as well as with forestation and agriculture structure adjustment. The purpose of the pattern was to alleviate poverty in the karst areas by improving soil productivity and promoting agriculturaldevelopment. A typical area was studied with the help of Participatory Rural Appraisal (PRA) and the pattern was carried out there for fifteen years, have produced excellent ecological benefits and good economic benefits. Its application in the area approved that it was a sustainable land use pattern for rocky desert areas.

Study of oxygen fugacity during magma evolution and ore genesis in the Hongge mafic–ultramafic intrusion, the Panxi region, SW China

Economic concentrations of Fe–Ti oxides occurring as massive layers in the middle and upper parts of the Hongge intrusion are different from other layered intrusions(Panzhihua and Baima) in the Emeishan large igneous province, SW China. This paper reports on the new mineral compositions of magnetite and ilmenite for selected cumulate rocks and clinopyroxene and plagioclase for basalts. We use these data to estimate the oxidation state of parental magmas and during ore formation to constrain the factors leading to the abundant accumulation of Fe–Ti oxides involved with the Hongge layered intrusion. The results show that the oxygen fugacities of parental magma are in the range of FMQ-1.56 to FMQ+0.14, and the oxygen fugacities during the ore formation of the Fe–Ti oxides located in the lower olivine clinopyroxenite zone(LOZ) and the middle clinopyroxenite zone(MCZ) of the Hongge intrusion are in the range of FMQ-1.29 to FMQ-0.2 and FMQ-0.49 to FMQ+0.82, respectively.The MELTS model demonstrates that, as the oxygen fugacity increases from the FMQ-1 to FMQ+1, the proportion of crystallization magnetite increases from 11 % to 16 % and the crystallization temperature of the Fe–Ti oxides advances from 1134 to 1164 °C. The moderate oxygen fugacities for the Hongge MCZ indicate that the oxygen fugacity was not the only factor affecting the crystallization of Fe–Ti oxides. We speculated that theinitial anhydrous magma that arrived at the Hongge shallow magma chamber became hydrous by attracting the H_2O of the strata. In combination with increasing oxygen fugacities from the LOZ(FMQ-1.29 to FMQ-0.2) to the MCZ(FMQ-0.49 to FMQ+0.82), these two factors probably account for the large-scale Fe–Ti oxide ore layers in the MCZ of the Hongge intrusion.

Failure precursor of surrounding rock mass around cross tunnel in high-steep rock slope

The stability of the surrounding rock mass around cross tunnel in the right bank slope of Dagangshan hydropower station, in the southwestern China, was analyzed by microseismic monitoring as well as numerical simulations. The realistic failure process analysis code （abbreviated as RFPA3D） was employed to reproduce the initiation, propagation, coalescence and interactions of micro-fractures, the evolution of associated stress fields and acoustic emission （AE） activities during the whole failure processes of the surrounding rock mass around cross tunnel. Combined with microseismic activities by microseismic monitoring on the fight bank slope, the spatial-temporal evolution and the micro-fracture precursor characteristics during the complete process of progressive failure of the surrounding rock mass around cross tunnel were discussed and the energy release law of the surrounding rock mass around the cross tunnel was obtained. The result shows that the precursor characteristic of microfractures occurring in rock mass is an effective approach to early warn catastrophic damage of rock mass around cross tunnel. Moreover, the heterogeneity of rock mass is the source and internal cause of the failure precursor of rock mass.

Relationship between the Classification of Rock Surrounding Underground Chambers and the Initial Damage Variations in Rock Masses

On the basis of the relationship between each classification index for underground chambers and the elastic wave velocity of rock mass, a corresponding relationship between the classification of rock surrounding underground chambers and the initial damage variable is established by using the wave velocity definition of the initial damage variable of rock masses. Calculation and analysis of relevant data from a hydropower dam located in Southwest China show that the initial damage variable obtained by means of surrounding rock classification has a close relationship with that calculated by wave velocity, which verifies the rationality of the relationship of the two classification indices. This study establishes a foundation for further damage mechanics and stability analysis on the basis of surrounding rock classification.

Sources and control factors of rare earth elements in Late Permian mudstones,Southwest China

The material sources and control factors of rare earth elemems （REEs） for 25 borehole bulk samples from the Late Permian Longtan Formation in Mount Huaying （borehole number： ZK10-6）, Sichuan Province, South China, were investigated. All samples were determined by inductively coupled plasma mass spectrometry （ICP-MS）. The chondrite-normalized distribution patterns of mudstone samples are uniform. All samples belong to the light rare earth element （LREE）-rich type and are enriched in LREEs relative to heavy rare earth elements （HREEs）. The distribution curves of REEs in mudstone are highly similar to Mount Emei basalt and the three periods of REEs enrichment correspond to three Mount Emei basalt eruption cycles in Longtan period. The results indicate that REE patterns are not controlled by materials from the seawater or land plants. The predominant sources of REEs are from terrigenous material as indicated by negative Eu anomaly. So, the sources of REEs are controlled by terrigenous material, and the Mount Emei basalt is the predominant source of terrigenous material. Thus, transgression-regression is another control factor of REEs enrichment.

A New Occurrence of （Gold-Bearing） Graphite in the Assosa Region, BenishanguI-Gumuz State, W Ethiopia

The Assosa region of western Ethiopia hosts newly discovered and potentially highly economic graphite-bearing schist units. Due to its unique physical and chemical properties, graphite is quickly becoming an increasingly important economic resource. Graphite occurs over much of the area, and is hosted predominantly by quartz-graphitic schist, quartz-feldspar-mica schist and quartzite. The quartz-graphitic schist covers an area of 37 km2, forming steep valleys and ridges across a 190 km long belt. Graphite is texturally-variable within and across units. Crystal habit varies from highly crystalline to irregular flakes. Flake sizes range from amorphous and crystalline small flake to coarse large flake （〉 150 p.m）, with beneficiation of- 70% and yield potential of 〉 95% （froth flotation methods）. The license area is already a well-known gold-hosting area, and potentially economic gold deposits occur within the graphite-bearing units. Overall, the site shows excellent geochemical indicators, field observations and historical accounts of high gold content. It is suggested that textural variations may be the product of （1） early in-situ formation during （early- to late-Proterozoic） prograde metamorphism and （2） later vein-type mineralization during retrograde metamorphism. The discovery of graphite in western Ethiopia is the first documented and preliminary studies suggest a high economic potential for the deposits.

^(137)Cs Redistribution in Thin Stony Soil of a Carbonate Rock Slope in Southwest China

The fallout radionuclide cesium-137(137 Cs) has been widely employed as a tracer for assessment of soil loss from thick uniform soils;however,few studies have been conducted on thin stony soils on slopes underlain by carbonate rocks which are widely distributed in karst areas.Information derived from 137 Cs measurement of soil samples collected along a carbonate rock slope with thin stony soil where neither soil erosion nor deposition occurred was used to investigate the characteristics of 137 Cs redistribution in a karst area of Southwest China.The results indicated that the 137 Cs inventories of the surface soil on the slope studied were much lower than that of the local 137 Cs reference inventory and the 137 Cs activities were much higher than those on slopes with thick uniform soils.The spatial distribution of 137 Cs inventories was characterized by considerable variation.The high 137 Cs depletion in the stony soil of the slope studied was mainly because a considerable proportion of the fallout input of 137 Cs could be lost with runoff and the dissolution of carbonate particles in the soil promoted the loss of 137 Cs.These demonstrated that the rates of soil loss could not be estimated from the degree of depletion of the 137 Cs inventory relative to the local reference inventory for the thin stony soil of the rocky slope underlain by carbonate rocks in the study area in the way that has been widely used in areas with thick uniform soils.

A comparison study of tungsten-bearing granite and related mineralization in the northern Jiangxi-southern Anhui provinces and southern Jiangxi Province in South China

The southern Jiangxi Province(SJP) and northern Jiangxi-southern Anhui provinces(NJSAP) are the two most important tungsten metallogenic districts in South China. The SJP district is a well-known tungsten producer in South China where distributes several ore concentrated areas such as the "Chongyi-Dayu-Shangyou", "Yudu" and "Longnan-Quanan-Dingnan"areas, with many large and super large tungsten deposits including the famous Xihuashan, Piaotang, Pangushan and Dajishan deposits. In recent years, major prospecting breakthrough for W-polymetallic resources has been made in the NJSAP district.Several large and super large W-Cu(Mo) deposits, such as the Dahutang, Zhuxi, Dongyuan and Baizhangyan deposits, are discovered. These deposits are all genetically associated with the Yanshanian(Mesozoic) granitic magmatism. In this study, a systematic comparison of the temporal and spatial distribution, petrology, geochronology, and geochemical characteristics of the tungsten-bearing granites between the SJP and NJSAP districts has been made, with an aim to improving the understanding of the petrogenesis of the granites and associated metal enrichment mechanisms in the two tungsten ore districts in South China. The following conclusions can be drawn:(1) The ages of the tungsten-bearing granites and associated mineralization are different in the two districts, in the SJP district the ages are mainly concentrated in 165–150 Ma, whereas in the NJSAP district it displays two age periods, one is 150–140 Ma(Late Jurassic-Early Cretaceous), and the other is 135–120 Ma(Early Cretaceous).(2) The tungsten-bearing granites from both the NJSAP and SJP districts are highly fractionated granitic rocks, but the SJP granites have experienced higher degree of fractional crystallization and more extensive fluid metasomatism than the NJSAP granites.(3) The petrogeneses of the tungsten-bearing granites from the two districts are different, those from the NJSAP district originated from partial melting of less mature sandstone-mudstone intercalated with meta-volcanic rocks of the Neoproterozoic Shuangqiaoshan Group which are both W and Cu enriched, in contrast those from the SJP district were likely derived from the highly mature,clay-rich mudstones of the Mesoproterozoic age which are only W enriched. In summary, the different source rocks with different metal enrichment features and different magmatic evolution and fractional degrees for the granites in the two districts might be the key factors that controlled the different matallogenic characteristics of tungsten ore deposits in the two districts in South China.

Early Permian Tarim Large Igneous Province in northwest China

Tarim Large Igneous Province （TLIP） is the second Late Paleozoic LIPs in China after the recognition of Emeishan LIP, and is a hot research topic in geosciences. On the basis of the analysis of research history about TLIP, this paper summarizes the re- search result during last twenty years and suggests the key research area in the future. The residual distribution range of TLIP is up to 250000 km2, and the largest residual thickness is 780 m. The eruption of basalt happened during 290-288 Ma and be- longs to LIPs magmatic event with fast eruption of magma. The lithological units of the TLIP include basalt, diabase, layered intrusive rock, breccia pipe mica-olivine pyroxenite, olivine pyroxenite, gabbro, ultramafic dyke, quartz syenite, quartz syenite porphyry and bimodal dyke. The basalt and diabase of TLIP exhibit OIB-like trace element patterns and enrichment of LILE and HFSE, and mainly belong to high TiO2 series. There is an obvious difference in isotope among the basalt from Keping and the basalt and dibase from the northern Tarim Basin. The basalt from Keping with negative eNa and high REE value derives from enriched mantle, and the diabase and basalt from the northern Tarim Basin with positive ENa and low REE value axe re- lated to depleted mantle. The crust uplifting in the Early Permian and the development of picrite and large scale dyke and for- mation of large scale V-Ti-Magnetite deposit in Wajilitag area support the view that the TLIP is related to mantle plume. The TLIP has a temporal-spatial relationship with Permian basic to ultra-basic igneous rock, which is distributed widely in Central Asia, and they represent a tectono-magmatic event with very important geodynamic setting. This paper also suggests that the deep geological process, the relation with mantle plume, mineralization, the relation with environmental change and biological evolution, and the geodynamics of the TLIP will be the key research topics in the future.

The discovery of Palaeoproterozoic volcanic rocks in the Bulunkuoler Group from the Tianshuihai Massif in Xinjiang of Northwest China and its geological significance

In the Dabudaer region of the Tianshuihai Massif （Xinjiang, Northwest China）, metavolcanic rocks within the mainly meta- sedimentary Bulunkuoler Group are basalt, basaltic andesite, and rhyolite. In situ zircon U-Pb LA-ICP-MS dating on rhyolite magmatic zircons yielded an age of 2481±14 Ma, interpreted as the eruption age of the Bulunkuoler Group volcanic rocks. The basalt and basaltic andesite are low-A1 tholeiite series and the rhyolite is low-Al calc-alkaline series. All of rocks are charac- terized by enrichment of LREE and LILE （Rb, Th and Ba）, depletion of P, Nb, Ta and Ti, and absence of Eu anomalies. The Cnd（t） of basalts ranges from 3.14 to 4.88 indicating a depleted mantle source. The trace element signatures show that these magmas experienced intense crustal contamination during their ascent. Direct evidence for crustal contamination is the xenocrystic zircons in the ryholite, with ages back to ca. 3300 Ma. The primitive-mantle normalized and Zr/Y-Zr diagrams for the basic volcanic rocks show that they formed in an intra-continental tectonic setting. Combined with the previous studies and compared with North China Craton Neoarchean basic volcanic rocks, it is supposed that the Bulunkuoler Group volcanic rocks reflect the Palaeoproterozoic mantle magma underplating and interaction with felsic crust.

Peperites in the Permian Tarim large igneous province in Northwest China and their constraints on the local eruption environments

Peperites are special kinds of volcaniclastic materials generated by mingling of magma and unconsolidated sediments. They directly demonstrate the contemporaneity of volcanism and sedimentation, and hence they can be used to constrain the local paleoenvironments during volcanic eruptions. We identified peperites in the lower sequence of the northwest outcrops（Inggan-Kalpin area） of Permian Tarim large igneous province（TLIP）, Northwest China. In Inggan, blocky peperites were observed at the base of lava flows generated in the second eruption phase. This kind of peperites is generated by quenching of magma in a brittle fragmentation mechanism. While in Kalpin, both the second and the fourth eruption phases preserved peperites in the base of lava flows. Not only blocky but also fluidal peperites can be observed in Kalpin. The fluidal peperites were generated in vapor films, which insulated the magmas from cold sediments and avoided direct thermal shock, and therefore kept the fluidal forms of magma. All of these peperites are hosted by submarine carbonates. In lava sequences generated in the same eruption phases but located in Kaipaizileike, ~15 km east to Inggan, terrestrial flood basalts developed while peperites are absent, implying a paleoenvironmental transition between Kaipaizileike and Inggan-Kalpin area. Gathering information from observed peperites, TLIP lava flows, and the Lower Permian sedimentary strata, we precisely constrained the spatial distribution and temporal evolution of sedimentary facies of the early stage of TLIP. As a result, two marine transgressions were identified. The first transgression occurred contemporaneous with the second eruption phase. The transition from submarine to subaerial is located between Kaipaizileike and Inggan. The second transgression occurred contemporaneous with the forth eruption phase, and the transition from submarine to subaerial occurred between Inggan and Kalpin.

Differences in lithospheric structures between two sides of Taihang Mountain obtained from the Zhucheng-Yichuan deep seismic sounding profile

A 2-D model of lithospheric velocity structures in the southern part of the North China Craton was obtained using data from the Zhucheng-Yichuan deep seismic sounding profile.Results show that there are great differences in lithospheric structures between two sides of Taihang Mountain.In the eastern region,the lithosphere is thinner,with a thickness of about 70-80 km,while in the western region,the thickness is 85-120 km.There is a jump of the lithospheric thickness across Taihang Mountain gravity anomaly belt with a magnitude of about 30 km.P wave velocities of the lithospheric mantle and lower crust are lower in the eastern region and higher in the western region.In the eastern region,there are low velocity bodies in the middle and lower crust,while none were found in the western region.These differences indicate that the Taihang Mountain gravity anomaly belt is a belt with a abrupt change of lithospheric thickness and lithological composition.According to the Pm waveform,it can be deduced that the Moho in the eastern region is not a sharp discontinuity,but a complex transitional zone.From a preliminary analysis,it is found that the geothermal mechanical-chemical erosion could be the main mechanism causing the thinning and destruction of the lithosphere beneath the eastern side of Taihang Mountain.In addition,subduction of the Pacific Plate is an important factor which changes the properties of the lithospheric mantle of the North China Craton.

End-Guadalupian mass extinction and negative carbon isotope excursion at Xiaojiaba,Guangyuan,Sichuan

The end-Paleozoic biotic crisis is characterized by two-phase mass extinctions;the first strike,resulting in a large decline of sessile benthos in shallow marine environments,occurred at the end-Guadalupian time.In order to explore the mechanism of organisms' demise,detailed analyses of depositional facies,fossil record,and carbonate carbon isotopic variations were carried out on a Maokou-Wujiaping boundary succession in northwestern Sichuan,SW China.Our data reveal a negative carbon isotopic excursion across the boundary;the gradual excursion with relatively low amplitude(2.15‰) favors a long-term influx of isotopically light 12 C sourced by the Emeishan basalt trap,rather than by rapid releasing of gas hydrate.The temporal coincidence of the beginning of accelerated negative carbon isotopic excursion with onsets of sea-level fall and massive biotic demise suggests a cause-effect link between them.Intensive volcanic activity of the Emeishan trap and sea-level fall could have resulted in detrimental environmental stresses and habitat loss for organisms,particularly for those benthic dwellers,leading to their subsequent massive extinction.

Distinct sedimentary environments and their influences on carbonate reservoir evolution of the Lianglitag Formation in the Tarim Basin,Northwest China

The Upper Ordovician Lianglitag Formation carbonate rocks are important oil and gas reservoirs in the Tarim Basin, Northwest China, with obviously distinct reservoir properties among different oilfields. As a case area of the above carbonate reser- voirs correlation, Tahe and Tazhong oilfields are chosen for the study through an integrated analysis of biostratigraphic isoch- ronous framework, cores, thin sections, logs, and strontium isotopes. The research shows that the two areas were respectively attributed to different carbonate platforms during the Lianglitag Formation depositional phase. For the Lianglitag Formation, five fourth-order sequences may be divided in Tazhong, whereas only four fourth-order sequences are preserved in Tahe that correspond to the lower ones observed in Tazhong. The Lianglitag Formation carbonate platform in Tahe was characterized by ramp and/or weak rimmed types, with low depositional rates （37 ktm/a）, higher whole-rock clastic contents, and higher 878r/86Sr isotope ratios of carbonate matrix, showing relatively deep-water environment and evident terrigenous input for car- bonate deposition. However, a strongly rimmed carbonate platform was developed in Tazhong, with high depositional rates of 250 p.m/a and less whole-rock clastic contents, indicating a high-energy depositional environment. Because of the sedimentary environment differences mentioned above, less high-energy facies but relatively intense syndepositional （early diagenetic） sea-water cementation of carbonates were developed in Tahe, and ubiquitous high-energy reef and shoal facies, with a frequent exposure to subaerial, and weak syndepositional sea-water cementation of carbonates in Tazhong. Therefore, fewer primary pores occurred in the Lianglitag Formation carbonate rocks of Tahe, whereas more primary pores were preserved in the same lithostratigraphic unit of the Tazhong （No. 1 fault zone）. Available high-energy reef-shoal facies and early diagenesis, with more primary pores preserved, provided a key material basis for the Lianglitag Formation carbonate reservoirs that largely oc- curred in Tazhong.