ZnO/Znml2O4 nanocomposites with heteronanostructures were successfully prepared by co-precipitation method. The as-prepared samples were characterized by HRTEM, TEM, XRD, BET, TG-DTA, and UV-Vis spectra techniques. Th...ZnO/Znml2O4 nanocomposites with heteronanostructures were successfully prepared by co-precipitation method. The as-prepared samples were characterized by HRTEM, TEM, XRD, BET, TG-DTA, and UV-Vis spectra techniques. The photoeatalytic activities of the as-prepared samples were evaluated by the photocatalytic degradation of methyl orange and inactivation of Escherichia coli in suspension under the irradiation of the simulated sunlight. The effects of compositions, calcination temperatures, concentration ofphotocatalysts and light source on the photocatalytic activities were systematically studied. The results show that when the concentration of ZnO/ZnA1204 photocatalyst with the starting Zn to Al molar ratio of 1:1.5 calcined at 600 ℃ is 1.0 g/L, the maximum photocatalytic degradation rate of 98.5% can be obtained in 50 min under the irradiation of the simulated sunlight. Under the same conditions, an inactivation rate of 99.8% for E.coli is achieved in 60 min.展开更多
Magnetic anomalies are often disturbed by the magnetization direction, so we can't directly use the original magnetic anomaly to estimate the exact location and geometry of the source. The 2D analytic signal is insen...Magnetic anomalies are often disturbed by the magnetization direction, so we can't directly use the original magnetic anomaly to estimate the exact location and geometry of the source. The 2D analytic signal is insensitive to magnetization direction. In this paper, we present an automatic method based on the analytic signal horizontal and vertical derivatives to interpret the magnetic anomaly. We derive a linear equation using the analytic signal properties and we obtain the 2D magnetic body location parameters without giving a priori information. Then we compute the source structural index (expressing the geometry) by the estimated location parameters. The proposed method is demonstrated on synthetic magnetic anomalies with noise. For different models, the proposed technique can both successfully estimate the location parameters and the structural index of the sources and is insensitive to noise. Lastly, we apply it to real magnetic anomalies from China and obtain the distribution of unexploited iron ore. The inversion results are consistent with the parameters of known ore bodies.展开更多
With the significant discharge of antibiotic wastewater into the aquatic and terrestrial ecosystems, antibiotic pollution has become a serious problem and presents a hazardous risk to the environment. To address such ...With the significant discharge of antibiotic wastewater into the aquatic and terrestrial ecosystems, antibiotic pollution has become a serious problem and presents a hazardous risk to the environment. To address such issues, various investigations on the removal of antibiotics have been undertaken. Photocatalysis has received tremendous attention owing to its great potential in removing antibiotics from aqueous solutions via a green, economic, and effective process. However, such a technology employing traditional photocatalysts suffers from major drawbacks such as light absorption being restricted to the UV spectrum only and fast charge recombination. To overcome these issues, considerable effort has been directed towards the development of advanced visible light-driven photocatalysts. This mini review summarises recent research progress in the state-of-the-art design and fabrication of photocatalysts with visible-light response for photocatalytic degradation of antibiotic wastewater. Such design strategies involve the doping of metal and non-metal into ultraviolet light-driven photocatalysts, development of new semiconductor photocatalysts, construction of heterojunction photocatalysts, and fabrication of surface plasmon resonance-enhanced photocatalytic systems. Additionally, some perspectives on the challenges and future developments in the area of photocatalytic degradation of antibiotics are provided.展开更多
The method of regularization factor selection determines stability and accuracy of the regularization method. A formula of regularization factor was proposed by analyzing the relationship between the improved SVD and ...The method of regularization factor selection determines stability and accuracy of the regularization method. A formula of regularization factor was proposed by analyzing the relationship between the improved SVD and regularization method. The improved SVD algorithm and regularization method could adapt to low SNR. The regularization method is better than the improved SVD in the case that SNR is below 30 and the improved SVD is better than the regularization method when SNR is higher than 30. The regularization method with the regularization factor proposed in this paper can be better applied into low SNR (5〈SNR) NMR logging. The numerical simulations and real NMR data process results indicated that the improved SVD algorithm and regularization method could adapt to the low signal to noise ratio and reduce the amount of computation greatly. These algorithms can be applied in NMR logging.展开更多
A new digital watermarking algorithm based on the contourlet transform is proposed to improve the robustness and anti-attack performances of digital watermarking. The algorithm uses the Arnold scrambling technique and...A new digital watermarking algorithm based on the contourlet transform is proposed to improve the robustness and anti-attack performances of digital watermarking. The algorithm uses the Arnold scrambling technique and the singular value decomposition (SVD) scheme. The Arnold scrambling technique is used to preprocess the watermark, and the SVD scheme is used to find the best suitable hiding points. After the contourlet transform of the carrier image, intermediate frequency sub-bands are decomposed to obtain the singularity values. Then the watermark bits scrambled in the Arnold rules are dispersedly embedded into the selected SVD points. Finally, the inverse contourlet transform is applied to obtain the carrier image with the watermark. In the extraction part, the watermark can be extracted by the semi-blind watermark extracting algorithm. Simulation results show that the proposed algorithm has better hiding and robustness performances than the traditional contourlet watermarking algorithm and the contourlet watermarking algorithm with SVD. Meanwhile, it has good robustness performances when the embedded watermark is attacked by Gaussian noise, salt- and-pepper noise, multiplicative noise, image scaling and image cutting attacks, etc. while security is ensured.展开更多
A series of WO3 samples with different crystalline phases were prepared by the thermal decomposition method from ammonium tungstate hydrate.X-ray diffraction(XRD),scanning electron microscopy(SEM),high-resolution ...A series of WO3 samples with different crystalline phases were prepared by the thermal decomposition method from ammonium tungstate hydrate.X-ray diffraction(XRD),scanning electron microscopy(SEM),high-resolution transmission electron microscopy(HRTEM),X-ray photoelectron spectroscopy,and N2 adsorption-desorption were used to characterize the crystalline phase,morphology,particle size,chemical composition,and surface area of the WO3 samples.The formation of hexagonal(h-WO3) and monoclinic(m-WO3) crystal structures of WO3 at different temperatures or different times was confirmed by XRD.m-WO3 is formed at 600 ℃,while m-WO3 starts to transform into h-WO3 at 800℃.However,h-WO3,which forms at 800℃,may transform into m-WO3 by increasing the calcination temperature to 1000℃.SEM results indicate that m-WO3 particles exhibit a bulky shape with heavy aggregates,while h-WO3 particles exhibit a rod-like shape.Moreover,m-WO3 crystals are sporadically patched on the surface of the h-WO3 rod-like particles,resulting in the exposure of both m-WO3 and h-WO3 on the surface.It is observed that the monoclinic phase(m-WO3)/hexagonal phase(h-WO3) junction was fabricated by tuning the calcination temperature and calcination time.The relative ratios between m-WO3 and h-WO3 in the phase junction can readily be tailored by control of the calcination time.The photocatalytic activities of WO3 with different crystalline phases were evaluated by the photocatalytic degradation of rhodamine B as a model pollutant.A higher photocatalytic activity was observed in the WO3 sample with the m-WO3/h-WO3junction as compared with the sample with only m-WO3.The improvement of photocatalytic activity can be attributed to the reduction of the electron-hole recombination rate owing to the formation of the phase junction,whose presence has been confirmed by HRTEM and photoluminescence spectra.展开更多
During transient electromagnetic method (TEM) exploration of a copper mine, we detected the late-channel TEM signal reversal phenomenon (a voltage change from positive to negative) caused by the influence of the i...During transient electromagnetic method (TEM) exploration of a copper mine, we detected the late-channel TEM signal reversal phenomenon (a voltage change from positive to negative) caused by the influence of the induced polarization (IP) effect, which affects the depth and precision of the TEM detection. The conventional inversion method is inefficient because it is difficult to process the data. In this paper, the Cole-Cole model is adopted to analyze the effect of Dc resistivity, chargeability, time constant, and frequency exponent on the TEM response in an homogeneous half space model. Singular Value Decomposition (SVD) is used to invert the measured TEM data, and the Dc resistivity, chargeability, time constant and frequency exponent were extracted from the measured TEM data in the mine area. The extracted parameters are used for interpreting the detection result as a supplement. This reveals why the TEM data acquired in the area has a low resolution. It was found that the DC resistivity and time constant do not significantly change the results, however, the chargeability and frequency exponent have a significant effect. Because of these influences, the SVD method is more accurate than the conventional method in the apparent resistivity profile. The area of the copper mine is confined accurately based on the SVD inverted data. The conclusion has been verified by drill and is identical to the practical geological situation.展开更多
Anodic dissolutionbehaviorof zirconium inBu^n 4NBr-contaningisopropanol solution was investigated using cyclic voltammetry, linear sweep voltammetry and chronoamperometry, complemented with a scanning electron microsc...Anodic dissolutionbehaviorof zirconium inBu^n 4NBr-contaningisopropanol solution was investigated using cyclic voltammetry, linear sweep voltammetry and chronoamperometry, complemented with a scanning electron microscope (SEM).The voltammograms did not exhibit active dissolutionuntil the breakdown of passive layer induced by aggressive bromide anions.SEM images confirmed the existence of pits on zirconium surface.The depth and breadth of pits were intensified with increasing potential. The pitting potentialshifted negatively as either temperature orBu^n 4NBr concentration was increased, while it increased with increasing scan rate.The corrosion current density increased with increasing temperature. The apparent activation energyof anodic dissolutionofzirconiumwas 21.88kJ/mol. The chronoamperometry revealed that increasingBu^n 4NBrconcentration shortened the incubation time for passivity breakdown and accelerated the pit nucleation and growth. The experimental results were helpfulto obtain the optimum conditions for electrosynthesis of zirconium isopropoxide.展开更多
A model updating optimization algorithm under quadratic constraints is applied to structure dynamic model updating. The updating problems of structure models are turned into the optimization with a quadratic constrain...A model updating optimization algorithm under quadratic constraints is applied to structure dynamic model updating. The updating problems of structure models are turned into the optimization with a quadratic constraint. Numerical method is presented by using singular value decomposition and an example is given. Compared with the other method, the method is efficient and feasible.展开更多
Aimed at studying normali zed radial basis function network (NRBFN), this paper introduces the subtractiv e clustering based on a mountain function to construct the initial structure of NR BFN, adopts singular value ...Aimed at studying normali zed radial basis function network (NRBFN), this paper introduces the subtractiv e clustering based on a mountain function to construct the initial structure of NR BFN, adopts singular value decomposition (SVD) to analyze the relationship betwe en neural nodes of the hidden layer and singular values, cumulative contribution ratio, index vector, and optimizes the structure of NRBFN. Finally, simulation and performance comparison show that the algorithm is feasible and effective.展开更多
Finding solutions of matrix equations in given set SR n×n is an active research field. Lots of investigation have done for these cases, where S are the sets of general or symmetric matrices and symmetric posit...Finding solutions of matrix equations in given set SR n×n is an active research field. Lots of investigation have done for these cases, where S are the sets of general or symmetric matrices and symmetric positive definite or sysmmetric semiposite definite matrices respectively . Recently, however, attentions are been paying to the situation for S to be the set of general(semi) positive definite matrices(called as semipositive subdefinite matrices below) . In this paper the necessary and sufficient conditions for the following two kinds of matrix equations having semipositive, subdefinite solutions are obtained. General solutions and symmetric solutions of the equations (Ⅰ) and (Ⅱ) have been considered in in detail.展开更多
The solubility of natural hemimorphite in ammonium sulfate solution was measured by isothermal solution method at 25 °C and the dissolved residue of hemimorphite was investigated by X-ray powder diffraction (XRD...The solubility of natural hemimorphite in ammonium sulfate solution was measured by isothermal solution method at 25 °C and the dissolved residue of hemimorphite was investigated by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) methods. The results show that zinc and silica in hemimorphite simultaneously dissolve in ammonium sulfate solution. The solubility of zinc in solution increases rapidly from 4.5381 mmol/kg in 0.5469 mol/kg ammonium sulfate solution to 11.5083 mmol/kg in 3.7038 mol/kg ammonium sulfate solution. The solubility of silica in solution increases slowly from 2.5509 mmol/kg in 0.5469 mol/kg ammonium sulfate solution to 7.2891 mmol/kg in 3.7038 mol/kg ammonium sulfate solution. The dissolved residue is the characteristic of hemimorphite Zn4Si2O7(OH)2·H2O based on the results of the XRD, SEM and FTIR. Thus, no phase transition occurs in the dissolution process of hemimorphite in ammonium sulfate solution.展开更多
基金Project(21271071)supported by the National Natural Science Foundation of ChinaProject(21306041)supported by the National Natural Science Young Foundation of China
文摘ZnO/Znml2O4 nanocomposites with heteronanostructures were successfully prepared by co-precipitation method. The as-prepared samples were characterized by HRTEM, TEM, XRD, BET, TG-DTA, and UV-Vis spectra techniques. The photoeatalytic activities of the as-prepared samples were evaluated by the photocatalytic degradation of methyl orange and inactivation of Escherichia coli in suspension under the irradiation of the simulated sunlight. The effects of compositions, calcination temperatures, concentration ofphotocatalysts and light source on the photocatalytic activities were systematically studied. The results show that when the concentration of ZnO/ZnA1204 photocatalyst with the starting Zn to Al molar ratio of 1:1.5 calcined at 600 ℃ is 1.0 g/L, the maximum photocatalytic degradation rate of 98.5% can be obtained in 50 min under the irradiation of the simulated sunlight. Under the same conditions, an inactivation rate of 99.8% for E.coli is achieved in 60 min.
基金supported by the Special Investigation and Assessment of Geological Mineral Resources of the China Geological Survey(No.GZH003-07-03)
文摘Magnetic anomalies are often disturbed by the magnetization direction, so we can't directly use the original magnetic anomaly to estimate the exact location and geometry of the source. The 2D analytic signal is insensitive to magnetization direction. In this paper, we present an automatic method based on the analytic signal horizontal and vertical derivatives to interpret the magnetic anomaly. We derive a linear equation using the analytic signal properties and we obtain the 2D magnetic body location parameters without giving a priori information. Then we compute the source structural index (expressing the geometry) by the estimated location parameters. The proposed method is demonstrated on synthetic magnetic anomalies with noise. For different models, the proposed technique can both successfully estimate the location parameters and the structural index of the sources and is insensitive to noise. Lastly, we apply it to real magnetic anomalies from China and obtain the distribution of unexploited iron ore. The inversion results are consistent with the parameters of known ore bodies.
基金supported by the National Natural Science Foundation of China(21421001,21276116,21477050,21301076,21303074)Natural Science Foundation of Jiangsu Province(BK20140530,BK20150482)+5 种基金China Postdoctoral Science Foundation(2015M570409)Chinese-German Cooperation Research Project(GZ1091)Program for High-Level Innovative and Entrepreneurial Talents in Jiangsu ProvinceProgram for New Century Excellent Talents in University(NCET-13-0835)Henry Fok Education Foundation(141068)Six Talents Peak Project in Jiangsu Province(XCL-025)~~
文摘With the significant discharge of antibiotic wastewater into the aquatic and terrestrial ecosystems, antibiotic pollution has become a serious problem and presents a hazardous risk to the environment. To address such issues, various investigations on the removal of antibiotics have been undertaken. Photocatalysis has received tremendous attention owing to its great potential in removing antibiotics from aqueous solutions via a green, economic, and effective process. However, such a technology employing traditional photocatalysts suffers from major drawbacks such as light absorption being restricted to the UV spectrum only and fast charge recombination. To overcome these issues, considerable effort has been directed towards the development of advanced visible light-driven photocatalysts. This mini review summarises recent research progress in the state-of-the-art design and fabrication of photocatalysts with visible-light response for photocatalytic degradation of antibiotic wastewater. Such design strategies involve the doping of metal and non-metal into ultraviolet light-driven photocatalysts, development of new semiconductor photocatalysts, construction of heterojunction photocatalysts, and fabrication of surface plasmon resonance-enhanced photocatalytic systems. Additionally, some perspectives on the challenges and future developments in the area of photocatalytic degradation of antibiotics are provided.
文摘The method of regularization factor selection determines stability and accuracy of the regularization method. A formula of regularization factor was proposed by analyzing the relationship between the improved SVD and regularization method. The improved SVD algorithm and regularization method could adapt to low SNR. The regularization method is better than the improved SVD in the case that SNR is below 30 and the improved SVD is better than the regularization method when SNR is higher than 30. The regularization method with the regularization factor proposed in this paper can be better applied into low SNR (5〈SNR) NMR logging. The numerical simulations and real NMR data process results indicated that the improved SVD algorithm and regularization method could adapt to the low signal to noise ratio and reduce the amount of computation greatly. These algorithms can be applied in NMR logging.
基金The National Natural Science Foundation of China( No. 69092008)
文摘A new digital watermarking algorithm based on the contourlet transform is proposed to improve the robustness and anti-attack performances of digital watermarking. The algorithm uses the Arnold scrambling technique and the singular value decomposition (SVD) scheme. The Arnold scrambling technique is used to preprocess the watermark, and the SVD scheme is used to find the best suitable hiding points. After the contourlet transform of the carrier image, intermediate frequency sub-bands are decomposed to obtain the singularity values. Then the watermark bits scrambled in the Arnold rules are dispersedly embedded into the selected SVD points. Finally, the inverse contourlet transform is applied to obtain the carrier image with the watermark. In the extraction part, the watermark can be extracted by the semi-blind watermark extracting algorithm. Simulation results show that the proposed algorithm has better hiding and robustness performances than the traditional contourlet watermarking algorithm and the contourlet watermarking algorithm with SVD. Meanwhile, it has good robustness performances when the embedded watermark is attacked by Gaussian noise, salt- and-pepper noise, multiplicative noise, image scaling and image cutting attacks, etc. while security is ensured.
基金supported by the National Natural Science Foundation of China (21573101)the Liaoning Provincial Natural Science Foundation(2014020107)+2 种基金the Program for Liaoning Excellent Talents in University (LJQ2014041)the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry ([2013]1792)the Opening Project of Key Laboratory of Photochemical Conversion and Optoelectronic Materials, TIPC, CAS,the Opening Project of State Key Laboratory of Catalysis, DICP, CAS (N-09-06)~~
文摘A series of WO3 samples with different crystalline phases were prepared by the thermal decomposition method from ammonium tungstate hydrate.X-ray diffraction(XRD),scanning electron microscopy(SEM),high-resolution transmission electron microscopy(HRTEM),X-ray photoelectron spectroscopy,and N2 adsorption-desorption were used to characterize the crystalline phase,morphology,particle size,chemical composition,and surface area of the WO3 samples.The formation of hexagonal(h-WO3) and monoclinic(m-WO3) crystal structures of WO3 at different temperatures or different times was confirmed by XRD.m-WO3 is formed at 600 ℃,while m-WO3 starts to transform into h-WO3 at 800℃.However,h-WO3,which forms at 800℃,may transform into m-WO3 by increasing the calcination temperature to 1000℃.SEM results indicate that m-WO3 particles exhibit a bulky shape with heavy aggregates,while h-WO3 particles exhibit a rod-like shape.Moreover,m-WO3 crystals are sporadically patched on the surface of the h-WO3 rod-like particles,resulting in the exposure of both m-WO3 and h-WO3 on the surface.It is observed that the monoclinic phase(m-WO3)/hexagonal phase(h-WO3) junction was fabricated by tuning the calcination temperature and calcination time.The relative ratios between m-WO3 and h-WO3 in the phase junction can readily be tailored by control of the calcination time.The photocatalytic activities of WO3 with different crystalline phases were evaluated by the photocatalytic degradation of rhodamine B as a model pollutant.A higher photocatalytic activity was observed in the WO3 sample with the m-WO3/h-WO3junction as compared with the sample with only m-WO3.The improvement of photocatalytic activity can be attributed to the reduction of the electron-hole recombination rate owing to the formation of the phase junction,whose presence has been confirmed by HRTEM and photoluminescence spectra.
基金supported by the National Technology R&D Program in the 11th Five year Plan of China(No.2007BAQ00168-1-1)the National Natural Science Foundation of China(No. 41103052/D0309)the Shanxi Province Excellent Graduate Innovation Program(No. 20113038)
文摘During transient electromagnetic method (TEM) exploration of a copper mine, we detected the late-channel TEM signal reversal phenomenon (a voltage change from positive to negative) caused by the influence of the induced polarization (IP) effect, which affects the depth and precision of the TEM detection. The conventional inversion method is inefficient because it is difficult to process the data. In this paper, the Cole-Cole model is adopted to analyze the effect of Dc resistivity, chargeability, time constant, and frequency exponent on the TEM response in an homogeneous half space model. Singular Value Decomposition (SVD) is used to invert the measured TEM data, and the Dc resistivity, chargeability, time constant and frequency exponent were extracted from the measured TEM data in the mine area. The extracted parameters are used for interpreting the detection result as a supplement. This reveals why the TEM data acquired in the area has a low resolution. It was found that the DC resistivity and time constant do not significantly change the results, however, the chargeability and frequency exponent have a significant effect. Because of these influences, the SVD method is more accurate than the conventional method in the apparent resistivity profile. The area of the copper mine is confined accurately based on the SVD inverted data. The conclusion has been verified by drill and is identical to the practical geological situation.
基金Project(51374254)supported by the National Natural Science Foundation of ChinaProject(2013JSJJ026)supported by the Teacher Research Foundation of Central South University,China
文摘Anodic dissolutionbehaviorof zirconium inBu^n 4NBr-contaningisopropanol solution was investigated using cyclic voltammetry, linear sweep voltammetry and chronoamperometry, complemented with a scanning electron microscope (SEM).The voltammograms did not exhibit active dissolutionuntil the breakdown of passive layer induced by aggressive bromide anions.SEM images confirmed the existence of pits on zirconium surface.The depth and breadth of pits were intensified with increasing potential. The pitting potentialshifted negatively as either temperature orBu^n 4NBr concentration was increased, while it increased with increasing scan rate.The corrosion current density increased with increasing temperature. The apparent activation energyof anodic dissolutionofzirconiumwas 21.88kJ/mol. The chronoamperometry revealed that increasingBu^n 4NBrconcentration shortened the incubation time for passivity breakdown and accelerated the pit nucleation and growth. The experimental results were helpfulto obtain the optimum conditions for electrosynthesis of zirconium isopropoxide.
文摘A model updating optimization algorithm under quadratic constraints is applied to structure dynamic model updating. The updating problems of structure models are turned into the optimization with a quadratic constraint. Numerical method is presented by using singular value decomposition and an example is given. Compared with the other method, the method is efficient and feasible.
文摘Aimed at studying normali zed radial basis function network (NRBFN), this paper introduces the subtractiv e clustering based on a mountain function to construct the initial structure of NR BFN, adopts singular value decomposition (SVD) to analyze the relationship betwe en neural nodes of the hidden layer and singular values, cumulative contribution ratio, index vector, and optimizes the structure of NRBFN. Finally, simulation and performance comparison show that the algorithm is feasible and effective.
文摘Finding solutions of matrix equations in given set SR n×n is an active research field. Lots of investigation have done for these cases, where S are the sets of general or symmetric matrices and symmetric positive definite or sysmmetric semiposite definite matrices respectively . Recently, however, attentions are been paying to the situation for S to be the set of general(semi) positive definite matrices(called as semipositive subdefinite matrices below) . In this paper the necessary and sufficient conditions for the following two kinds of matrix equations having semipositive, subdefinite solutions are obtained. General solutions and symmetric solutions of the equations (Ⅰ) and (Ⅱ) have been considered in in detail.
基金Foundation item:Project(2007CB613601)supported by the National Basic Research and Development Program of ChinaProject(511340071)supported by the National Natural Science Foundation of China
文摘The solubility of natural hemimorphite in ammonium sulfate solution was measured by isothermal solution method at 25 °C and the dissolved residue of hemimorphite was investigated by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) methods. The results show that zinc and silica in hemimorphite simultaneously dissolve in ammonium sulfate solution. The solubility of zinc in solution increases rapidly from 4.5381 mmol/kg in 0.5469 mol/kg ammonium sulfate solution to 11.5083 mmol/kg in 3.7038 mol/kg ammonium sulfate solution. The solubility of silica in solution increases slowly from 2.5509 mmol/kg in 0.5469 mol/kg ammonium sulfate solution to 7.2891 mmol/kg in 3.7038 mol/kg ammonium sulfate solution. The dissolved residue is the characteristic of hemimorphite Zn4Si2O7(OH)2·H2O based on the results of the XRD, SEM and FTIR. Thus, no phase transition occurs in the dissolution process of hemimorphite in ammonium sulfate solution.