Departing from an analytical phase transformation model, a new analytical approach to deduce transformed fraction for non-isothermal phase transformation was developed. In the new approach, the effect of the initial t...Departing from an analytical phase transformation model, a new analytical approach to deduce transformed fraction for non-isothermal phase transformation was developed. In the new approach, the effect of the initial transformation temperature and the accurate "temperature integral" approximations are incorporated to obtain an extended analytical model. Numerical approach demonstrated that the extended analytical model prediction for transformed fraction and transformation rate is in good agreement with the exact numerical calculation. The new model can describe more precisely the kinetic behavior than the original analytical model, especially for transformation with relatively high initial transformation temperature. The kinetic parameters obtained from the new model are more accurate and reasonable than those from the original analytical model.展开更多
Bi0.9La0.1Fe0.95Mn0.05O3 (BLFMO) ferroelectric thin films were fabricated on Pt/Ti/SiO2/Si/ substrates by the sol-gel process at different pyrolysis temperatures. The mass loss of BLFMO powder was investigated by th...Bi0.9La0.1Fe0.95Mn0.05O3 (BLFMO) ferroelectric thin films were fabricated on Pt/Ti/SiO2/Si/ substrates by the sol-gel process at different pyrolysis temperatures. The mass loss of BLFMO powder was investigated by thermo gravimetry analyser (TGA), and the polycrystalline structure and smooth surface of BLFMO thin films were characterized by X-ray diffraction (XRD) and atomic force microscopy (AFM), respectively. The remnant polarization (Pr) of the BLFMO films pyrolyzed at 420 ℃ is 21.2 μC/cm2 at the coercive field (Ec) of 99 kV/cm and the leakage current density is 7.1×10-3 A/cm2, which indicates that the BLFMO thin films display relatively good ferroelectric property at this temperature.展开更多
An exact solution for simply-supported laminated beams with material properties variable with temperature under a combination of uniform thermo-load and mechanical loads was investigated,based on the two-dimensional(2...An exact solution for simply-supported laminated beams with material properties variable with temperature under a combination of uniform thermo-load and mechanical loads was investigated,based on the two-dimensional(2-D)thermo-elasticity theory.Firstly,the beam was divided into a series of layers with uniform material properties along the interfaces of the beam.The uniform thermo-load acted on each layer was transformed into a combination of the normal surface forces acted at the two ends and the transverse thermo-load.Secondly,the state space method was employed to obtain the general solutions of displacements and stresses in an arbitrary layer.Thirdly,based on the interfacial continuity conditions between adjacent layers,the relations of displacement and stress components between the top and bottom layers of the beam were recursively derived by use of the transfer-matrix method.The unknowns in the solutions can be solved by the mechanical loads acted on the top and bottom surfaces.The convergence of the present solutions was checked.The comparative study of the present solutions with the Timoshenko’s solutions and the finite element(FE)solutions was carried out.The effects of material properties variable with temperature on the thermo-elastic behavior of laminated beams were discussed in detail.展开更多
In this work, the main characteristics of the Qingdao Cold Water Mass were studied by using "the comparison analysis method" based on 1980 temperature,salinity and dissolved oxygen data on the western South ...In this work, the main characteristics of the Qingdao Cold Water Mass were studied by using "the comparison analysis method" based on 1980 temperature,salinity and dissolved oxygen data on the western South Yellow Sea. The formation cause of the water mass was analyzed based on February of 1959 temperature and salinity data for this area and on some other authors’ studies. The results showed that the Qingdao Cold Water Mass has growing and vanishing processes: appears in the last ten days of March; has stable pattern in April; is biggest in its area in May; becomes small in its area in June; vanishes in July. It comes from the northern Shandong Coastal Water and is characterized by low temperature and salinity and high dissolved oxygen. The mass is formed under the joint effects of anticyclonic circulation and solar radiation.展开更多
This study is focused on a steady dissipative layer, which is generated by Marangoni convection flow over the surface resulted from an imposed temperature gradient, coupled with buoyancy effects due to gravity and ext...This study is focused on a steady dissipative layer, which is generated by Marangoni convection flow over the surface resulted from an imposed temperature gradient, coupled with buoyancy effects due to gravity and external pressure. A model is proposed with Marangoni condition in the boundary conditions at the interface. The similarity equations are determined and approximate analytical solutions are obtained by an efficient transformation, asymptotic expansion and Pade approximant technique. For the cases that buoyancy force is favorable or unfavor-able to Marangoni flow, the features of flow and temperature fields are investigated in terms of Marangoni mixed convection parameter and Prantl number.展开更多
The pyrolysis characteristics of Shendong Shangwan coal and its macerals concentrate were investigated using thermogravimetry (TG) coupled with mass spectrometry (MS). The evolved gases were analyzed online by MS ...The pyrolysis characteristics of Shendong Shangwan coal and its macerals concentrate were investigated using thermogravimetry (TG) coupled with mass spectrometry (MS). The evolved gases were analyzed online by MS spectroscopy. The results of TG/DTG (derivative thermogravimetry) show ths vitrinite concentrate has greater weight loss rate and higher volatile yield than the other two samples. More light hydrocarbons C1-C5 are released from the vitfinite concentrate than from the Shendong Shangwan coal and inertinite concentrated in the process of pyrolysis. Three samples have similar shape curves of evolved gases of C2~C5 with different intensities. When the pyrolysis temperature was lower than 418℃, the amount of C6H6 evolved in the process of pyrolysis of inertinite concentrated was higher than that of raw coal and vitrinite concentrate. As the temperature rising, the production rate of C6H6 increased. Below 672℃, C6H6 evolution rate of vitrinite concentrate was far greater than the other two samples; the main evolution temperature range of C7H8 was 400℃ to 700℃ for the three samples. The amount of HE and H20 released first increased and then decreased with the temperature increase while more H2 released for pyrolysis of inertinite concentrated and more H20 released for the pyrolysis of vitrinite concentrate.展开更多
The study firstly discusses the pyrolysis characteristics and kinetics by thermogravimetric analysis (TGA), and then investigates the pyrolysis of lignite and co-pyrolysis with plastic (polyethylene or polypropyl- ...The study firstly discusses the pyrolysis characteristics and kinetics by thermogravimetric analysis (TGA), and then investigates the pyrolysis of lignite and co-pyrolysis with plastic (polyethylene or polypropyl- ene) in tube furnace. Meanwhile, the research focuses on the co-pyrolysis products under different mix- ing ratios as well as pyrolysis products at different testing temperatures and heating rates. The results show that higher final testing temperature and lower heating rate contribute to bond fission in lignite pyrolysis, resulting in less char product. In co-pyrolysis, lignite acts as hydrogen donor, and the yields of char and water rise with increasing amount of plastic in the mixture, while the yields of gas and tar decrease; and a little admixture of plastic will promote the production of gas and tar. Kinetic studies indi- cate that in temperature range of 530-600℃, activation energies of lignite are higher than those of lig- nite/plastic blends, and as plastic mass ratio increases from 0% to 10%, samples need less energy to be decomposed during co-pyrolysis.展开更多
基金Projects (09-QZ-2008, 24-TZ-2009) supported by the Free Research Fund of State Key Laboratory of Solidification Processing, ChinaProject (B08040) supported by the Program of Introducing Talents of Discipline to Universities, China+3 种基金Projects (51071127, 51134011) supported by the National Natural Science Foundation of ChinaProject (JC200801) supported by the Fundamental Research Fund of Northwestern Polytechnical University, ChinaProject (51125002) supported by the National Science Foundation for Distinguished Young Scholars, ChinaProject (2011CB610403) supported by the National Basic Research Program of China
文摘Departing from an analytical phase transformation model, a new analytical approach to deduce transformed fraction for non-isothermal phase transformation was developed. In the new approach, the effect of the initial transformation temperature and the accurate "temperature integral" approximations are incorporated to obtain an extended analytical model. Numerical approach demonstrated that the extended analytical model prediction for transformed fraction and transformation rate is in good agreement with the exact numerical calculation. The new model can describe more precisely the kinetic behavior than the original analytical model, especially for transformation with relatively high initial transformation temperature. The kinetic parameters obtained from the new model are more accurate and reasonable than those from the original analytical model.
基金Project (11032010) supported by Key Project of National Natural Science Foundation of ChinaProjects (51072171, 61274107, 61176093, 11275163) supported by the National Natural Science Foundation of China+3 种基金Project (IRT1080) supported by Program for Changjiang Scholars and Innovation Research Team in UniversityProject (2012CB326404) supported by National Basic Research Program of ChinaProject (CX2011B248) supported by Hunan Provincial Innovation Foundation for PostgraduateProject (20104301110001) supported by the Doctoral Program of Higher Education of China
文摘Bi0.9La0.1Fe0.95Mn0.05O3 (BLFMO) ferroelectric thin films were fabricated on Pt/Ti/SiO2/Si/ substrates by the sol-gel process at different pyrolysis temperatures. The mass loss of BLFMO powder was investigated by thermo gravimetry analyser (TGA), and the polycrystalline structure and smooth surface of BLFMO thin films were characterized by X-ray diffraction (XRD) and atomic force microscopy (AFM), respectively. The remnant polarization (Pr) of the BLFMO films pyrolyzed at 420 ℃ is 21.2 μC/cm2 at the coercive field (Ec) of 99 kV/cm and the leakage current density is 7.1×10-3 A/cm2, which indicates that the BLFMO thin films display relatively good ferroelectric property at this temperature.
基金Project(2012CB026205)supported by the National Basic Research Program of ChinaProjects(51608264,51778289)supported by the National Natural Science Foundation of ChinaProject(2014Y01)supported by the Transportation Science and Technology Project of Jiangsu Province,China
文摘An exact solution for simply-supported laminated beams with material properties variable with temperature under a combination of uniform thermo-load and mechanical loads was investigated,based on the two-dimensional(2-D)thermo-elasticity theory.Firstly,the beam was divided into a series of layers with uniform material properties along the interfaces of the beam.The uniform thermo-load acted on each layer was transformed into a combination of the normal surface forces acted at the two ends and the transverse thermo-load.Secondly,the state space method was employed to obtain the general solutions of displacements and stresses in an arbitrary layer.Thirdly,based on the interfacial continuity conditions between adjacent layers,the relations of displacement and stress components between the top and bottom layers of the beam were recursively derived by use of the transfer-matrix method.The unknowns in the solutions can be solved by the mechanical loads acted on the top and bottom surfaces.The convergence of the present solutions was checked.The comparative study of the present solutions with the Timoshenko’s solutions and the finite element(FE)solutions was carried out.The effects of material properties variable with temperature on the thermo-elastic behavior of laminated beams were discussed in detail.
文摘In this work, the main characteristics of the Qingdao Cold Water Mass were studied by using "the comparison analysis method" based on 1980 temperature,salinity and dissolved oxygen data on the western South Yellow Sea. The formation cause of the water mass was analyzed based on February of 1959 temperature and salinity data for this area and on some other authors’ studies. The results showed that the Qingdao Cold Water Mass has growing and vanishing processes: appears in the last ten days of March; has stable pattern in April; is biggest in its area in May; becomes small in its area in June; vanishes in July. It comes from the northern Shandong Coastal Water and is characterized by low temperature and salinity and high dissolved oxygen. The mass is formed under the joint effects of anticyclonic circulation and solar radiation.
基金Supported by the National Natural Science Foundation of China(21206009)Funding Project for Academic Human Resources Development in Institutions of Higher Learning under the Jurisdiction of Beijing Municipality(PHR201107123)Program for Doctoral Fund in Beijing University of Civil Engineering and Architecture(101102307)
文摘This study is focused on a steady dissipative layer, which is generated by Marangoni convection flow over the surface resulted from an imposed temperature gradient, coupled with buoyancy effects due to gravity and external pressure. A model is proposed with Marangoni condition in the boundary conditions at the interface. The similarity equations are determined and approximate analytical solutions are obtained by an efficient transformation, asymptotic expansion and Pade approximant technique. For the cases that buoyancy force is favorable or unfavor-able to Marangoni flow, the features of flow and temperature fields are investigated in terms of Marangoni mixed convection parameter and Prantl number.
文摘The pyrolysis characteristics of Shendong Shangwan coal and its macerals concentrate were investigated using thermogravimetry (TG) coupled with mass spectrometry (MS). The evolved gases were analyzed online by MS spectroscopy. The results of TG/DTG (derivative thermogravimetry) show ths vitrinite concentrate has greater weight loss rate and higher volatile yield than the other two samples. More light hydrocarbons C1-C5 are released from the vitfinite concentrate than from the Shendong Shangwan coal and inertinite concentrated in the process of pyrolysis. Three samples have similar shape curves of evolved gases of C2~C5 with different intensities. When the pyrolysis temperature was lower than 418℃, the amount of C6H6 evolved in the process of pyrolysis of inertinite concentrated was higher than that of raw coal and vitrinite concentrate. As the temperature rising, the production rate of C6H6 increased. Below 672℃, C6H6 evolution rate of vitrinite concentrate was far greater than the other two samples; the main evolution temperature range of C7H8 was 400℃ to 700℃ for the three samples. The amount of HE and H20 released first increased and then decreased with the temperature increase while more H2 released for pyrolysis of inertinite concentrated and more H20 released for the pyrolysis of vitrinite concentrate.
基金the financial support from the Priority Academic Program Development of Jiangsu Higher Education Institutionsthe Special Found of International S&T Cooperation Project of China (No.2010DFA72730)
文摘The study firstly discusses the pyrolysis characteristics and kinetics by thermogravimetric analysis (TGA), and then investigates the pyrolysis of lignite and co-pyrolysis with plastic (polyethylene or polypropyl- ene) in tube furnace. Meanwhile, the research focuses on the co-pyrolysis products under different mix- ing ratios as well as pyrolysis products at different testing temperatures and heating rates. The results show that higher final testing temperature and lower heating rate contribute to bond fission in lignite pyrolysis, resulting in less char product. In co-pyrolysis, lignite acts as hydrogen donor, and the yields of char and water rise with increasing amount of plastic in the mixture, while the yields of gas and tar decrease; and a little admixture of plastic will promote the production of gas and tar. Kinetic studies indi- cate that in temperature range of 530-600℃, activation energies of lignite are higher than those of lig- nite/plastic blends, and as plastic mass ratio increases from 0% to 10%, samples need less energy to be decomposed during co-pyrolysis.