Nanosize TiO 2,Y 2 O 3/TiO 2 particles were prepared by the sol-gel process. The structur e was characterized by means of XRD,TEM. The photoelectric properties of the nan oparticles were studied by PL. The thickness a...Nanosize TiO 2,Y 2 O 3/TiO 2 particles were prepared by the sol-gel process. The structur e was characterized by means of XRD,TEM. The photoelectric properties of the nan oparticles were studied by PL. The thickness and the surface of the carboxymethy l cellulose film was measured by SEM. Based on a model reaction, the photocataly tic degradation of methylene blue with positive charge was investigated in TiO 2, Y2O3/TiO 2 nanopowder composite films irradiated by UV lamp. The results revealed that the degradation process belonged to the first-order k inetic reaction.展开更多
Persulfate decontamination technologies utilizing radical‐driven processes are powerful tools for the treatment of a broad range of impurities.However,the design of high‐performance catalytic activators with multi‐...Persulfate decontamination technologies utilizing radical‐driven processes are powerful tools for the treatment of a broad range of impurities.However,the design of high‐performance catalytic activators with multi‐functionality remains a great challenge.Therefore,in this study,three‐dimensional multifunctional FexOy/N‐GN/CNTs(N‐GN:nitrogen‐doped graphene,CNTs:carbon nanotubes)heterojunctions,which can be employed as microwave absorbers and catalysts,were synthesized via a solvothermal method and applied to activate peroxymonosulfate for the degradation of methylene blue(MB).X‐ray diffraction(XRD),Fourier transform infrared spectrometer(FTIR),scanning electron microscope(SEM),and X‐ray photoelectron microscopy(XPS)analyses revealed that the FexOy were anchored in‐situ onto the N‐GN network.Using MB as the model organic dye,various factors,such as degradation systems,PMS loading,initial organic pollutant concentration,and catalyst dosage were optimized.The results revealed that the remarkable efficiency was attributable to the synergistic effects of carbon,nitrogen,and iron‐based species.The oxidation system corresponded to the pseudo‐first‐order kinetic with a k value of^0.33 min^-1.It was demonstrated that both SO4^-and OH^-were the predominant reactive species through quenching experiments.Because these heterojunctions were employed as microwave absorbers and have a semiconductor‐like texture,the Fe/N co‐rich hierarchical porous carbon skeleton favored electron transport and storage.These heterojunctions increase the options for transitional metal catalysts and highlights the importance of designing other heterojunctions for specific applications,such as supercapacitors,energy storage,CO2 capture,and oxygen reduction electrocatalysts.展开更多
Nodular structures were formed by rhizobia on oilseed rape roots following treatment with pectinolytic bacteria. Nodules developed within 50 days.Photomicrograph of nodule cells showed that the capsulated bacteria wer...Nodular structures were formed by rhizobia on oilseed rape roots following treatment with pectinolytic bacteria. Nodules developed within 50 days.Photomicrograph of nodule cells showed that the capsulated bacteria were intrarellular.Rhizobia reisolated from the root nodules retained not only the ability of nodulation but also the characteristic of resistance to 100 μg neomycin mL-1.A low nitrogenaSe activity of the nodules was determined by the method of acetylene reduction.展开更多
INTRODUCTION It is an interesting research area using urease inhibitors to curb urease activity in soil,to decrease the rate of urea hydrolysis and to increase the recovery of urea nitrogen(Zhou,1984;Guan,1985).Few st...INTRODUCTION It is an interesting research area using urease inhibitors to curb urease activity in soil,to decrease the rate of urea hydrolysis and to increase the recovery of urea nitrogen(Zhou,1984;Guan,1985).Few studies have been conducted on the relationship betweenthe effectiveness of the inhibitors applied to rice and the environmental conditions and展开更多
基金Support Foundation of Fujian Education Bureau( K04026) Support Foundation of Fujian Development &Reformation Committee(04FJSD)
文摘Nanosize TiO 2,Y 2 O 3/TiO 2 particles were prepared by the sol-gel process. The structur e was characterized by means of XRD,TEM. The photoelectric properties of the nan oparticles were studied by PL. The thickness and the surface of the carboxymethy l cellulose film was measured by SEM. Based on a model reaction, the photocataly tic degradation of methylene blue with positive charge was investigated in TiO 2, Y2O3/TiO 2 nanopowder composite films irradiated by UV lamp. The results revealed that the degradation process belonged to the first-order k inetic reaction.
基金supported by the National Natural Science Foundation of China(21676039)Innovative talents in Liaoning universities and colleges(LR2017045)the Opening Foundation of State Key Laboratory of Inorganic Synthesis and Preparative Chemistry of Jilin University(2016–04)~~
文摘Persulfate decontamination technologies utilizing radical‐driven processes are powerful tools for the treatment of a broad range of impurities.However,the design of high‐performance catalytic activators with multi‐functionality remains a great challenge.Therefore,in this study,three‐dimensional multifunctional FexOy/N‐GN/CNTs(N‐GN:nitrogen‐doped graphene,CNTs:carbon nanotubes)heterojunctions,which can be employed as microwave absorbers and catalysts,were synthesized via a solvothermal method and applied to activate peroxymonosulfate for the degradation of methylene blue(MB).X‐ray diffraction(XRD),Fourier transform infrared spectrometer(FTIR),scanning electron microscope(SEM),and X‐ray photoelectron microscopy(XPS)analyses revealed that the FexOy were anchored in‐situ onto the N‐GN network.Using MB as the model organic dye,various factors,such as degradation systems,PMS loading,initial organic pollutant concentration,and catalyst dosage were optimized.The results revealed that the remarkable efficiency was attributable to the synergistic effects of carbon,nitrogen,and iron‐based species.The oxidation system corresponded to the pseudo‐first‐order kinetic with a k value of^0.33 min^-1.It was demonstrated that both SO4^-and OH^-were the predominant reactive species through quenching experiments.Because these heterojunctions were employed as microwave absorbers and have a semiconductor‐like texture,the Fe/N co‐rich hierarchical porous carbon skeleton favored electron transport and storage.These heterojunctions increase the options for transitional metal catalysts and highlights the importance of designing other heterojunctions for specific applications,such as supercapacitors,energy storage,CO2 capture,and oxygen reduction electrocatalysts.
文摘Nodular structures were formed by rhizobia on oilseed rape roots following treatment with pectinolytic bacteria. Nodules developed within 50 days.Photomicrograph of nodule cells showed that the capsulated bacteria were intrarellular.Rhizobia reisolated from the root nodules retained not only the ability of nodulation but also the characteristic of resistance to 100 μg neomycin mL-1.A low nitrogenaSe activity of the nodules was determined by the method of acetylene reduction.
文摘INTRODUCTION It is an interesting research area using urease inhibitors to curb urease activity in soil,to decrease the rate of urea hydrolysis and to increase the recovery of urea nitrogen(Zhou,1984;Guan,1985).Few studies have been conducted on the relationship betweenthe effectiveness of the inhibitors applied to rice and the environmental conditions and
